Chemistry:Methyl pivalate

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Methyl pivalate
MePivalate.png
Names
Preferred IUPAC name
Methyl 2,2-dimethylpropanoate
Other names
Methyl trimethylacetate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 209-959-1
UNII
Properties
C6H12O2
Molar mass 116.160 g·mol−1
Appearance Colorless liquid
Odor Vinegar-Like
Density 0.873 g/cm3
Boiling point 101 °C (214 °F; 374 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Methyl pivalate is an organic compound with the formula CH3O2CC(CH3)3. It is a colorless liquid, the methyl ester of pivalic acid. The ester is well known for being resistant to hydrolysis to the parent acid. Hydrolysis can be effected with a solution of trimethylsilyl iodide in hot acetonitrile followed by aqueous workup.[1] [2]

References

  1. Olah, George A.; Narang, Subhash C.; Gupta, B. G. Balaram; Malhotra, Ripudaman (1979). "Transformations with chlorotrimethylsilane/sodium iodide, a convenient in situ Iodotrimethylsilane Reagent". J. Org. Chem. 44: 1247–1251. doi:10.1021/jo01322a012. 
  2. "MSDS Methyl trimethylacetate". https://www.fishersci.com/store/msds?partNumber=AC127951000&productDescription=METHYL+TRIMETHYLACETATE%2C+100ML&vendorId=VN00032119&countryCode=US&language=en.