Chemistry:Tonka (fuel)
Tonka (also TONKA-250 and R-Stoff) is the name given to a Germany -designed rocket propellant first used in the Wasserfall missile,[1] and recently used by North Korea.[2] It was used in the Soviet Union under the name TG-02, for example in the engine designs of the A.M. Isayev Chemical Engineering Design Bureau.
Its name is a reference to the tonka bean.[3] Being invented during the Second World War, it has no connection to the similarly named toys.
Its composition is approximately 50% triethylamine and 50% xylidine, most commonly used with nitric acid or its anhydrous nitric oxide derivatives (classified as the AK-2x family in the Soviet Union) as the oxidiser; the combination is hypergolic and has a maximum practical specific impulse of approximately 2.12–2.43 km/s (216–248 s) at sea level, with the latter figure stated as a specification for the R-21 Submarine Launched Ballistic Missile, first fielded in 1963.[4]
The Soviet Union reverse-engineered the Wasserfall missile and investigated the use of hypergolic propellants for the eventually abandoned Burya intercontinental cruise missile project. It put TG-02/AK-2x fuelled engines into service with the Kh-22 cruise missile[5] and the S5.4 de-orbit engine used on the Vostok and Voskhod spacecraft and the Zenit satellite.[6]
The most globalized use of Tonka is as an igniter in many Soviet Scud missile variants and its descendants, such as the North Korean Nodong, which are principally propelled by nitric acid and kerosene (TM-185). This combination is not hypergolic so needs an ignition source, supplied by a system that injects a few kilograms of Tonka fuel when ignition is desired.[7] The progenitor Scud engine, the S2.253, with a specific impulse of 2.15 km/s (219 s) at sea level,[8] popularized this ignition arrangement.
Triethylamine/xylidine mixtures composed the TX and TX2 fuels of the French SEPR rocket engines of the 1950s, used for auxiliary rocket power in the Mirage IIIC.[9] In aircraft use, TX fuels were later replaced by non-toxic kerosene jet fuels, simplifying fuelling of the aircraft. Little change was required to the engines but as this was no longer hypergolic with nitric acid, a small tank of TX was retained for ignition.
The use of Tonka by amateurs is not advised,[citation needed] because the exact proportions of ingredients necessary for the mixture to work as desired, rather than fail catastrophically, is a function both of the purity of the ingredients and their temperature during use.
See also
- Furfuryl alcohol - also hypergolic with nitric acid but lower performance
- Unsymmetrical dimethylhydrazine - a higher performance substance that replaced Tonka/TG-02 as a fuel for Soviet spacecraft.
References
- ↑ Nitric acid/Amine. Encycylopedia Astronautica
- ↑ "Analysis of North Korean missiles using Tonka fuel". Archived from the original on 2006-09-07. https://web.archive.org/web/20060907063417/http://www.nti.org/e_research/profiles/NK/Missile/1376.html.
- ↑ Clark, John D. (1972). Ignition! An Informal History of Liquid Rocket Propellants. Rutgers University Press. p. 14. ISBN 0-8135-0725-1.
- ↑ Nodong missile analysis by FAS. data on R-13/SS-N-4 and R-21/SS-N-5 Isayev engine S5.38
- ↑ Soviet/Russian Cruise Missiles, Technical Report APA-TR-2009-0805
- ↑ Brügge, Norbert. "Spacecraft-propulsion blocks (KDU) from Isayev's design bureau (now Khimmash)". B14643.de. Archived from the original on 2015-06-02. https://web.archive.org/web/20150602231608/http://www.b14643.de/Spacerockets/Diverse/KB-Isayev_KDUs/index.htm. Retrieved 2015-06-02.
- ↑ Debris from North Korea’s Launcher: What It Shows
- ↑ "S2.253". http://www.friends-partners.org/mwade/engines/s2253.htm.
- ↑ Rothmund, Christophe (2004). "Reusable Man-rated Rocket Engines: The French Experience, 1944-1996". 55th International Astronautical Congress. Vancouver, Canada. p. 2. IAC-04-IAA-6.15.3.02. Archived from the original on 2015-10-24. https://web.archive.org/web/20151024232902/http://www.spl.ch/news/SEPR/AIAA-43160-765.pdf.
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