View source for Physics:Birefringence

{{short description|Property of materials whose refractive index depends on light polarization and direction}}
[[File:Crystal on graph paper.jpg|right|thumb|A calcite crystal laid upon a graph paper with blue lines showing the double refraction]]
[[File:Positively birefringent material.svg|right|thumb|In this example, optic axis along the surface is shown perpendicular to plane of incidence. Incoming light in the {{mvar|s}} polarization (which means perpendicular to plane of incidence – and so in this example becomes "parallel polarisation" to optic axis, thus is called extraordinary ray) sees a greater refractive index than light in the {{mvar|p}} polarization (which becomes ordinary ray because "perpendicular polarisation" to optic axis) and so {{mvar|s}} polarization ray is undergoing greater refraction on entering and exiting the crystal.]]
'''Birefringence''' is the [[Physics:Optics|optical]] property of a material having a [[Physics:Refractive index|refractive index]] that depends on the [[Physics:Polarization (waves)|polarization]] and propagation direction of [[Physics:Light|light]].<ref>{{cite web |url=https://www.olympus-lifescience.com/en/microscope-resource/primer/lightandcolor/birefringence/ |title=Olympus Microscopy Resource Center |publisher=Olympus Life Science Inc. |last1=Abramowitz |first1=Mortimer |last2=Davidson |first2=Michael W. |access-date=2021-07-21 }}</ref> These optically anisotropic materials are said to be '''birefringent''' (or '''birefractive'''). The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. [[Earth:Crystal|Crystal]]s with non-cubic [[Chemistry:Crystal structure|crystal structure]]s are often birefringent, as are [[Chemistry:Plastic|plastic]]s under mechanical stress.  

Birefringence is responsible for the phenomenon of '''double refraction''' whereby a [[Physics:Ray (optics)|ray]] of light, when incident upon a birefringent material, is split by polarization into two rays taking slightly different paths. This effect was first described by Danish scientist Rasmus Bartholin in 1669, who observed it<ref>See:
* Erasmus Bartholin, [https://books.google.com/books?id=F7RAAAAAcAAJ&pg=PP11 ''Experimenta crystalli islandici disdiaclastici quibus mira & infolita refractio detegitur''] [Experiments on birefringent Icelandic crystal through which is detected a remarkable and unique refraction] (Copenhagen, Denmark: Daniel Paulli, 1669). 
* Erasmus Bartholin (January 16, 1671) [https://books.google.com/books?id=Zl5FAAAAcAAJ&pg=PA2141 "An account of sundry experiments made and communicated by that learn'd mathematician, Dr. Erasmus Bartholin, upon a chrystal-like body, sent to him out of Island,"] ''Philosophical Transactions of the Royal Society of London'', '''5''' : 2041–2048 (pdf pp 282–289).</ref> in [[Chemistry:Calcite|calcite]] crystals which have one of the strongest birefringences. In the 19th century [[Biography:Augustin-Jean Fresnel|Augustin-Jean Fresnel]] described the phenomenon in terms of polarization, understanding light as a wave with field components in transverse polarization (perpendicular to the direction of the wave vector).<ref name=fresnel-1821a>A. Fresnel, "Note sur le calcul des teintes que la polarisation développe dans les lames cristallisées" et&nbsp;seq., ''Annales de Chimie et de Physique'', Ser.&nbsp;2, vol.&nbsp;17, pp.&nbsp;102–111 (May&nbsp;1821), 167–96 (June&nbsp;1821), 312–15 ("Postscript", July&nbsp;1821); reprinted (with added section nos.) in Fresnel, 1866–70, vol.&nbsp;1, pp.&nbsp;609–648; translated as "On the calculation of the tints that polarization develops in crystalline plates, &amp;&nbsp;postscript", {{Zenodo|4058004}} (Creative Commons), 2021; §14.</ref><ref name=fresnel-1822-25>A. Fresnel, "Extrait d'un Mémoire sur la double réfraction", ''Annales de Chimie et de Physique'', Ser.&nbsp;2, vol.&nbsp;28, pp.&nbsp;263–279 (March&nbsp;1825); reprinted as "Extrait du second Mémoire sur la double réfraction" in Fresnel, 1866–70, vol.&nbsp;2, pp.&nbsp;465–478; translated as "Extract of a [second] memoir on double refraction", {{Zenodo|5442206}}, 2021 (open&nbsp;access).</ref> Birefringence plays an important role in achieving phase-matching for a number of [[Physics:Nonlinear optics|nonlinear]] optical processes.

==Explanation==
[[File:Calcite and polarizing filter.gif|right|thumb|Doubly refracted image as seen through a calcite crystal, seen through a rotating polarizing filter illustrating the opposite polarization states of the two images.]]

A mathematical description of wave propagation in a birefringent medium is presented below. Following is a qualitative explanation of the phenomenon.

===Uniaxial materials===
The simplest type of birefringence is described as ''uniaxial'', meaning that there is a single direction governing the optical anisotropy whereas all directions perpendicular to it (or at a given angle to it) are optically equivalent. Thus rotating the material around this axis does not change its optical behaviour. This special direction is known as the [[Physics:Optic axis of a crystal|optic axis]] of the material. Light propagating parallel to the optic axis (whose polarization is always ''perpendicular'' to the optic axis) is governed by a refractive index {{math|''n''<sub>o</sub>}} (for "ordinary") regardless of its specific polarization. For rays with any other propagation direction, there is one linear polarization that is perpendicular to the optic axis, and a ray with that polarization is called an ''ordinary ray'' and is governed by the same refractive index value {{math|''n''<sub>o</sub>}}. For a ray propagating in the same direction but with a polarization perpendicular to that of the ordinary ray, the polarization direction will be partly in the direction of (parallel to) the optic axis, and this ''extraordinary ray'' will be governed by a different, ''direction-dependent'' refractive index. Because the index of refraction depends on the polarization when unpolarized light enters a uniaxial birefringent material, it is split into two beams travelling in different directions, one having the polarization of the ordinary ray and the other the polarization of the extraordinary ray.
The ordinary ray will always experience a refractive index of {{math|''n''<sub>o</sub>}}, whereas the refractive index of the extraordinary ray will be in between {{math|''n''<sub>o</sub>}} and {{math|''n''<sub>e</sub>}}, depending on the ray direction as described by the [[Index ellipsoid|index ellipsoid]]. The magnitude of the difference is quantified by the birefringence<ref>{{Cite book |last=Ehlers |first=Ernest G. |title=Optical Mineralogy: Theory and Technique |publisher=Blackwell Scientific Publications |year=1987 |isbn=0-86542-323-7 |volume=1 |location=Palo Alto |pages=28}}</ref>

:<math>\Delta n=n_\mathrm{e}-n_\mathrm{o}\,.</math>

The propagation (as well as [[Physics:Fresnel equations|reflection coefficient]]) of the ordinary ray is simply described by {{math|''n''<sub>o</sub>}} as if there were no birefringence involved. The extraordinary ray, as its name suggests, propagates unlike any wave in an isotropic optical material. Its refraction (and reflection) at a surface can be understood using the effective refractive index (a value in between {{math|''n''<sub>o</sub>}} and {{math|''n''<sub>e</sub>}}). Its power flow (given by the [[Poynting vector]]) is not exactly in the direction of the [[Physics:Wave vector|wave vector]]. This causes an additional shift in that beam, even when launched at normal incidence, as is popularly observed using a crystal of [[Chemistry:Calcite|calcite]] as photographed above. Rotating the calcite crystal will cause one of the two images, that of the extraordinary ray, to rotate slightly around that of the ordinary ray, which remains fixed.{{Verify source|date=February 2020}}

When the light propagates either along or orthogonal to the optic axis, such a lateral shift does not occur. In the first case, both polarizations are perpendicular to the optic axis and see the same effective refractive index, so there is no extraordinary ray. In the second case the extraordinary ray propagates at a different phase velocity (corresponding to {{math|''n''<sub>e</sub>}}) but still has the power flow in the direction of the [[Physics:Wave vector|wave vector]]. A crystal with its optic axis in this orientation, parallel to the optical surface, may be used to create a [[Physics:Waveplate|waveplate]], in which there is no distortion of the image but an intentional modification of the state of polarization of the incident wave. For instance, a [[Physics:Waveplate#Quarter-wave plate|quarter-wave plate]] is commonly used to create [[Astronomy:Circular polarization|circular polarization]] from a linearly polarized source.

===Biaxial materials===
The case of so-called biaxial crystals is substantially more complex.<ref name="landaulifshitz">Landau, L. D., and Lifshitz, E. M., ''Electrodynamics of Continuous Media'', Vol. 8 of the ''Course of Theoretical Physics'' 1960 (Pergamon Press), §79</ref> These are characterized by ''three'' refractive indices corresponding to three principal axes of the crystal. For most ray directions, ''both'' polarizations would be classified as extraordinary rays but with different effective refractive indices. Being extraordinary waves, the direction of power flow is not identical to the direction of the wave vector in either case.

The two refractive indices can be determined using the [[Index ellipsoid|index ellipsoid]]s for given directions of the polarization. Note that for biaxial crystals the index ellipsoid will ''not'' be an ellipsoid of revolution ("[[Spheroid|spheroid]]") but is described by three unequal principle refractive indices {{math|''n''<sub>α</sub>}}, {{math|''n''<sub>β</sub>}} and {{math|''n''<sub>γ</sub>}}. Thus there is no axis around which a rotation leaves the optical properties invariant (as there is with uniaxial crystals whose index ellipsoid ''is'' a spheroid).

Although there is no axis of symmetry, there are ''two'' optical axes or ''binormals'' which are defined as directions along which light may propagate without birefringence, i.e., directions along which the wavelength is independent of polarization.<ref name="landaulifshitz"/> For this reason, birefringent materials with three distinct refractive indices are called ''biaxial''. Additionally, there are two distinct axes known as ''optical ray axes'' or ''biradials'' along which the group velocity of the light is independent of polarization.

===Double refraction===
When an arbitrary beam of light strikes the surface of a birefringent material at non-normal incidence, the polarization component normal to the optic axis (ordinary ray) and the other linear polarization (extraordinary ray) will be refracted toward somewhat different paths. Natural light, so-called [[Physics:Polarization (waves)#Unpolarized and partially polarized light|unpolarized light]], consists of equal amounts of energy in any two orthogonal polarizations. Even linearly polarized light has some energy in both polarizations, unless aligned along one of the two axes of birefringence. According to [[Physics:Snell's law|Snell's law]] of refraction, the two angles of refraction are governed by the effective [[Physics:Refractive index|refractive index]] of each of these two polarizations. This is clearly seen, for instance, in the [[Wollaston prism]] which separates incoming light into two linear polarizations using prisms composed of a birefringent material such as [[Chemistry:Calcite|calcite]].

The different angles of refraction for the two polarization components are shown in the figure at the top of this page, with the optic axis along the surface (and perpendicular to the [[Plane of incidence|plane of incidence]]), so that the angle of refraction is different for the {{mvar|p}} polarization (the "ordinary ray" in this case, having its electric vector perpendicular to the optic axis) and the {{mvar|s}} polarization (the "extraordinary ray" in this case, whose electric field polarization includes a component in the direction of the optic axis). In addition, a distinct form of double refraction occurs, even with normal incidence, in cases where the optic axis is not along the refracting surface (nor exactly normal to it); in this case, the dielectric polarization of the birefringent material is not exactly in the direction of the wave's [[Physics:Electric field|electric field]] for the extraordinary ray. The direction of power flow (given by the [[Poynting vector]]) for this inhomogenous wave is at a finite angle from the direction of the [[Physics:Wave vector|wave vector]] resulting in an additional separation between these beams. So even in the case of normal incidence, where one would compute the angle of refraction as zero (according to Snell's law, regardless of the effective index of refraction), the energy of the extraordinary ray is propagated at an angle. If exiting the crystal through a face parallel to the incoming face, the direction of both rays will be restored, but leaving a ''shift'' between the two beams. This is commonly observed using a piece of calcite cut along its natural cleavage, placed above a paper with writing, as in the above photographs. On the contrary, [[Physics:Waveplate|waveplate]]s specifically have their optic axis ''along'' the surface of the plate, so that with (approximately) normal incidence there will be no shift in the image from light of either polarization, simply a relative phase shift between the two light waves.

==Terminology==
[[File:Comparison_of_positive_and_negative_birefringence.svg|thumb|Comparison of positive and negative birefringence : In positive birefringence (figure 1), the ordinary ray (p-polarisation in this case w.r.t. magenta-coloured plane of incidence), perpendicular to optic axis A is the fast ray (F) while the extraordinary ray (s-polarisation in this case and parallel to optic axis A) is the slow ray (S). In negative birefringence (figure 2), it is the reverse.]]
Much of the work involving polarization preceded the understanding of light as a transverse electromagnetic wave, and this has affected some terminology in use. Isotropic materials have symmetry in all directions and the refractive index is the same for any polarization direction. An anisotropic material is called "birefringent" because it will generally refract a single incoming ray in two directions, which we now understand correspond to the two different polarizations. This is true of either a uniaxial or biaxial material.

In a uniaxial material, one ray behaves according to the normal law of refraction (corresponding to the ordinary refractive index), so an incoming ray at normal incidence remains normal to the refracting surface. As explained above, the other polarization can deviate from normal incidence, which cannot be described using the law of refraction. This thus became known as the ''extraordinary ray''. The terms "ordinary" and "extraordinary" are still applied to the polarization components perpendicular to and not perpendicular to the optic axis respectively, even in cases where no double refraction is involved.

A material is termed ''uniaxial'' when it has a single direction of symmetry in its optical behavior, which we term the optic axis. It also happens to be the axis of symmetry of the index ellipsoid (a spheroid in this case). The index ellipsoid could still be described according to the refractive indices, {{math|''n''<sub>α</sub>}}, {{math|''n''<sub>β</sub>}} and {{math|''n''<sub>γ</sub>}}, along three coordinate axes; in this case two are equal. So if {{math|''n''<sub>α</sub> {{=}} ''n''<sub>β</sub>}} corresponding to the {{mvar|x}} and {{mvar|y}} axes, then the extraordinary index is {{math|''n''<sub>γ</sub>}} corresponding to the {{mvar|z}} axis, which is also called the ''optic axis'' in this case.

Materials in which all three refractive indices are different are termed ''biaxial'' and the origin of this term is more complicated and frequently misunderstood. In a uniaxial crystal, different polarization components of a beam will travel at different phase velocities, ''except'' for rays in the direction of what we call the optic axis. Thus the optic axis has the particular property that rays in that direction do ''not'' exhibit birefringence, with all polarizations in such a beam experiencing the same index of refraction. It is very different when the three principal refractive indices are all different; then an incoming ray in any of those principal directions will still encounter two different refractive indices. But it turns out that there are two special directions (at an angle to all of the 3 axes) where the refractive indices for different polarizations are again equal. For this reason, these crystals were designated as ''biaxial'', with the two "axes" in this case referring to ray directions in which propagation does not experience birefringence.

=== Fast and slow rays ===
In a birefringent material, a wave consists of two polarization components which generally are governed by different effective refractive indices. The so-called ''slow ray'' is the component for which the material has the higher effective refractive index (slower phase velocity), while the ''fast ray'' is the one with a lower effective refractive index. When a beam is incident on such a material from air (or any material with a lower refractive index), the slow ray is thus refracted more towards the normal than the fast ray. In the example figure at top of this page, it can be seen that refracted ray with ''s'' polarization (with its electric vibration along the direction of the optic axis, thus called the extraordinary ray<ref>Born & Wolf, 2002, pp.{{nnbsp}}807–808. (In 19th-century terminology, the ordinary ray is said to be polarized in the plane of the optic axis; but this "[[Physics:Plane of polarization|plane of polarization]]" is the plane ''perpendicular'' to the vibration; cf.&nbsp;Fresnel, 1827, tr.&nbsp;Hobson, p.{{nnbsp}}318.)</ref>) is the slow ray in given scenario.

Using a thin slab of that material at normal incidence, one would implement a [[Physics:Waveplate|waveplate]]. In this case, there is essentially no spatial separation between the polarizations, the phase of the wave in the parallel polarization (the slow ray) will be retarded with respect to the perpendicular polarization. These directions are thus known as the slow axis and fast axis of the waveplate.

===Positive or negative===
Uniaxial birefringence is classified as positive when the extraordinary index of refraction {{math|''n''<sub>e</sub>}} is greater than the ordinary index {{math|''n''<sub>o</sub>}}. Negative birefringence means that {{math|Δ''n'' {{=}} ''n''<sub>e</sub> − ''n''<sub>o</sub>}} is less than zero.<ref>''Brad Amos''. [http://homepage.ntlworld.com/w.amos2/Brad%20Amos%27s%20Website/BR1.pdf Birefringence for facetors I: what is birefringence?] {{webarchive |url=https://web.archive.org/web/20131214030317/http://homepage.ntlworld.com/w.amos2/Brad%20Amos%27s%20Website/BR1.pdf |date=December 14, 2013 }} First published in StoneChat, the Journal of the UK Facet Cutter's Guild. January–March. edition 2005.</ref> In other words, the polarization of the fast (or slow) wave is perpendicular to the optic axis when the birefringence of the crystal is positive (or negative, respectively). In the case of biaxial crystals, all three of the principal axes have different refractive indices, so this designation does not apply. But for any defined ray direction one can just as well designate the fast and slow ray polarizations.

== Sources of optical birefringence ==
[[File:cmglee_London_Embassy_Gardens_pool_polariser.jpg|thumb|upright|View from under the Sky Pool, London with coloured fringes due to stress birefringence of partially polarised skylight through a circular polariser]]
While the best known source of birefringence is the entrance of light into an anisotropic crystal, it can result in otherwise optically isotropic materials in a few ways:
* ''Stress birefringence'' results when a normally isotropic solid is stressed and deformed (i.e., stretched or bent) causing a loss of physical isotropy and consequently a loss of isotropy in the material's permittivity tensor;
* Form birefringence, whereby structure elements such as rods, having one refractive index, are suspended in a medium with a different refractive index. When the lattice spacing is much smaller than a wavelength, such a structure is described as a [[Physics:Metamaterial|metamaterial]];
* By the [[Pockels effect|Pockels]] or [[Physics:Kerr effect|Kerr effect]], whereby an applied electric field induces birefringence due to [[Physics:Nonlinear optics|nonlinear optics]];
* By the self or forced alignment into thin films of [[Chemistry:Amphiphile|amphiphilic]] molecules such as lipids, some surfactants or liquid crystals{{Citation needed|date=November 2021}};
* ''[[Physics:Optical rotation|Circular birefringence]]'' takes place generally not in materials which are anisotropic but rather ones which are chiral. This can include liquids where there is an [[Chemistry:Enantiomeric excess|enantiomeric excess]] of a chiral molecule, that is, one that has [[Chemistry:Stereoisomerism|stereo isomers]];
* By the [[Physics:Faraday effect|Faraday effect]], where a longitudinal magnetic field causes some materials to become ''[[Physics:Optical rotation|circularly birefringent]]'' (having slightly different indices of refraction for left- and right-handed [[Astronomy:Circular polarization|circular polarization]]s), similar to optical activity while the field is applied.

== Common birefringent materials ==
[[File:Food Polarization-Dierking.jpg|right|thumb|Sandwiched in between crossed polarizers, clear polystyrene cutlery exhibits wavelength-dependent birefringence]]

The best characterized birefringent materials are crystals. Due to their specific crystal structures their refractive indices are well defined. Depending on the symmetry of a crystal structure (as determined by one of the 32 possible [[Crystallographic point group|crystallographic point group]]s), crystals in that group may be forced to be isotropic (not birefringent), to have uniaxial symmetry, or neither in which case it is a biaxial crystal. The crystal structures permitting uniaxial and biaxial birefringence are noted in the two tables, below, listing the two or three principal refractive indices (at wavelength 590&nbsp;nm) of some better-known crystals.<ref name=hypertextbook/>

In addition to induced birefringence while under stress, many [[Chemistry:Plastic|plastic]]s obtain permanent birefringence during manufacture due to stresses which are "frozen in" due to mechanical forces present when the plastic is molded or extruded.<ref>{{cite journal|doi=10.1002/pen.10347 | volume=38 | issue=10 | title=The use of birefringence for predicting the stiffness of injection molded polycarbonate discs | year=1998 | journal=Polymer Engineering & Science | pages=1770–1777 | last1 = Neves | first1 = N. M.| url=https://ris.utwente.nl/ws/files/6879171/Powell98use.pdf }}</ref> For example, ordinary [[Chemistry:Cellophane|cellophane]] is birefringent. [[Physics:Polarizer|Polarizer]]s are routinely used to detect stress, either applied or frozen-in, in plastics such as [[Chemistry:Polystyrene|polystyrene]] and [[Physics:Polycarbonate|polycarbonate]].

[[Biology:Cotton|Cotton]] fiber is birefringent because of high levels of cellulosic material in the fibre's secondary cell wall which is directionally aligned with the cotton fibers.

Polarized light microscopy is commonly used in biological tissue, as many biological materials are linearly or circularly birefringent. Collagen, found in cartilage, tendon, bone, corneas, and several other areas in the body, is birefringent and commonly studied with polarized light microscopy.<ref>{{cite journal | last1 = Wolman | first1 = M. | last2 = Kasten | first2 = F. H. | year = 1986 | title = Polarized light microscopy in the study of the molecular structure of collagen and reticulin | journal = Histochemistry | volume = 85 | issue = 1| pages = 41–49 | doi=10.1007/bf00508652| pmid = 3733471 | s2cid = 25214054 }}</ref> Some proteins are also birefringent, exhibiting form birefringence.<ref>{{cite journal | last1 = Sano | first1 = Y | year = 1988 | title = Optical anistropy of bovine serum albumin | journal = J. Colloid Interface Sci. | volume = 124 | issue = 2| pages = 403–407 | doi=10.1016/0021-9797(88)90178-6|bibcode = 1988JCIS..124..403S }}</ref>

Inevitable manufacturing imperfections in [[Engineering:Optical fiber|optical fiber]] leads to birefringence, which is one cause of [[Physics:Polarization mode dispersion|pulse broadening]] in [[Physics:Fiber-optic communication|fiber-optic communication]]s. Such imperfections can be geometrical (lack of circular symmetry), or due to unequal lateral stress applied to the optical fibre. Birefringence is ''intentionally'' introduced (for instance, by making the cross-section elliptical) in order to produce [[Engineering:Polarization-maintaining optical fiber|polarization-maintaining optical fiber]]s. Birefringence can be induced (or corrected!) in optical fibers through bending them which causes anisotropy in form and stress given the axis around which it is bent and radius of curvature.

In addition to anisotropy in the electric polarizability that we have been discussing, anisotropy in the [[Physics:Permeability (electromagnetism)|magnetic permeability]] could be a source of birefringence. At optical frequencies, there is no measurable magnetic polarizability (''μ''=[[Physics:Vacuum permeability|''μ''<sub>0</sub>]]) of natural materials, so this is not an actual source of birefringence.
{{col-begin}}
{{col-2}}
{| class="wikitable sortable" style="margin: 0em 0em 1em 1em;"
|+ Uniaxial crystals, at 590&nbsp;nm<ref name=hypertextbook>{{cite journal|last=Elert|first=Glenn|title=Refraction|journal=The Physics Hypertextbook|year=2021|url=http://physics.info/refraction/}}</ref>
|-
! Material || [[Crystal system]] || {{math|''n''<sub>o</sub>}} || {{math|''n''<sub>e</sub>}} || {{math|Δ''n''}}
|-
| [[Chemistry:Barium borate|barium borate]] BaB<sub>2</sub>O<sub>4</sub>|| [[Chemistry:Trigonal|Trigonal]] ||1.6776 ||1.5534 ||−0.1242
|-
| [[Chemistry:Beryl|beryl]] Be<sub>3</sub>Al<sub>2</sub>(SiO<sub>3</sub>)<sub>6</sub>|| Hexagonal ||1.602 ||1.557 ||−0.045
|-
| [[Chemistry:Calcite|calcite]] CaCO<sub>3</sub> || [[Chemistry:Trigonal|Trigonal]] || 1.658 || 1.486 || −0.172
|-
| [[Earth:Ice|ice]] H<sub>2</sub>O || Hexagonal || 1.3090 || 1.3104 || +0.0014<ref name="HobbsIcePhysics">{{cite book |last1=Hobbs |first1=Peter Victor |title=Ice physics |date=2010 |publisher=Oxford University Press |location=New York |isbn=978-0-19-958771-1 |page=202}}</ref>
|-
| [[Chemistry:Lithium niobate|lithium niobate]] LiNbO<sub>3</sub>|| [[Chemistry:Trigonal|Trigonal]] || 2.272|| 2.187|| −0.085
|-
| [[Chemistry:Magnesium fluoride|magnesium fluoride]] MgF<sub>2</sub>|| Tetragonal || 1.380|| 1.385|| +0.006
|-
| [[Chemistry:Quartz|quartz]] SiO<sub>2</sub>|| [[Chemistry:Trigonal|Trigonal]] || 1.544|| 1.553|| +0.009
|-
| [[Chemistry:Ruby|ruby]] Al<sub>2</sub>O<sub>3</sub>|| [[Chemistry:Trigonal|Trigonal]] || 1.770|| 1.762|| −0.008
|-
| [[Chemistry:Rutile|rutile]] TiO<sub>2</sub>|| Tetragonal || 2.616|| 2.903|| +0.287
|-
| [[Chemistry:Sapphire|sapphire]] Al<sub>2</sub>O<sub>3</sub>|| [[Chemistry:Trigonal|Trigonal]] || 1.768|| 1.760|| −0.008
|-
| [[Chemistry:Silicon carbide|silicon carbide]] SiC|| Hexagonal || 2.647|| 2.693|| +0.046
|-
| [[Chemistry:Tourmaline|tourmaline]] (complex silicate)|| [[Chemistry:Trigonal|Trigonal]] || 1.669|| 1.638|| −0.031
|-
| [[Chemistry:Zircon|zircon]], high ZrSiO<sub>4</sub>|| Tetragonal || 1.960|| 2.015|| +0.055
|-
| zircon, low ZrSiO<sub>4</sub>|| Tetragonal || 1.920|| 1.967|| +0.047
|}
{{col-2}}
{| class="wikitable sortable" style="margin: 0em 0em 1em 1em;"
|+ Biaxial crystals, at 590&nbsp;nm<ref name=hypertextbook/>
|-
! Material ||Crystal system || {{math|''n''<sub>α</sub>}} || {{math|''n''<sub>β</sub>}} || {{math|''n''<sub>γ</sub>}}
|-
|[[Chemistry:Borax|borax]] Na<sub>2</sub>(B<sub>4</sub>O<sub>5</sub>)(OH)<sub>4</sub>·8H<sub>2</sub>O ||[[Chemistry:Monoclinic|Monoclinic]]||1.447 ||1.469 ||1.472
|-
|[[Chemistry:Magnesium sulfate|epsom salt]] MgSO<sub>4</sub>·7H<sub>2</sub>O || [[Chemistry:Monoclinic|Monoclinic]]||1.433 ||1.455 ||1.461
|-
|[[Chemistry:Mica|mica]], [[Chemistry:Biotite|biotite]] K(Mg,Fe)<sub>3</sub>(AlSi<sub>3</sub>O<sub>10</sub>)(F,OH)<sub>2</sub> ||[[Chemistry:Monoclinic|Monoclinic]] ||1.595 ||1.640 ||1.640
|-
|mica, [[Chemistry:Muscovite|muscovite]] KAl<sub>2</sub>(AlSi<sub>3</sub>O<sub>10</sub>)(F,OH)<sub>2</sub> ||[[Chemistry:Monoclinic|Monoclinic]] ||1.563 ||1.596 ||1.601
|-
|[[Chemistry:Olivine|olivine]] (Mg,Fe)<sub>2</sub>SiO<sub>4</sub>||[[Chemistry:Orthorhombic|Orthorhombic]]||1.640 ||1.660 ||1.680
|-
|[[Chemistry:Perovskite|perovskite]] [[Chemistry:Calcium titanate|CaTiO<sub>3</sub>]] ||[[Chemistry:Orthorhombic|Orthorhombic]]||2.300 ||2.340 ||2.380
|-
|[[Chemistry:Topaz|topaz]] Al<sub>2</sub>SiO<sub>4</sub>(F,OH)<sub>2</sub> ||[[Chemistry:Orthorhombic|Orthorhombic]]||1.618 ||1.620 ||1.627
|-
|[[Chemistry:Ulexite|ulexite]] NaCaB<sub>5</sub>O<sub>6</sub>(OH)<sub>6</sub>·5H<sub>2</sub>O ||Triclinic||1.490 ||1.510 ||1.520
|}
{{col-end}}

== Measurement ==
Birefringence and other polarization-based optical effects (such as [[Physics:Optical rotation|optical rotation]] and linear or [[Physics:Circular dichroism|circular dichroism]]) can be observed by measuring any change in the polarization of light passing through the material. These measurements are known as [[Physics:Polarimetry|polarimetry]]. Polarized light microscopes, which contain two polarizers that are at 90° to each other on either side of the sample, are used to visualize birefringence, since light that has ''not'' been affected by birefringence remains in a polarization that is totally rejected by the second polarizer ("analyzer"). The addition of quarter-wave plates permits examination using circularly polarized light. Determination of the change in polarization state using such an apparatus is the basis of [[Physics:Ellipsometry|ellipsometry]], by which the optical properties of specular surfaces can be gauged through reflection.

Birefringence measurements have been made with phase-modulated systems for examining the transient flow behaviour of fluids.<ref>{{cite journal | title = A note on phase‐modulated flow birefringence: a promising rheo‐optical method| year = 1984| last1 = Frattini| first1 = P. L.| last2 = Fuller| first2 = G. G.| journal = Journal of Rheology| volume = 28| issue = 1| pages = 61–70| bibcode = 1984JRheo..28...61F| doi = 10.1122/1.549768}}</ref><ref>{{cite journal | title = Relaxation of dilute polymer solutions following extensional flow| year = 1998| last1 = Doyle| first1 = P. S.| last2 = Shaqfeh| first2 = E. S. G.| last3 = McKinley| first3 = G. H.| last4 = Spiegelberg| first4 = S. H.| journal = Journal of Non-Newtonian Fluid Mechanics| volume = 76| issue = 1–3| pages = 79–110| doi = 10.1016/S0377-0257(97)00113-4| doi-access = free}}</ref> Birefringence of lipid bilayers can be measured using [[Physics:Dual-polarization interferometry|dual-polarization interferometry]]. This provides a measure of the degree of order within these fluid layers and how this order is disrupted when the layer interacts with other biomolecules.
{{clear}}

For the '''3D measurement of birefringence''', a technique based on holographic tomography [https://doi.org/10.1038/s41563-022-01202-8] can be used.

== Applications ==
[[Image:LCD layers.svg|left|thumb|250px| Reflective twisted-nematic [[Engineering:Liquid-crystal display|liquid-crystal display]]. Light reflected by the surface (6) (or coming from a backlight) is horizontally polarized (5) and passes through the liquid-crystal modulator (3) sandwiched in between transparent layers (2, 4) containing electrodes. Horizontally polarized light is blocked by the vertically oriented polarizer (1), except where its polarization has been rotated by the liquid crystal (3), appearing bright to the viewer.]]
Birefringence is used in many optical devices. [[Engineering:Liquid-crystal display|Liquid-crystal display]]s, the most common sort of [[Flat-panel display|flat-panel display]], cause their pixels to become lighter or darker through rotation of the polarization (circular birefringence) of linearly polarized light as viewed through a sheet polarizer at the screen's surface. Similarly, [[Physics:Electro-optic modulator|light modulators]] modulate the intensity of light through [[Pockels effect|electrically induced birefringence]] of polarized light followed by a polarizer. The [[Physics:Lyot filter|Lyot filter]] is a specialized narrowband spectral filter employing the wavelength dependence of birefringence. [[Physics:Waveplate|Waveplate]]s are thin birefringent sheets widely used in certain optical equipment for modifying the polarization state of light passing through it.

Birefringence also plays an important role in [[Physics:Second-harmonic generation|second-harmonic generation]] and other [[Physics:Nonlinear optics|nonlinear optical components]], as the crystals used for this purpose are almost always birefringent. By adjusting the angle of incidence, the effective refractive index of the extraordinary ray can be tuned in order to achieve [[Physics:Nonlinear optics#Phase matching|phase matching]], which is required for the efficient operation of these devices.

===Medicine===
Birefringence is utilized in medical diagnostics. One powerful accessory used with optical microscopes is a pair of crossed [[Physics:Polarizer|polarizing]] filters. Light from the source is polarized in the {{mvar|x}} direction after passing through the first polarizer, but above the specimen is a polarizer (a so-called ''analyzer'') oriented in the {{mvar|y}} direction. Therefore, no light from the source will be accepted by the analyzer, and the field will appear dark. Areas of the sample possessing birefringence will generally couple some of the {{mvar|x}}-polarized light into the {{mvar|y}} polarization; these areas will then appear bright against the dark background. Modifications to this basic principle can differentiate between positive and negative birefringence.

{{multiple image
| direction = horizontal
| total_width = 300
| footer = Gout and pseudogout crystals viewed under a microscope with a red compensator, which slows red light in one orientation (labeled "polarized light axis").<ref name="Frances1983">{{cite journal | last=Frances Lixey | first=Mary | title=Inexpensive Compensator for a Polarizing Microscope | journal=Laboratory Medicine | publisher=Oxford University Press (OUP) | volume=14 | issue=6 | date=1983-06-01 | issn=0007-5027 | doi=10.1093/labmed/14.6.382 | pages=382}}</ref> Urate crystals ('''left''' image) in [[Medicine:Gout|gout]] appear yellow when their long axis is parallel to the slow transmission axis of the red compensator and appear blue when perpendicular.  The opposite colors are seen in [[Medicine:Calcium pyrophosphate dihydrate crystal deposition disease|calcium pyrophosphate dihydrate crystal deposition disease]] (pseudogout, '''right''' image): blue when parallel and yellow when perpendicular.
| image1 = Birefringence microscopy of gout, annotated.jpg
| image2 = Birefringence microscopy of pseudogout, annotated.jpg
| caption2 = 
}}

For instance, needle aspiration of fluid from a [[Medicine:Gout|gout]]y joint will reveal negatively birefringent monosodium urate crystals. [[Chemistry:Calcium pyrophosphate|Calcium pyrophosphate]] crystals, in contrast, show weak positive birefringence.<ref>{{cite journal |vauthors=Hardy RH, Nation B |title=Acute gout and the accident and emergency department |journal=Arch Emerg Med |volume=1 |issue=2 |pages=89–95 |date=June 1984 |pmid=6536274 |pmc=1285204 |doi= 10.1136/emj.1.2.89}}</ref> Urate crystals appear yellow, and calcium pyrophosphate crystals appear blue when their long axes are aligned parallel to that of a red compensator filter,<ref>[http://emedicine.medscape.com/article/336054-workup#a0721 The Approach to the Painful Joint Workup] Author: Alan N. Baer; Chief Editor: Herbert S. Diamond. Updated: Nov 22, 2010.</ref> or a crystal of known birefringence is added to the sample for comparison.

The birefringence of tissue inside a living human thigh was measured using polarization-sensitive optical coherence tomography at 1310&nbsp;nm and a single mode fiber in a needle. Skeletal muscle birefringence was Δn = 1.79 × 10<sup>−3</sup> ± 0.18×10<sup>−3</sup>, adipose Δn = 0.07 × 10<sup>−3</sup> ± 0.50 × 10<sup>−3</sup>, superficial aponeurosis Δn = 5.08 × 10<sup>−3</sup> ± 0.73 × 10<sup>−3</sup> and interstitial tissue Δn = 0.65 × 10<sup>−3</sup> ±0.39 × 10<sup>−3</sup>.<ref>{{Cite journal |last1=McBride |first1=Jeffrey M. |last2=Hackmann |first2=Michael J. |last3=Nimphius |first3=Sophia |last4=Cense |first4=Barry |date=2022 |title=In vivo PS-OCT needle probe scan of human skeletal muscle |url=https://doi.org/10.1364/BOE.446169 |journal=[[Medicine:Biomedical Optics Express|Biomedical Optics Express]] |volume=13 |issue=3 |pages=1386–1397 |doi=10.1364/BOE.446169 |pmid=35414965 |pmc=8973164 |via=Optica}}</ref> These measurements may be important for the development of a less invasive method to diagnose [[Medicine:Duchenne muscular dystrophy|Duchenne muscular dystrophy]].

Birefringence can be observed in [[Biology:Amyloid|amyloid]] plaques such as are found in the brains of [[Medicine:Alzheimer's disease|Alzheimer's]] patients when stained with a dye such as Congo Red. Modified proteins such as immunoglobulin light chains abnormally accumulate between cells, forming fibrils. Multiple folds of these fibers line up and take on a beta-pleated sheet [[Chemistry:Chemical structure|conformation]]. [[Chemistry:Congo red|Congo red]] dye [[Chemistry:Intercalation (biochemistry)|intercalates]] between the folds and, when observed under polarized light, causes birefringence.

In [[Medicine:Ophthalmology|ophthalmology]], binocular retinal birefringence screening of the ''Henle fibers'' (photoreceptor axons that go radially outward from the fovea) provides a reliable detection of [[Medicine:Strabismus|strabismus]] and possibly also of [[Medicine:Amblyopia#Refractive|anisometropic amblyopia]].<ref>{{cite journal|author1=Reed M. Jost|author2=Joost Felius|author3=Eileen E. Birch|title=High sensitivity of binocular retinal birefringence screening for anisometropic amblyopia without strabismus|journal=Journal of American Association for Pediatric Ophthalmology and Strabismus|volume=18|number=4|pages=e5–e6|date=August 2014|doi=10.1016/j.jaapos.2014.07.017}}</ref> In healthy subjects, the maximum retardation induced by the Henle fiber layer is approximately 22 degrees at 840&nbsp;nm.<ref>{{Cite journal|last1=Cense|first1=Barry|last2=Wang|first2=Qiang|last3=Lee|first3=Sangyeol|last4=Zhao|first4=Liang|last5=Elsner|first5=Ann E.|last6=Hitzenberger|first6=Christoph K.|last7=Miller|first7=Donald T.|date=2013-11-01|title=Henle fiber layer phase retardation measured with polarization-sensitive optical coherence tomography|url=https://www.osapublishing.org/boe/abstract.cfm?uri=boe-4-11-2296|journal=Biomedical Optics Express|language=EN|volume=4|issue=11|pages=2296–2306|doi=10.1364/BOE.4.002296 |pmid=24298395| pmc=3829392 |issn=2156-7085}}</ref> Furthermore, [[Medicine:Scanning laser polarimetry|scanning laser polarimetry]] uses the birefringence of the [[Biology:Optic nerve|optic nerve]] fiber layer to indirectly quantify its thickness, which is of use in the assessment and monitoring of [[Medicine:Glaucoma|glaucoma]]. Polarization-sensitive optical coherence tomography measurements obtained from healthy human subjects have demonstrated a change in birefringence of the retinal nerve fiber layer as a function of location around the optic nerve head.<ref>{{Cite journal|last1=Cense|first1=Barry|last2=Chen|first2=Teresa C.|last3=Park|first3=B. Hyle|last4=Pierce|first4=Mark C.|last5=Boer|first5=Johannes F. de|date=2004-08-01|title=Thickness and Birefringence of Healthy Retinal Nerve Fiber Layer Tissue Measured with Polarization-Sensitive Optical Coherence Tomography|url=https://iovs.arvojournals.org/article.aspx?articleid=2124143|journal=Investigative Ophthalmology & Visual Science|language=en|volume=45|issue=8|pages=2606–2612|doi=10.1167/iovs.03-1160|pmid=15277483|issn=1552-5783}}</ref> The same technology was recently applied in the living human retina to quantify the polarization properties of vessel walls near the optic nerve.<ref>{{Cite journal |last1=Afsharan |first1=Hadi |last2=Hackmann |first2=Michael J. |last3=Wang |first3=Qiang |last4=Navaeipour |first4=Farzaneh |last5=Jayasree |first5=Stephy Vijaya Kumar |last6=Zawadzki |first6=Robert J. |last7=Silva |first7=Dilusha |last8=Joo |first8=Chulmin |last9=Cense |first9=Barry |date=2021-07-01 |title=Polarization properties of retinal blood vessel walls measured with polarization sensitive optical coherence tomography |url=https://www.osapublishing.org/boe/abstract.cfm?uri=boe-12-7-4340 |journal=[[Medicine:Biomedical Optics Express|Biomedical Optics Express]] |language=EN |volume=12 |issue=7 |pages=4340–4362 |doi=10.1364/BOE.426079 |issn=2156-7085 |pmc=8367251 |pmid=34457418}}</ref> While retinal vessel walls become thicker and less birefringent in patients who suffer from hypertension,<ref>{{Cite journal |last1=Afsharan |first1=Hadi |last2=Anilkumar |first2=Vidyalakshmi |last3=Silva |first3=Dilusha |last4=Dwivedi |first4=Girish |last5=Joo |first5=Chulmin |last6=Cense |first6=Barry |date=2024-01-01 |title=Hypertension-associated changes in retinal blood vessel walls measured in vivo with polarization-sensitive optical coherence tomography |url=https://www.sciencedirect.com/science/article/pii/S0143816623003676 |journal=Optics and Lasers in Engineering |volume=172 |pages=107838 |doi=10.1016/j.optlaseng.2023.107838 |issn=0143-8166|doi-access=free }}</ref> hinting at a decrease in vessel wall condition, the vessel walls of diabetic patients do not experience a change in thickness, but do see an increase in birefringence,<ref>{{Cite journal |last1=Afsharan |first1=Hadi |last2=Silva |first2=Dilusha |last3=Joo |first3=Chulmin |last4=Cense |first4=Barry |date=August 2023 |title=Non-Invasive Retinal Blood Vessel Wall Measurements with Polarization-Sensitive Optical Coherence Tomography for Diabetes Assessment: A Quantitative Study |journal=Biomolecules |language=en |volume=13 |issue=8 |pages=1230 |doi=10.3390/biom13081230 |issn=2218-273X |pmc=10452597 |pmid=37627295 |doi-access=free }}</ref> presumably due to fibrosis or inflammation.

Birefringence characteristics in sperm heads allow the selection of spermatozoa for [[Medicine:Intracytoplasmic sperm injection|intracytoplasmic sperm injection]].<ref>{{cite journal |author=Gianaroli L. |author2=Magli M. C. |author3=Ferraretti A. P. |title=Birefringence characteristics in sperm heads allow for the selection of reacted spermatozoa for intracytoplasmic sperm injection |journal=Fertil. Steril. |volume= 93|issue= 3|pages= 807–813|date=December 2008 |pmid=19064263 |doi=10.1016/j.fertnstert.2008.10.024 |display-authors=0|doi-access=free }}</ref> Likewise, ''zona imaging'' uses birefringence on [[Biology:Oocyte|oocyte]]s to select the ones with highest chances of successful pregnancy.<ref>{{cite journal |author=Ebner T. |author2=Balaban B. |author3=Moser M. |title=Automatic user-independent zona pellucida imaging at the oocyte stage allows for the prediction of preimplantation development |journal=Fertil. Steril. |volume= 94|issue= 3|pages= 913–920|date=May 2009 |pmid=19439291 |doi=10.1016/j.fertnstert.2009.03.106 |display-authors=0|doi-access=free }}</ref> Birefringence of particles biopsied from pulmonary nodules indicates silicosis.

Dermatologists use dermatoscopes to view skin lesions. Dermoscopes use polarized light, allowing the user to view crystalline structures corresponding to dermal collagen in the skin. These structures may appear as shiny white lines or rosette shapes and are only visible under polarized dermoscopy.

===Stress-induced birefringence===
[[Image:Birefringence Stress Plastic.JPG|left|thumb|250px|Color pattern of a plastic box with "frozen in" mechanical stress placed between two crossed polarizers]]
Isotropic solids do not exhibit birefringence. When they are under mechanical stress, birefringence results. The stress can be applied externally or is "frozen in" after a birefringent plastic ware is cooled after it is manufactured using injection molding. When such a sample is placed between two crossed polarizers, colour patterns can be observed, because polarization of a light ray is rotated after passing through a birefringent material and the amount of rotation is dependent on wavelength. The experimental method called [[Physics:Photoelasticity|photoelasticity]] used for analyzing stress distribution in solids is based on the same principle. There has been recent research on using stress induced birefringence in a glass plate to generate an [[Physics:Optical vortex|Optical vortex]] and full Poincare beams (optical beams that have every possible polarization state across a cross-section).<ref>{{Cite journal|last1=Beckley|first1=Amber M.|last2=Brown|first2=Thomas G.|last3=Alonso|first3=Miguel A.|date=2010-05-10|title=Full Poincaré beams|url=https://www.osapublishing.org/abstract.cfm?uri=oe-18-10-10777|journal=Optics Express|language=EN|volume=18|issue=10|pages=10777–10785|doi=10.1364/OE.18.010777|pmid=20588931|issn=1094-4087|bibcode=2010OExpr..1810777B|doi-access=free}}</ref>

===Other cases of birefringence===

[[File:Rutile birefringence.gif|right|thumb|Birefringent rutile observed in different polarizations using a rotating polarizer (or ''analyzer'')]]
Birefringence is observed in anisotropic elastic materials. In these materials, the two polarizations split according to their effective refractive indices, which are also sensitive to stress.

The study of birefringence in shear waves traveling through the solid Earth (the Earth's liquid core does not support shear waves) is widely used in [[Earth:Seismology|seismology]]. {{citation needed|date=July 2020}}

Birefringence is widely used in mineralogy to identify rocks, minerals, and gemstones.{{citation needed|date=July 2020}}
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==Theory==
[[File:Birifrangence k-surface.gif|400px|thumb|right|Surface of the allowed '''k''' vectors for a fixed frequency for a biaxial crystal (see {{EquationNote|7|eq. 7}}).]]
In an isotropic medium (including free space) the so-called electric displacement ({{math|'''D'''}}) is just proportional to the electric field ({{math|'''E'''}}) according to {{math|'''D''' {{=}} ''ɛ'''''E'''}} where the material's [[Physics:Permittivity|permittivity]] {{math|''ε''}} is just a [[Physics:Scalar|scalar]] (and equal to {{math|''n''<sup>2</sup>''ε''<sub>0</sub>}} where {{math|''n''}} is the index of refraction). In an anisotropic material exhibiting birefringence, the relationship between {{math|'''D'''}} and {{math|'''E'''}} must now be described using a [[Tensor|tensor]] equation:

{{NumBlk|:|<math>\mathbf D = \boldsymbol\varepsilon \mathbf E </math>|{{EquationRef|1}}}}

where {{math|'''ε'''}} is now a 3&nbsp;×&nbsp;3 permittivity tensor. We assume linearity and no magnetic permeability in the medium: {{math|''μ'' {{=}} ''μ''<sub>0</sub>}}. The electric field of a plane wave of angular frequency {{math|''ω''}} can be written in the general form:

{{NumBlk|:|<math>\mathbf{E}=\mathbf{E}_0 e^{i(\mathbf{k} \cdot \mathbf{r}-\omega t)}</math>|{{EquationRef|2}}}}

where {{math|'''r'''}} is the position vector, {{math|''t''}} is time, and {{math|'''E'''<sub>0</sub>}} is a vector describing the electric field at {{math|'''r''' {{=}} 0}}, {{math|''t'' {{=}} 0}}. Then we shall find the possible [[Physics:Wave vector|wave vector]]s {{math|'''k'''}}. By combining [[Physics:Maxwell's equations|Maxwell's equations]] for {{math|∇ × '''E'''}} and {{math|∇ × '''H'''}}, we can eliminate {{math|'''H''' {{=}} {{sfrac|1|''μ''<sub>0</sub>}}'''B'''}} to obtain:

{{NumBlk|:|<math>-\nabla \times \nabla \times \mathbf{E}= \mu_0\frac{\partial^2 }{\partial t^2} \mathbf{D}</math> |{{EquationRef|3a}}}}

With no free charges, Maxwell's equation for the divergence of {{math|'''D'''}} vanishes:
{{NumBlk|:|<math>\nabla \cdot \mathbf{D}=0 </math>|{{EquationRef|3b}}}}

We can apply the vector identity {{math|[[Vector calculus identities#Curl of the curl|∇ × (∇ × '''A''') {{=}} ∇(∇ ⋅ '''A''') − ∇<sup>2</sup>'''A''']]}} to the left hand side of {{EquationNote|3a|eq. 3a}}, and use the spatial dependence in which each differentiation in {{math|''x''}} (for instance) results in multiplication by {{math|''ik<sub>x</sub>''}} to find:
{{NumBlk|:|<math> - \nabla \times \nabla \times \mathbf{E} =(\mathbf{k} \cdot \mathbf{E}) \mathbf{k} - (\mathbf{k} \cdot \mathbf{k}) \mathbf{E}</math>|{{EquationRef|3c}}}}

The right hand side of {{EquationNote|3a|eq. 3a}} can be expressed in terms of {{math|'''E'''}} through application of the permittivity tensor {{math|'''ε'''}} and noting that differentiation in time results in multiplication by {{math|−''iω''}}, {{EquationNote|3a|eq. 3a}} then becomes:
{{NumBlk|:|<math>(-\mathbf{k}\cdot\mathbf{k})\mathbf{E} + (\mathbf{k} \cdot \mathbf{E}) \mathbf{k}= -\mu_0 \omega^2 (\boldsymbol{\varepsilon} \mathbf{E})</math>|{{EquationRef|4a}}}}

Applying the differentiation rule to {{EquationNote|3b|eq. 3b}} we find:
{{NumBlk|:|<math>\mathbf{k} \cdot \mathbf{D} =0</math>|{{EquationRef|4b}}}}

{{EquationNote|4b|Eq. 4b}} indicates that {{math|'''D'''}} is orthogonal to the direction of the wavevector {{math|'''k'''}}, even though that is no longer generally true for {{math|'''E'''}} as would be the case in an isotropic medium. {{EquationNote|4b|Eq. 4b}} will not be needed for the further steps in the following derivation.

Finding the allowed values of {{math|'''k'''}} for a given {{math|''ω''}} is easiest done by using Cartesian coordinates with the {{math|''x''}}, {{math|''y''}} and {{math|''z''}} axes chosen in the directions of the symmetry axes of the crystal (or simply choosing {{math|''z''}} in the direction of the optic axis of a uniaxial crystal), resulting in a diagonal matrix for the permittivity tensor {{math|'''ε'''}}:
{{NumBlk|:|<math>\mathbf{\varepsilon}= \varepsilon_0 \begin{bmatrix} n_x^2 & 0 & 0 \\ 0& n_y^2 & 0 \\ 0& 0& n_z^2 \end{bmatrix} </math>|{{EquationRef|4c}}}}

where the diagonal values are squares of the refractive indices for polarizations along the three principal axes {{math|''x''}}, {{math|''y''}} and {{math|''z''}}. With {{math|'''ε'''}} in this form, and substituting in the speed of light {{math|''c''}} using {{math|''c''<sup>2</sup> {{=}} {{sfrac|1|''μ''<sub>0</sub>''ε''<sub>0</sub>}}}}, the {{math|''x''}} component of the vector equation {{EquationNote|4a|eq. 4a}} becomes
{{NumBlk|:|<math>\left(-k_x^2-k_y^2-k_z^2 \right)E_x + k_x^2 E_x + k_xk_yE_y + k_xk_zE_z = -\frac{\omega^2n_x^2}{c^2} E_x</math>|{{EquationRef|5a}}}}

where {{math|''E<sub>x</sub>''}}, {{math|''E<sub>y</sub>''}}, {{math|''E<sub>z</sub>''}} are the components of {{math|'''E'''}} (at any given position in space and time) and {{math|''k<sub>x</sub>''}}, {{math|''k<sub>y</sub>''}}, {{math|''k<sub>z</sub>''}} are the components of {{math|'''k'''}}. Rearranging, we can write (and similarly for the {{math|''y''}} and {{math|''z''}} components of {{EquationNote|4a|eq. 4a}})
{{NumBlk|:|<math>\left(-k_y^2-k_z^2+\frac{\omega^2n_x^2}{c^2}\right)E_x + k_xk_yE_y + k_xk_zE_z =0</math>|{{EquationRef|5b}}}}
{{NumBlk|:|<math>k_xk_yE_x + \left(-k_x^2-k_z^2+\frac{\omega^2n_y^2}{c^2}\right)E_y + k_yk_zE_z =0</math>|{{EquationRef|5c}}}}
{{NumBlk|:|<math>k_xk_zE_x + k_yk_zE_y + \left(-k_x^2-k_y^2+\frac{\omega^2n_z^2}{c^2}\right)E_z =0</math>|{{EquationRef|5d}}}}

This is a set of linear equations in {{math|''E<sub>x</sub>''}}, {{math|''E<sub>y</sub>''}}, {{math|''E<sub>z</sub>''}}, so it can have a nontrivial solution (that is, one other than {{math|'''E''' {{=}} 0}}) as long as the following [[Determinant|determinant]] is zero:
{{NumBlk|:|<math>\begin{vmatrix}
\left(-k_y^2-k_z^2+\frac{\omega^2n_x^2}{c^2}\right) & k_xk_y & k_xk_z \\
k_xk_y & \left(-k_x^2-k_z^2+\frac{\omega^2n_y^2}{c^2}\right) & k_yk_z \\
k_xk_z & k_yk_z & \left(-k_x^2-k_y^2+\frac{\omega^2n_z^2}{c^2}\right) \end{vmatrix} =0</math>|{{EquationRef|6}}}}

Evaluating the determinant of {{EquationNote|6|eq. 6}}, and rearranging the terms according to the powers of <math>\frac{\omega^2}{c^2}</math>, the constant terms cancel. After eliminating the common factor <math>\frac{\omega^2}{c^2}</math> from the remaining terms, we obtain

{{NumBlk|:|<math> \frac{\omega^4}{c^4} - \frac{\omega^2}{c^2}\left(\frac{k_x^2+k_y^2}{n_z^2}+\frac{k_x^2+k_z^2}{n_y^2}+\frac{k_y^2+k_z^2}{n_x^2}\right) + \left(\frac{k_x^2}{n_y^2n_z^2}+\frac{k_y^2}{n_x^2n_z^2}+\frac{k_z^2}{n_x^2n_y^2}\right)\left(k_x^2+k_y^2+k_z^2\right)=0 </math>|{{EquationRef|7}}}}
 
In the case of a uniaxial material, choosing the optic axis to be in the {{math|''z''}} direction so that {{math|''n<sub>x</sub>'' {{=}} ''n<sub>y</sub>'' {{=}} ''n''<sub>o</sub>}} and {{math|''n<sub>z</sub>'' {{=}} ''n''<sub>e</sub>}}, this expression can be factored into

{{NumBlk|:|<math>\left(\frac{k_x^2}{n_\mathrm{o}^2}+\frac{k_y^2}{n_\mathrm{o}^2}+\frac{k_z^2}{n_\mathrm{o}^2} -\frac{\omega^2}{c^2}\right)\left(\frac{k_x^2}{n_\mathrm{e}^2}+\frac{k_y^2}{n_\mathrm{e}^2}+\frac{k_z^2}{n_\mathrm{o}^2} -\frac{\omega^2}{c^2}\right)=0</math>|{{EquationRef|8}}}}

Setting either of the factors in {{EquationNote|8|eq. 8}} to zero will define an [[Ellipsoid|ellipsoid]]al surface<ref group=note>Although related, note that this is not the same as the [[Index ellipsoid|index ellipsoid]].</ref> in the space of wavevectors {{math|'''k'''}} that are allowed for a given {{math|''ω''}}. The first factor being zero defines a sphere; this is the solution for so-called ordinary rays, in which the effective refractive index is exactly {{math|''n''<sub>o</sub>}} regardless of the direction of {{math|'''k'''}}. The second defines a [[Spheroid|spheroid]] symmetric about the {{math|''z''}} axis. This solution corresponds to the so-called extraordinary rays in which the effective refractive index is in between {{math|''n''<sub>o</sub>}} and {{math|''n''<sub>e</sub>}}, depending on the direction of {{math|'''k'''}}. Therefore, for any arbitrary direction of propagation (other than in the direction of the optic axis), two distinct wavevectors {{math|'''k'''}} are allowed corresponding to the polarizations of the ordinary and extraordinary rays.

For a biaxial material a similar but more complicated condition on the two waves can be described;<ref>Born & Wolf, 2002, §15.3.3</ref> the locus of allowed {{math|'''k'''}} vectors (the ''wavevector surface'') is a 4th-degree two-sheeted surface, so that in a given direction there are generally two permitted {{math|'''k'''}} vectors (and their opposites).<ref name=berry-jeffrey-2007>M.V. Berry and M.R.&nbsp;Jeffrey, "Conical diffraction: Hamilton's diabolical point at the heart of crystal optics", in E.&nbsp;Wolf&nbsp;(ed.), ''Progress in Optics'', vol.{{nnbsp}}50, Amsterdam: Elsevier, 2007, {{nowrap|pp.{{tsp}}13–50}}, {{doi|10.1016/S0079-6638(07)50002-8}}, at {{nowrap|pp.{{tsp}}20–21}}.</ref> By inspection one can see that {{EquationNote|6|eq. 6}} is generally satisfied for two positive values of {{math|''ω''}}. Or, for a specified optical frequency {{math|''ω''}} and direction normal to the wavefronts {{math|{{sfrac|'''k'''|{{abs|'''k'''}}}}}}, it is satisfied for two wavenumbers (or propagation constants) {{math|{{abs|'''k'''}}}} (and thus effective refractive indices) corresponding to the propagation of two linear polarizations in that direction.

When those two propagation constants are equal then the effective refractive index is independent of polarization, and there is consequently no birefringence encountered by a wave traveling in that particular direction. For a uniaxial crystal, this is the optic axis, the ±''z'' direction according to the above construction. But when all three refractive indices (or permittivities), {{math|''n<sub>x</sub>''}}, {{math|''n<sub>y</sub>''}} and {{math|''n<sub>z</sub>''}} are distinct, it can be shown that there are exactly two such directions, where the two sheets of the wave-vector surface touch;{{r|berry-jeffrey-2007}} these directions are not at all obvious and do not lie along any of the three principal axes ({{math|''x''}}, {{math|''y''}}, {{math|''z''}} according to the above convention). Historically that accounts for the use of the term "biaxial" for such crystals, as the existence of exactly two such special directions (considered "axes") was discovered well before polarization and birefringence were understood physically. These two special directions are generally not of particular interest; biaxial crystals are rather specified by their three refractive indices corresponding to the three axes of symmetry.

A general state of polarization launched into the medium can always be decomposed into two waves, one in each of those two polarizations, which will then propagate with different wavenumbers {{math|{{abs|'''k'''}}}}. Applying the different phase of propagation to those two waves over a specified propagation distance will result in a generally ''different'' net polarization state at that point; this is the principle of the [[Physics:Waveplate|waveplate]] for instance. With a waveplate, there is no spatial displacement between the two rays as their {{math|'''k'''}}  vectors are still in the same direction. That is true when each of the two polarizations is either normal  to the optic axis (the ordinary ray) or parallel to it (the extraordinary ray).

In the more general case, there ''is'' a difference not only in the magnitude but the direction of the two rays. For instance, the photograph through a calcite crystal (top of page) shows a shifted image in the two polarizations; this is due to the optic axis being neither parallel nor normal to the crystal surface. And even when the optic axis ''is'' parallel to the surface, this will occur for waves launched at non-normal incidence (as depicted in the explanatory figure). In these cases the two {{math|'''k'''}} vectors can be found by solving {{EquationNote|6|eq. 6}} constrained by the boundary condition which requires that the components of the two transmitted waves' {{math|'''k'''}} vectors, and the {{math|'''k'''}} vector of the incident wave, as projected onto the surface of the interface, must all be identical. For a uniaxial crystal it will be found that there is ''not'' a spatial shift for the ordinary ray (hence its name) which will refract as if the material were non-birefringent with an index the same as the two axes which are not the optic axis. For a biaxial crystal neither ray is deemed "ordinary" nor would generally be refracted according to a refractive index equal to one of the principal axes.

== See also ==
{{Div col|small=yes}}
* [[Physics:Cotton–Mouton effect|Cotton–Mouton effect]]
* [[Physics:Crystal optics|Crystal optics]]
* [[Physics:Dichroism|Dichroism]]
* [[Physics:Iceland spar|Iceland spar]]
* [[Index ellipsoid]]
* [[Biography:John Kerr (physicist)|John Kerr]]
* [[Physics:Optical rotation|Optical rotation]]
* [[Physics:Periodic poling|Periodic poling]]
* [[Physics:Pleochroism|Pleochroism]]
{{Div col end}}

==Notes==
{{reflist|group=note}}

==References==
{{Reflist}}

==Bibliography==
* <span id="BW02"></span>M. Born and E. Wolf, 2002, ''[[Physics:Principles of Optics|Principles of Optics]]'', 7th&nbsp;Ed., Cambridge University Press, 1999 (reprinted with corrections, 2002).
* <span id="SecMem"></span>A. Fresnel, 1827, "Mémoire sur la double réfraction", ''Mémoires de l'Académie Royale des Sciences de l'Institut de France'', vol.{{nnbsp}}{{serif|VII}} (for 1824, printed 1827), [https://archive.org/details/mmoiresdelacad07memo/page/44 pp.{{nnbsp}}45–176]; reprinted as "Second mémoire..." in Fresnel, 1866–70, vol.&nbsp;2, [https://books.google.com/books?id=g6tzUG7JmoQC&pg=PA479 pp.{{nnbsp}}479–596]; translated by A.W.&nbsp;Hobson as [https://archive.org/details/scientificmemoir05memo/page/238 "Memoir on double refraction"], in R.{{nnbsp}}Taylor (ed.), ''Scientific Memoirs'', vol.{{nnbsp}}{{serif|V}} (London: Taylor & Francis, 1852), pp.{{nnbsp}}238–333. (Cited page numbers are from the translation.)
* <span id="OC2"></span>A. Fresnel (ed.{{tsp}} H. de Sénarmont, E.&nbsp;Verdet, and L.&nbsp;Fresnel), 1866–70, ''Oeuvres complètes d'Augustin Fresnel'' (3&nbsp;volumes), Paris: Imprimerie Impériale; [https://books.google.com/books?id=1l0_AAAAcAAJ vol.&nbsp;1&nbsp;(1866)], [https://books.google.com/books?id=g6tzUG7JmoQC vol.&nbsp;2&nbsp;(1868)], [https://archive.org/details/oeuvrescompltes01fresgoog vol.&nbsp;3&nbsp;(1870)].

==External links==
{{Commons}}
* [http://www.photostress.com Stress Analysis Apparatus (based on Birefringence theory)]{{Dead link|date=October 2023 |bot=InternetArchiveBot |fix-attempted=yes }}
* [https://web.archive.org/web/20020115202014/http://www.olympusmicro.com/primer/lightandcolor/birefringence.html]
* [https://www.youtube.com/watch?v=BEClYQbuG7U Video of stress birefringence in Polymethylmethacrylate (PMMA or Plexiglas).]
* [http://www.austine.com Artist Austine Wood Comarow employs birefringence to create kinetic figurative images.]
* {{cite web|last=Merrifield|first=Michael|title=Birefringence|url=http://www.sixtysymbols.com/videos/birefringence.htm|work=Sixty Symbols|publisher=[[Biography:Brady Haran|Brady Haran]] for the [[Organization:University of Nottingham|University of Nottingham]]}}
* [http://iowatom.weebly.com The Birefringence of Thin Ice (Tom Wagner, photographer)]


[[Category:Polarization (waves)]]
[[Category:Optical mineralogy]]

{{Sourceattribution|Birefringence}}