View source for Physics:Ceramic engineering

{{Short description|Science and technology of creating objects from inorganic, non-metallic materials}}
[[File:Stsheat.jpg|thumb|Simulation of the outside of the Space Shuttle as it heats up to over {{convert|1500|C}} during re-entry into the Earth's atmosphere]]
[[File:Si3N4bearings.jpg|thumb|Bearing components made from 100% [[Chemistry:Silicon nitride|silicon nitride]] Si<sub>3</sub>N<sub>4</sub>]]
[[File:Zayka-Ceramic-Knife.jpg|thumb|Ceramic bread knife]]

'''Ceramic engineering''' is the science and technology of creating objects from inorganic, non-metallic materials. This is done either by the action of heat, or at lower temperatures using precipitation reactions from high-purity chemical solutions. The term includes the purification of raw materials, the study and production of the chemical compounds concerned, their formation into components and the study of their structure, composition and properties.

Ceramic materials may have a crystalline or partly crystalline structure, with long-range order on atomic scale. [[Chemistry:Glass-ceramic|Glass-ceramic]]s may have an amorphous or glassy structure, with limited or short-range atomic order. They are either formed from a molten mass that solidifies on cooling, formed and matured by the action of heat, or chemically synthesized at low temperatures using, for example, [[Physics:Hydrothermal synthesis|hydrothermal]] or sol-gel synthesis.

The special character of ceramic materials gives rise to many applications in materials engineering, [[Electrical engineering|electrical engineering]], [[Chemistry:Chemical engineering|chemical engineering]] and [[Engineering:Mechanical engineering|mechanical engineering]]. As ceramics are heat resistant, they can be used for many tasks for which materials like metal and [[Chemistry:Polymer|polymer]]s are unsuitable. Ceramic materials are used in a wide range of industries, including mining, aerospace, medicine, refinery, food and chemical industries, packaging science, electronics, industrial and transmission electricity, and guided lightwave transmission.<ref name="KBU">Kingery, W.D., Bowen, H.K., and Uhlmann, D.R., ''Introduction to Ceramics'', p. 690 (Wiley-Interscience, 2nd Edition, 2006)</ref>

== History ==

The word "ceramic" is derived from the [[Social:Ancient Greek|Greek]] word {{lang|grc|κεραμικός}} ({{transliteration|grc|keramikos}}) meaning pottery. It is related to the older Indo-European language root "to burn".<ref name=hippel>{{cite book|author1=von Hippel |author2=A. R. | chapter= Ceramics| title = Dielectric Materials and Applications| publisher = Technology Press (M.I.T.) and John Wiley & Sons| year = 1954| isbn = 978-1-58053-123-8}}</ref> "Ceramic" may be used as a noun in the singular to refer to a ceramic material or the product of ceramic manufacture, or as an adjective. Ceramics is the making of things out of ceramic materials. Ceramic engineering, like many sciences, evolved from a different discipline by today's standards. Materials science engineering is grouped with ceramics engineering to this day.{{citation needed|date=November 2020}}

[[File:Sabbiatrice.jpg|thumb|Leo Morandi's tile glazing line (circa 1945)]]

Abraham Darby first used [[Chemistry:Coke (fuel)|coke]] in 1709 in Shropshire, England, to improve the yield of a smelting process.{{citation needed|date=November 2020}} Coke is now widely used to produce carbide ceramics. Potter Josiah Wedgwood opened the first modern ceramics factory in Stoke-on-Trent, England, in 1759. Austrian chemist Carl Josef Bayer, working for the textile industry in Russia, developed a [[Chemistry:Bayer process|process]] to separate alumina from [[Earth:Bauxite|bauxite]] ore in 1888. The Bayer process is still used to purify alumina for the ceramic and aluminium industries.{{citation needed|date=November 2020}} Brothers Pierre and Jacques [[Biography:Pierre Curie|Curie]] discovered [[Physics:Piezoelectricity|piezoelectricity]] in Rochelle salt {{circa|1880}}. Piezoelectricity is one of the key properties of [[Physics:Electroceramics|electroceramics]].

E.G. Acheson heated a mixture of coke and [[Earth:Clay|clay]] in 1893, and invented carborundum, or synthetic [[Chemistry:Silicon carbide|silicon carbide]]. [[Biography:Henri Moissan|Henri Moissan]] also synthesized SiC and [[Chemistry:Tungsten carbide|tungsten carbide]] in his [[Physics:Electric arc furnace|electric arc furnace]] in Paris about the same time as Acheson. Karl Schröter used liquid-phase [[Earth:Sintering|sintering]] to bond or "cement" Moissan's tungsten carbide particles with cobalt in 1923 in Germany. Cemented (metal-bonded) [[Chemistry:Carbide|carbide]] edges greatly increase the durability of hardened steel cutting tools. [[Biography:Walther Nernst|W.H. Nernst]] developed [[Chemistry:Cubic zirconia|cubic-stabilized zirconia]] in the 1920s in Berlin. This material is used as an oxygen sensor in exhaust systems. The main limitation on the use of ceramics in engineering is brittleness.<ref name="KBU" />

=== Military ===

[[File:Nightvision.jpg|thumb|Soldiers pictured during the 2003 Iraq War seen through IR transparent Night Vision Goggles]]

The military requirements of [[Social:World War II|World War II]] encouraged developments, which created a need for high-performance materials and helped speed the development of ceramic science and engineering. Throughout the 1960s and 1970s, new types of ceramics were developed in response to advances in atomic energy, electronics, communications, and space travel. The discovery of ceramic superconductors in 1986 has spurred intense research to develop superconducting ceramic parts for electronic devices, electric motors, and transportation equipment.{{citation needed|date=November 2020}}

There is an increasing need in the military sector for high-strength, robust materials which have the capability to transmit light around the visible (0.4–0.7 micrometers) and mid-infrared (1–5 micrometers) regions of the spectrum. These materials are needed for applications requiring transparent armour. Transparent armour is a material or system of materials designed to be optically transparent, yet protect from fragmentation or ballistic impacts. The primary requirement for a transparent armour system is to not only defeat the designated threat but also provide a multi-hit capability with minimized distortion of surrounding areas. Transparent armour windows must also be compatible with night vision equipment. New materials that are thinner, lightweight, and offer better ballistic performance are being sought.<ref>{{cite book|doi=10.1117/12.405270|title=Proceedings of SPIE|chapter=Transparent ceramics for armour and EM window applications|year=2000|last1=Patel|first1=Parimal J.|editor-first1=Alexander J. |editor-first2=Eugene G. |editor-last1=Marker Iii |editor-last2=Arthurs |volume=4102|pages=1–14|series=Inorganic Optical Materials II|s2cid=136568127|chapter-url=https://zenodo.org/record/1235592}}</ref>

Such solid-state components have found widespread use for various applications in the electro-optical field including: optical fibres for guided lightwave transmission, optical switches, laser amplifiers and [[Physics:Lens (optics)|lenses]], hosts for solid-state lasers and optical window materials for gas lasers, and [[Physics:Infrared homing|infrared (IR) heat seeking devices]] for [[Engineering:Missile guidance|missile guidance]] systems and IR night vision.<ref name="SPIE">Harris, D.C., "Materials for Infrared Windows and Domes: Properties and Performance", SPIE PRESS Monograph, Vol. PM70 (Int. Society of Optical Engineers, Bellingham WA, 2009) {{ISBN|978-0-8194-5978-7}}</ref>

== Modern industry ==

Now a multibillion-dollar a year industry, ceramic engineering and research has established itself as an important field of science. Applications continue to expand as researchers develop new kinds of ceramics to serve different purposes.<ref name="KBU" /><ref name="MOD">Richerson, D.W., ''Modern Ceramic Engineering'', 2nd Ed., (Marcel Dekker Inc., 1992) {{ISBN|0-8247-8634-3}}.</ref>

*[[Chemistry:Zirconium dioxide|Zirconium dioxide]] ceramics are used in the manufacture of knives. The blade of the [[Engineering:Ceramic knife|ceramic knife]] will stay sharp for much longer than that of a steel knife, although it is more brittle and can be snapped by dropping it on a hard surface.
*Ceramics such as alumina, [[Chemistry:Boron carbide|boron carbide]] and silicon carbide have been used in [[Physics:Bulletproof vest|bulletproof vest]]s to repel small arms [[Engineering:Rifle|rifle]] fire. Such plates are known commonly as [[Engineering:Ballistic plate|ballistic plate]]s. Similar material is used to protect cockpits of some military aircraft, because of the low weight of the material.
*[[Chemistry:Silicon nitride|Silicon nitride]] parts are used in ceramic ball bearings. Their higher hardness means that they are much less susceptible to wear and can offer more than triple lifetimes. They also deform less under load meaning they have less contact with the bearing retainer walls and can roll faster. In very high speed applications, heat from friction during rolling can cause problems for metal bearings; problems which are reduced by the use of ceramics. Ceramics are also more chemically resistant and can be used in wet environments where steel bearings would rust. The major drawback to using ceramics is a significantly higher cost. In many cases their electrically insulating properties may also be valuable in bearings.{{Citation needed|date=November 2013}}
*In the early 1980s, [[Company:Toyota|Toyota]] researched production of an [[Physics:Adiabatic|adiabatic]] ceramic engine which can run at a temperature of over 6000&nbsp;°F (3300&nbsp;°C). Ceramic engines do not require a cooling system and hence allow a major weight reduction and therefore greater fuel efficiency. [[Physics:Fuel efficiency|Fuel efficiency]] of the engine is also higher at high temperature, as shown by [[Physics:Carnot heat engine|Carnot's]] theorem. In a conventional metallic engine, much of the energy released from the fuel must be dissipated as [[Astronomy:Waste heat|waste heat]] in order to prevent a meltdown of the metallic parts. Despite all of these desirable properties, such engines are not in production because the manufacturing of ceramic parts in the requisite precision and durability is difficult. Imperfection in the ceramic leads to cracks, which can lead to potentially dangerous equipment failure. Such engines are possible in laboratory settings, but mass-production is not feasible with current technology.{{Citation needed|date=December 2010}}
*Work is being done in developing ceramic parts for [[Engineering:Gas turbine|gas turbine]] [[Physics:Heat engine|engines]]. Currently, even blades made of [[Chemistry:Superalloy|advanced metal alloys]] used in the engines' hot section require cooling and careful limiting of operating temperatures. Turbine engines made with ceramics could operate more efficiently, giving aircraft greater range and payload for a set amount of fuel.{{Citation needed|date=December 2010}}

[[File:Woven bone matrix.jpg|thumb|[[Biology:Collagen|Collagen]] fibers of woven bone]]
[[File:Bertazzo S - SEM deproteined bone - wistar rat - x10k.tif|thumb|Scanning electron microscopy image of bone]]

*Recently, there have been advances in ceramics which include bio-ceramics, such as dental implants and synthetic bones. [[Chemistry:Hydroxyapatite|Hydroxyapatite]], the natural mineral component of bone, has been made synthetically from a number of biological and chemical sources and can be formed into ceramic materials. Orthopedic implants made from these materials bond readily to bone and other tissues in the body without rejection or inflammatory reactions. Because of this, they are of great interest for gene delivery and [[Engineering:Tissue engineering|tissue engineering]] scaffolds. Most hydroxyapatite ceramics are very porous and lack mechanical strength and are used to coat metal orthopedic devices to aid in forming a bond to bone or as bone fillers. They are also used as fillers for orthopedic plastic screws to aid in reducing the inflammation and increase absorption of these plastic materials. Work is being done to make strong, fully dense nano crystalline hydroxyapatite ceramic materials for orthopedic weight bearing devices, replacing foreign metal and plastic orthopedic materials with a synthetic, but naturally occurring, bone mineral. Ultimately these ceramic materials may be used as bone replacements or with the incorporation of protein collagens, synthetic bones.{{Citation needed|date=December 2010}}
*Durable actinide-containing ceramic materials have many applications such as in nuclear fuels for burning excess Pu and in chemically-inert sources of alpha irradiation for power supply of unmanned space vehicles or to produce electricity for microelectronic devices. Both use and disposal of radioactive actinides require their immobilization in a durable host material. Nuclear waste long-lived radionuclides such as actinides are immobilized using chemically-durable crystalline materials based on polycrystalline ceramics and large single crystals.<ref>B.E. Burakov, M.I Ojovan, W.E. Lee. Crystalline Materials for Actinide Immobilisation, Imperial College Press, London, 198 pp. (2010).
http://www.worldscientific.com/worldscibooks/10.1142/p652.</ref>

== Glass-ceramics ==
[[File:Ceranfeld.jpg|thumb|A high strength glass-ceramic cook-top with negligible thermal expansion.]]

Glass-ceramic materials share many properties with both glasses and ceramics. Glass-ceramics have an amorphous phase and one or more crystalline phases and are produced by a so-called "controlled crystallization", which is typically avoided in glass manufacturing. Glass-ceramics often contain a crystalline phase which constitutes anywhere from 30% [m/m] to 90% [m/m] of its composition by volume, yielding an array of materials with interesting thermomechanical properties.<ref name="MOD" />

In the processing of glass-ceramics, molten glass is cooled down gradually before reheating and annealing. In this heat treatment the glass partly crystallizes. In many cases, so-called 'nucleation agents' are added in order to regulate and control the crystallization process. Because there is usually no pressing and sintering, glass-ceramics do not contain the volume fraction of porosity typically present in sintered ceramics.<ref name="KBU" />

The term mainly refers to a mix of lithium and [[Chemistry:Aluminosilicate|aluminosilicate]]s which yields an array of materials with interesting thermomechanical properties. The most commercially important of these have the distinction of being impervious to thermal shock. Thus, glass-ceramics have become extremely useful for countertop cooking. The negative [[Physics:Thermal expansion|thermal expansion]] coefficient (TEC) of the crystalline ceramic phase can be balanced with the positive TEC of the glassy phase. At a certain point (~70% crystalline) the glass-ceramic has a net TEC near zero. This type of [[Chemistry:Glass-ceramic|glass-ceramic]] exhibits excellent mechanical properties and can sustain repeated and quick temperature changes up to 1000&nbsp;°C.<ref name="KBU" /><ref name="MOD" />

==Processing steps==

The traditional ceramic process generally follows this sequence: Milling → Batching → Mixing → Forming → Drying → Firing → Assembly.<ref name="A"/><ref>
{{cite book |first=C.J. |last=Brinker |author2=Scherer, G.W. |title=Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing |publisher=Academic Press |year=1990 |isbn=978-0-12-134970-7}}</ref>
<ref name="Z">{{cite journal
|first=L.L. |last=Hench
|author2=West, J.K. 
|title=The Sol-Gel Process
|journal=Chemical Reviews
|volume=90
|page=33
|year=1990
 |doi=10.1021/cr00099a003}}
</ref><ref>
{{cite book |first=L. |last=Klein |title=Sol-Gel Optics: Processing and Applications |publisher=Springer Verlag |year=1994|url=https://books.google.com/books?id=wH11Y4UuJNQC|isbn=978-0-7923-9424-2}}
</ref>

[[File:Ball mill.gif|thumb|[[Engineering:Ball mill|Ball mill]]]]

*'''Milling''' is the process by which materials are reduced from a large size to a smaller size. Milling may involve breaking up cemented material (in which case individual particles retain their shape) or pulverization (which involves grinding the particles themselves to a smaller size). Milling is generally done by mechanical means, including ''attrition'' (which is particle-to-particle collision that results in agglomerate break up or particle shearing), ''compression'' (which applies a forces that results in fracturing), and ''impact'' (which employs a milling medium or the particles themselves to cause fracturing). Attrition milling equipment includes the wet scrubber (also called the planetary mill or wet attrition mill), which has paddles in water creating vortexes in which the material collides and break up. Compression mills include the jaw [[Engineering:Crusher|crusher]], roller crusher and cone crusher. Impact mills include the [[Engineering:Ball mill|ball mill]], which has media that tumble and fracture the material. Shaft impactors cause particle-to particle attrition and compression.
*'''Batching''' is the process of weighing the oxides according to recipes, and preparing them for mixing and drying.
*'''Mixing''' occurs after batching and is performed with various machines, such as dry mixing ribbon mixers (a type of cement mixer), Mueller mixers,{{Clarify|date=December 2010}} and pug mills. Wet mixing generally involves the same equipment.
*'''Forming''' is making the mixed material into shapes, ranging from toilet bowls to spark plug insulators. Forming can involve: (1) Extrusion, such as extruding "slugs" to make bricks, (2) Pressing to make shaped parts, (3) Slip casting, as in making toilet bowls, wash basins and ornamentals like ceramic statues. Forming produces a "green" part, ready for drying. Green parts are soft, pliable, and over time will lose shape. Handling the green product will change its shape. For example, a green brick can be "squeezed", and after squeezing it will stay that way.
*'''Drying''' is removing the water or binder from the formed material. [[Engineering:Spray drying|Spray drying]] is widely used to prepare powder for pressing operations. Other dryers are tunnel dryers and periodic dryers. Controlled heat is applied in this two-stage process. First, heat removes water. This step needs careful control, as rapid heating causes cracks and surface defects. The dried part is smaller than the green part, and is brittle, necessitating careful handling, since a small impact will cause crumbling and breaking.
*'''Sintering''' is where the dried parts pass through a controlled heating process, and the oxides are chemically changed to cause bonding and densification. The fired part will be smaller than the dried part.

==Forming methods==

[[Chemistry:Ceramic forming techniques|Ceramic forming techniques]] include throwing, slipcasting, tape casting, [[Earth:Freeze-casting|freeze-casting]], injection molding, dry pressing, isostatic pressing, hot isostatic pressing (HIP), 3D printing and others. Methods for forming ceramic powders into complex shapes are desirable in many areas of technology. Such methods are required for producing advanced, high-temperature structural parts such as heat engine components and turbines. Materials other than ceramics which are used in these processes may include: wood, metal, water, plaster and epoxy—most of which will be eliminated upon firing.<ref name="A"/> A '''ceramic-filled epoxy'''<!-- bolded per WP:MOSBOLD as a redirect target -->, such as Martyte, is sometimes used to protect structural steel under conditions of rocket exhaust impingement.<ref name=nasa200901>[https://ntrs.nasa.gov/citations/20130014277 Refractory Materials for Flame Deflector Protection System Corrosion Control: Similar Industries and/or Launch Facilities Survey], NASA/TM-2013-217910, January 2009, accessed 17 November 2020.</ref>

These forming techniques are well known for providing tools and other components with dimensional stability, surface quality, high (near theoretical) density and microstructural uniformity. The increasing use and diversity of specialty forms of ceramics adds to the diversity of process technologies to be used.<ref name="A"/>

Thus, reinforcing fibers and filaments are mainly made by polymer, sol-gel, or CVD processes, but melt processing also has applicability. The most widely used specialty form is layered structures, with tape casting for electronic substrates and packages being pre-eminent. Photo-lithography is of increasing interest for precise patterning of conductors and other components for such packaging. Tape casting or forming processes are also of increasing interest for other applications, ranging from open structures such as fuel cells to ceramic composites.<ref name="A"/>

The other major layer structure is coating, where melt spraying is very important, but chemical and physical vapor deposition and chemical (e.g., sol-gel and polymer pyrolysis) methods are all seeing increased use. Besides open structures from formed tape, extruded structures, such as honeycomb catalyst supports, and highly porous structures, including various foams, for example, [[Physics:Reticulated foam|reticulated foam]], are of increasing use.<ref name="A"/>

Densification of consolidated powder bodies continues to be achieved predominantly by (pleasureless) sintering. However, the use of pressure sintering by hot pressing is increasing, especially for non-oxides and parts of simple shapes where higher quality (mainly microstructural homogeneity) is needed, and larger size or multiple parts per pressing can be an advantage.<ref name="A"/>

== The sintering process ==


The principles of sintering-based methods are simple ("sinter" has roots in the English "cinder"). The firing is done at a temperature below the melting point of the ceramic. Once a roughly-held-together object called a "green body" is made, it is fired in a kiln, where atomic and molecular [[Physics:Diffusion|diffusion]] processes give rise to significant changes in the primary microstructural features. This includes the gradual elimination of [[Earth:Porosity|porosity]], which is typically accompanied by a net shrinkage and overall densification of the component. Thus, the pores in the object may close up, resulting in a denser product of significantly greater [[Physics:Strength of materials|strength]] and [[Engineering:Fracture toughness|fracture toughness]].

Another major change in the body during the firing or sintering process will be the establishment of the polycrystalline nature of the solid. Significant grain growth tends to occur during sintering, with this growth depending on temperature and duration of the sintering process. The growth of grains will result in some form of grain size distribution, which will have a significant impact on the ultimate physical properties of the material. In particular, [[Physics:Abnormal grain growth|abnormal grain growth]] in which certain grains grow very large in a matrix of finer grains will significantly alter the physical and mechanical properties of the obtained ceramic. In the sintered body, grain sizes are a product of the thermal processing parameters as well as the initial [[Chemistry:Particle size|particle size]], or possibly the sizes of aggregates or particle [[Physics:Cluster|cluster]]s which arise during the initial stages of processing.

The ultimate [[Physics:Microstructure|microstructure]] (and thus the physical properties) of the final product will be limited by and subject to the form of the structural template or precursor which is created in the initial stages of [[Chemistry:Chemical synthesis|chemical synthesis]] and physical forming. Hence the importance of chemical powder and [[Chemistry:Polymer|polymer]] [[Chemistry:Chemical process|processing]] as it pertains to the synthesis of industrial ceramics, glasses and glass-ceramics.

There are numerous possible refinements of the sintering process. Some of the most common involve pressing the green body to give the densification a head start and reduce the sintering time needed. Sometimes organic [[Chemistry:Binder (material)|binders]] such as [[Chemistry:Polyvinyl alcohol|polyvinyl alcohol]] are added to hold the green body together; these burn out during the firing (at 200–350&nbsp;°C). Sometimes organic lubricants are added during pressing to increase densification. It is common to combine these, and add binders and lubricants to a powder, then press. (The formulation of these organic chemical additives is an art in itself. This is particularly important in the manufacture of high performance ceramics such as those used by the billions for [[Engineering:Electronics|electronics]], in capacitors, [[Engineering:Inductor|inductor]]s, [[Engineering:Sensor|sensor]]s, etc.)

A slurry can be used in place of a powder, and then cast into a desired shape, dried and then sintered. Indeed, traditional pottery is done with this type of method, using a plastic mixture worked with the hands. If a mixture of different materials is used together in a ceramic, the sintering temperature is sometimes above the melting point of one minor component – a ''liquid phase'' sintering. This results in shorter sintering times compared to solid state sintering.<ref>Rahaman, M.N., ''Ceramic Processing and Sintering'', 2nd Ed. (Marcel Dekker Inc., 2003) {{ISBN|0-8247-0988-8}}</ref> Such liquid phase sintering involves in faster diffusion processes and may result in [[Physics:Abnormal grain growth|abnormal grain growth]].

==Strength of ceramics==
A material's strength is dependent on its microstructure. The engineering processes to which a material is subjected can alter its microstructure. The variety of strengthening mechanisms that alter the strength of a material include the mechanism of [[Engineering:Grain boundary strengthening|grain boundary strengthening]]. Thus, although yield strength is maximized with decreasing grain size, ultimately, very small grain sizes make the material brittle. Considered in tandem with the fact that the yield strength is the parameter that predicts plastic deformation in the material, one can make informed decisions on how to increase the strength of a material depending on its microstructural properties and the desired end effect.

The relation between yield stress and grain size is described mathematically by the Hall-Petch equation which is
:<math>\sigma_y = \sigma_0 + {k_y \over \sqrt {d}}</math>
where ''k<sub>y</sub>'' is the strengthening coefficient (a constant unique to each material), ''σ<sub>o</sub>'' is a materials constant for the starting stress for dislocation movement (or the resistance of the lattice to dislocation motion), ''d'' is the grain diameter, and ''σ<sub>y</sub>'' is the yield stress.

Theoretically, a material could be made infinitely strong if the grains are made infinitely small. This is, unfortunately, impossible because the lower limit of grain size is a single [[Unit cell|unit cell]] of the material. Even then, if the grains of a material are the size of a single unit cell, then the material is in fact amorphous, not crystalline, since there is no long range order, and dislocations can not be defined in an amorphous material. It has been observed experimentally that the microstructure with the highest yield strength is a grain size of about 10 nanometers, because grains smaller than this undergo another yielding mechanism, grain boundary sliding.<ref name="Grain boundary sliding">{{cite journal |last= Schuh|first=Christopher|author2=Nieh, T.G. |year=2002|doi=10.1557/PROC-740-I1.8|title=Hardness and Abrasion Resistance of Nanocrystalline Nickel Alloys Near the Hall-Petch Breakdown Regime|url=http://apps.dtic.mil/dtic/tr/fulltext/u2/p014240.pdf |archive-url=https://web.archive.org/web/20121202130945/http://www.dtic.mil/dtic/tr/fulltext/u2/p014240.pdf |url-status=live |archive-date=2 December 2012 |journal=Mater. Res. Soc. Symp. Proc. |volume=740}}</ref> Producing engineering materials with this ideal grain size is difficult because of the limitations of initial particle sizes inherent to [[Physics:Nanomaterials|nanomaterials]] and nanotechnology.

== Faber-Evans model ==
{{main|Physics:Faber-Evans model}}

The [[Physics:Faber-Evans model|Faber-Evans model]], developed by Katherine Faber and Anthony G. Evans, was developed to predict the increase in fracture toughness in ceramics due to crack deflection around second-phase particles that are prone to microcracking in a matrix.<ref>{{Cite journal |last1=Evans |first1=A. G. |last2=Faber |first2=K. T. |date=1981 |title=Toughening of Ceramics by Circumferential Microcracking |url=https://onlinelibrary.wiley.com/doi/10.1111/j.1151-2916.1981.tb09877.x |journal=Journal of the American Ceramic Society |language=en |volume=64 |issue=7 |pages=394–398 |doi=10.1111/j.1151-2916.1981.tb09877.x |issn=0002-7820}}</ref> The model considers particle morphology, aspect ratio, spacing, and volume fraction of the second phase, as well as the reduction in local stress intensity at the crack tip when the crack is deflected or the crack plane bows. Actual crack tortuosity is obtained through imaging techniques, which allows for the direct input of deflection and bowing angles into the model.

The model calculates the average strain energy release rate and compares the resulting increase in fracture toughness to that of a flat crack through the plain matrix. The magnitude of the toughening is determined by the mismatch strain caused by thermal contraction incompatibility and the microfracture resistance of the particle/matrix interface. The toughening becomes noticeable with a narrow size distribution of appropriately sized particles, and researchers typically accept that deflection effects in materials with roughly equiaxial grains may increase the fracture toughness by about twice the grain boundary value.<ref>{{Cite journal |last1=Faber |first1=K. T. |last2=Evans |first2=A. G. |date=1983-04-01 |title=Crack deflection processes—I. Theory |url=https://dx.doi.org/10.1016/0001-6160%2883%2990046-9 |journal=Acta Metallurgica |language=en |volume=31 |issue=4 |pages=565–576 |doi=10.1016/0001-6160(83)90046-9 |issn=0001-6160}}</ref>

The model reveals that the increase in toughness is dependent on particle shape and the volume fraction of the second phase, with the most effective morphology being the rod of high aspect ratio, which can account for a fourfold increase in fracture toughness. The toughening arises primarily from the twist of the crack front between particles, as indicated by deflection profiles. Disc-shaped particles and spheres are less effective in toughening. Fracture toughness, regardless of morphology, is determined by the twist of the crack front at its most severe configuration, rather than the initial tilt of the crack front. Only for disc-shaped particles does the initial tilting of the crack front provide significant toughening; however, the twist component still overrides the tilt-derived toughening.<ref>{{Cite journal |last1=Faber |first1=K.T. |last2=Evans |first2=Anthony G. |date=1983 |title=Intergranular Crack-Deflection Toughening in Silicon Carbide |url=http://dx.doi.org/10.1111/j.1151-2916.1983.tb10084.x |journal=Journal of the American Ceramic Society |volume=66 |issue=6 |pages=C–94-C-95 |doi=10.1111/j.1151-2916.1983.tb10084.x |issn=0002-7820}}</ref>

Additional important features of the deflection analysis include the appearance of asymptotic toughening for the three morphologies at volume fractions in excess of 0.2. It is also noted that a significant influence on the toughening by spherical particles is exerted by the interparticle spacing distribution; greater toughening is afforded when spheres are nearly contacting such that twist angles approach π/2. These predictions provide the basis for the design of high-toughness two-phase ceramic materials.

The ideal second phase, in addition to maintaining chemical compatibility, should be present in amounts of 10 to 20 volume percent. Greater amounts may diminish the toughness increase due to overlapping particles. Particles with high aspect ratios, especially those with rod-shaped morphologies, are most suitable for maximum toughening. This model is often used to determine the factors that contribute to the increase in fracture toughness in ceramics which is ultimately useful in the development of advanced ceramic materials with improved performance.<ref>{{Cite journal |last1=Liu |first1=Haiyan |last2=Weisskopf |first2=Karl-L. |last3=Petzow |first3=Gunter |date=1989 |title=Crack Deflection Process for Hot-Pressed Whisker-Reinforced Ceramic Composites |url=https://onlinelibrary.wiley.com/doi/10.1111/j.1151-2916.1989.tb06175.x |journal=Journal of the American Ceramic Society |language=en |volume=72 |issue=4 |pages=559–563 |doi=10.1111/j.1151-2916.1989.tb06175.x |issn=0002-7820}}</ref><ref>{{Cite journal |last1=Carter |first1=David H. |last2=Hurley |first2=George F. |date=1987 |title=Crack Deflection as a Toughening Mechanism in SiC-Whisker-Reinforced MoSi2 |url=https://onlinelibrary.wiley.com/doi/10.1111/j.1151-2916.1987.tb04992.x |journal=Journal of the American Ceramic Society |language=en |volume=70 |issue=4 |pages=C–79–C-81 |doi=10.1111/j.1151-2916.1987.tb04992.x |issn=0002-7820}}</ref>

==Theory of chemical processing==

===Microstructural uniformity===
In the processing of fine ceramics, the irregular particle sizes and shapes in a typical powder often lead to non-uniform packing morphologies that result in packing [[Physics:Density|density]] variations in the powder compact. Uncontrolled [[Chemistry:Flocculation|agglomeration]] of powders due to attractive [[Physics:Van der Waals forces|van der Waals forces]] can also give rise to in microstructural inhomogeneities.<ref name="A">{{cite book
|editor1=Onoda, G.Y. Jr. |editor2=Hench, L.L. |title= Ceramic Processing Before Firing|publisher=Wiley & Sons|place=New York
|year=1979
}}</ref><ref name="B">{{cite journal
|author=Aksay, I.A., Lange, F.F., Davis, B.I.
|title=Uniformity of Al<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Composites by Colloidal Filtration
|journal=J. Am. Ceram. Soc.
|volume=66
|page=C–190
|year=1983
|doi=10.1111/j.1151-2916.1983.tb10550.x
|issue=10
|last2=Lange
|last3=Davis
}}</ref>

Differential stresses that develop as a result of non-uniform drying shrinkage are directly related to the rate at which the [[Physics:Solvent|solvent]] can be removed, and thus highly dependent upon the distribution of porosity. Such stresses have been associated with a plastic-to-brittle transition in consolidated bodies,<ref name="C">{{cite journal
|author1=Franks, G.V.  |author2=Lange, F.F.
|title=Plastic-to-Brittle Transition of Saturated, Alumina Powder Compacts
|journal=J. Am. Ceram. Soc.
|volume=79
|page=3161
|year=1996
|doi=10.1111/j.1151-2916.1996.tb08091.x
|issue=12
}}</ref>
and can yield to crack propagation in the unfired body if not relieved.

In addition, any fluctuations in packing density in the compact as it is prepared for the kiln are often amplified during the sintering process, yielding inhomogeneous densification.<ref name="D">{{cite journal
|author=Evans, A.G. |author2= Davidge, R.W.
|title=Strength and fracture of fully dense polycrystalline magnesium oxide
|journal=Phil. Mag.
|volume=20
|page=373
|year=1969
|doi=10.1080/14786436908228708
|bibcode=1969PMag...20..373E
|issue=164
}}</ref><ref name="E">{{cite journal
|author=Evans, A.G. |author2= Davidge, R.W.
|title=Strength and fracture of fully dense polycrystalline magnesium oxide
|journal=J. Mater. Sci.
|volume=5
|page=314
|year=1970
|bibcode = 1970JMatS...5..314E |doi = 10.1007/BF02397783
|issue=4 |s2cid= 137539240
}}</ref>
Some pores and other structural defects associated with density variations have been shown to play a detrimental role in the sintering process by growing and thus limiting end-point densities.<ref name="F">{{cite journal
|author=Lange, F.F.|author2=Metcalf, M.
|title=Processing-Related Fracture Origins in Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> Composites II: Agglomerate Motion and Crack-like Internal Surfaces Caused by Differential Sintering
|journal=J. Am. Ceram. Soc.
|volume=66
|page=398
|year=1983
|doi=10.1111/j.1151-2916.1983.tb10069.x
|issue=6
}}</ref>
Differential stresses arising from inhomogeneous densification have also been shown to result in the propagation of internal cracks, thus becoming the strength-controlling flaws.<ref name="G">{{cite journal|author=Evans, A.G.|journal=J. Am. Ceram. Soc.|volume=65|page=497|year=1987|doi=10.1111/j.1151-2916.1982.tb10340.x|title=Considerations of Inhomogeneity Effects in Sintering|issue=10}}</ref>

It would therefore appear desirable to process a material in such a way that it is physically uniform with regard to the distribution of components and porosity, rather than using particle size distributions which will maximize the green density. The containment of a uniformly dispersed assembly of strongly interacting particles in suspension requires total control over particle-particle interactions. Monodisperse [[Physics:Colloid|colloid]]s provide this potential.<ref name="J">{{cite journal
|author=Mangels, J.A. |author2= Messing, G.L., Eds.
|title=Microstructural Control Through Colloidal Consolidation
|journal=Advances in Ceramics: Forming of Ceramics
|volume=9
|page=94
|year=1984
}}</ref>

Monodisperse powders of colloidal [[Chemistry:Silica|silica]], for example, may therefore be stabilized sufficiently to ensure a high degree of order in the [[Physics:Colloidal crystal|colloidal crystal]] or polycrystalline colloidal solid which results from aggregation. The degree of order appears to be limited by the time and space allowed for longer-range correlations to be established.<ref name="K">{{cite journal|author=Whitesides, G.M.
|title=Molecular Self-Assembly and Nanochemistry: A Chemical Strategy for the Synthesis of Nanostructures
|journal=Science
|volume=254
|year=1991|doi=10.1126/science.1962191
|pmid=1962191
|bibcode=1991Sci...254.1312W|issue=5036|pages=1312–9|display-authors=1|last2=Mathias|first2=J.|last3=Seto|first3=C.
}}</ref><ref name="L">{{cite journal|author=Dubbs D. M, Aksay I.A.|title=Self-Assembled Ceramics|journal=Annu. Rev. Phys. Chem.|volume=51|year=2000|doi=10.1146/annurev.physchem.51.1.601|pmid=11031294|bibcode=2000ARPC...51..601D|pages=601–22|last2=Aksay|s2cid=14113689}}</ref>

Such defective polycrystalline colloidal structures would appear to be the basic elements of sub-micrometer colloidal [[Physics:Materials science|materials science]], and, therefore, provide the first step in developing a more rigorous understanding of the mechanisms involved in microstructural evolution in inorganic systems such as polycrystalline ceramics.

=== Self-assembly ===

[[File:Host Guest Complex Nanocapsule Science Year2005 Vol309 Page2037.jpg|thumbnail|An example of a supramolecular assembly.<ref>{{cite journal|journal=Science|year=2005|volume=309|doi=10.1126/science.1116579|title=Fluorescent Guest Molecules Report Ordered Inner Phase of Host Capsules in Solution|last1=Dalgarno|first1=S. J.|pmid=16179474|last2=Tucker|first2=SA|last3=Bassil|first3=DB|last4=Atwood|first4=JL|s2cid=41468421|issue=5743|bibcode = 2005Sci...309.2037D|pages=2037–9 }}</ref>]]
[[Biology:Self-assembly|Self-assembly]] is the most common term in use in the modern scientific community to describe the spontaneous aggregation of particles (atoms, molecules, colloids, micelles, etc.) without the influence of any external forces. Large groups of such particles are known to assemble themselves into [[Physics:Thermodynamic|thermodynamic]]ally stable, structurally well-defined arrays, quite reminiscent of one of the 7 [[Earth:Crystal|crystal]] systems found in [[Chemistry:Metallurgy|metallurgy]] and [[Earth:Mineralogy|mineralogy]] (e.g. face-centered cubic, body-centered cubic, etc.).{{Citation needed|date=December 2010}}  The fundamental difference in equilibrium structure is in the spatial scale of the unit cell (or lattice parameter) in each particular case.

Thus, self-assembly is emerging as a new strategy in chemical synthesis and [[Engineering:Nanotechnology|nanotechnology]]. Molecular self-assembly has been observed in various biological systems and underlies the formation of a wide variety of complex biological structures. Molecular crystals, liquid crystals, colloids, micelles, emulsions, phase-separated polymers, thin films and self-assembled monolayers all represent examples of the types of highly ordered structures which are obtained using these techniques. The distinguishing feature of these methods is self-organization in the absence of any external forces.{{Citation needed|date=December 2010}}

In addition, the principal mechanical characteristics and structures of biological ceramics, polymer [[Chemistry:Composite material|composites]], elastomers, and [[Biology:Cell|cellular]] materials are being re-evaluated, with an emphasis on bioinspired materials and structures. Traditional approaches focus on design methods of biological materials using conventional synthetic materials. This includes an emerging class of [[Physics:Mechanics|mechanically]] superior biomaterials based on microstructural features and designs found in nature. The new horizons have been identified in the synthesis of bioinspired materials through processes that are characteristic of biological systems in nature. This includes the nanoscale self-assembly of the components and the development of hierarchical structures.<ref name="K"/><ref name="L"/><ref name=ariga>{{Cite journal | doi = 10.1088/1468-6996/9/1/014109| pmid = 27877935| title = Challenges and breakthroughs in recent research on self-assembly| journal = Science and Technology of Advanced Materials| volume = 9| issue = 1| pages = 014109| year = 2008| last1 = Ariga | first1 = K. | last2 = Hill | first2 = J. P. | last3 = Lee | first3 = M. V. | last4 = Vinu | first4 = A. | last5 = Charvet | first5 = R. | last6 = Acharya | first6 = S. | bibcode = 2008STAdM...9a4109A|pmc=5099804}}</ref>

==Ceramic composites==

[[File:PCCB Brake Carrera GT.jpg|thumb|The Porsche Carrera GT's carbon-ceramic (silicon carbide) composite [[Engineering:Disc brake|disc brake]]]]
Substantial interest has arisen in recent years in fabricating ceramic composites. While there is considerable interest in composites with one or more non-ceramic constituents, the greatest attention is on composites in which all constituents are ceramic. These typically comprise two ceramic constituents: a continuous matrix, and a dispersed phase of ceramic particles, whiskers, or short (chopped) or continuous ceramic fibers. The challenge, as in wet chemical processing, is to obtain a uniform or homogeneous distribution of the dispersed particle or fiber phase.<ref name="COMP">Hull, D. and Clyne, T.W. (1996) ''An Introduction to Composite Materials''. Cambridge Solid State Science Series, Cambridge University Press</ref>
<ref name="DES">Barbero, E.J. (2010) ''Introduction to Composite Materials Design'', 2nd Edn., CRC Press.</ref>

Consider first the processing of particulate composites. The particulate phase of greatest interest is tetragonal zirconia because of the toughening that can be achieved from the phase transformation from the metastable tetragonal to the monoclinic crystalline phase, aka transformation toughening. There is also substantial interest in dispersion of hard, non-oxide phases such as SiC, TiB, TiC, [[Chemistry:Boron|boron]], [[Chemistry:Carbon|carbon]] and especially oxide matrices like alumina and [[Chemistry:Mullite|mullite]]. There is also interest too incorporating other ceramic particulates, especially those of highly anisotropic thermal expansion. Examples include Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, graphite, and boron nitride.<ref name="COMP" /><ref name="DES" />

[[File:SiC p1390066.jpg|thumb|right|[[Chemistry:Silicon carbide|Silicon carbide]] single crystal]]

In processing particulate composites, the issue is not only homogeneity of the size and spatial distribution of the dispersed and matrix phases, but also control of the matrix grain size. However, there is some built-in self-control due to inhibition of matrix grain growth by the dispersed phase. Particulate composites, though generally offer increased resistance to damage, failure, or both, are still quite sensitive to inhomogeneities of composition as well as other processing defects such as pores. Thus they need good processing to be effective.<ref name="KBU" /><ref name="MOD" />

Particulate composites have been made on a commercial basis by simply mixing powders of the two constituents. Although this approach is inherently limited in the homogeneity that can be achieved, it is the most readily adaptable for existing ceramic production technology. However, other approaches are of interest.<ref name="KBU" /><ref name="MOD" />

[[File:Tungsten carbide.jpg|thumb|right|[[Chemistry:Tungsten carbide|Tungsten carbide]] milling bits]]

From the technological standpoint, a particularly desirable approach to fabricating particulate composites is to coat the matrix or its precursor onto fine particles of the dispersed phase with good control of the starting dispersed particle size and the resultant matrix coating thickness. One should in principle be able to achieve the ultimate in homogeneity of distribution and thereby optimize composite performance. This can also have other ramifications, such as allowing more useful composite performance to be achieved in a body having porosity, which might be desired for other factors, such as limiting thermal conductivity.

There are also some opportunities to utilize melt processing for fabrication of ceramic, particulate, whisker and short-fiber, and continuous-fiber composites. Clearly, both particulate and whisker composites are conceivable by solid-state precipitation after solidification of the melt. This can also be obtained in some cases by sintering, as for precipitation-toughened, partially stabilized zirconia. Similarly, it is known that one can directionally solidify ceramic eutectic mixtures and hence obtain uniaxially aligned fiber composites. Such composite processing has typically been limited to very simple shapes and thus suffers from serious economic problems due to high machining costs.<ref name="COMP" /><ref name="DES" />

Clearly, there are possibilities of using melt casting for many of these approaches. Potentially even more desirable is using melt-derived particles. In this method, quenching is done in a solid solution or in a fine eutectic structure, in which the particles are then processed by more typical ceramic powder processing methods into a useful body. There have also been preliminary attempts to use melt spraying as a means of forming composites by introducing the dispersed particulate, whisker, or fiber phase in conjunction with the melt spraying process.

Other methods besides melt infiltration to manufacture ceramic composites with long fiber reinforcement are chemical vapor infiltration and the infiltration of fiber preforms with organic [[Biology:Precursor|precursor]], which after [[Chemistry:Pyrolysis|pyrolysis]] yield an [[Physics:Amorphous|amorphous]] ceramic matrix, initially with a low density. With repeated cycles of infiltration and pyrolysis one of those types of [[Chemistry:Ceramic matrix composite|ceramic matrix composite]]s is produced. Chemical vapor infiltration is used to manufacture carbon/carbon and silicon carbide reinforced with carbon or silicon carbide fibers.

Besides many process improvements, the first of two major needs for fiber composites is lower fiber costs. The second major need is fiber compositions or coatings, or composite processing, to reduce degradation that results from high-temperature composite exposure under oxidizing conditions.<ref name="COMP" /><ref name="DES" />

==Applications==

[[File:Si3N4thruster.jpg|thumb|Silicon nitride thruster. Left: Mounted in test stand. Right: Being tested with H<sub>2</sub>/O<sub>2</sub> propellants]]

The products of technical ceramics include tiles used in the [[Engineering:Space Shuttle program|Space Shuttle program]], gas burner [[Physics:Nozzle|nozzle]]s, ballistic protection, nuclear fuel uranium oxide pellets, [[Medicine:Implant|bio-medical implants]], [[Engineering:Jet engine|jet engine]] [[Physics:Turbine|turbine]] blades, and [[Engineering:Missile|missile]] nose cones.

Its products are often made from materials other than clay, chosen for their particular physical properties. These may be classified as follows:

*[[Chemistry:Oxide|Oxide]]s: silica, alumina, zirconia
*Non-oxides: carbides, [[Chemistry:Boride|boride]]s, [[Chemistry:Nitride|nitride]]s, [[Chemistry:Silicide|silicide]]s
*[[Physics:Mixture|Composite]]s: particulate or whisker reinforced matrices, combinations of oxides and non-oxides (e.g. polymers).

Ceramics can be used in many technological industries. One application is the ceramic tiles on [[Organization:NASA|NASA]]'s Space Shuttle, used to protect it and the future supersonic space planes from the searing heat of re-entry into the Earth's atmosphere. They are also used widely in electronics and optics. In addition to the applications listed here, ceramics are also used as a coating in various engineering cases. An example would be a ceramic bearing coating over a titanium frame used for an aircraft. Recently the field has come to include the studies of single crystals or glass fibers, in addition to traditional polycrystalline materials, and the applications of these have been overlapping and changing rapidly.

=== Aerospace ===

*[[Engineering:Engine|Engine]]s: shielding a hot running aircraft engine from damaging other components.
*[[Engineering:Airframe|Airframe]]s: used as a high-stress, high-temp and lightweight bearing and structural component.
*Missile nose-cones: shielding the missile internals from heat.
*[[Engineering:Space Shuttle|Space Shuttle]] tiles
*[[Astronomy:Space debris|Space-debris]] ballistic shields: ceramic fiber woven shields offer better protection to hypervelocity (~7&nbsp;km/s) particles than [[Chemistry:Aluminium|aluminum]] shields of equal weight.<ref>[http://www.3m.com/market/industrial/ceramics/pdfs/CeramicFabric.pdf Ceramic Fabric Offers Space Age Protection], 1994 Hypervelocity Impact Symposium</ref><!-- This summary source from 3M is not an ideal WP source but it provides a very good summary of a number of extensive NASA-funded studies on hypervelocity projectile impacts and several references in the technical literature for further research. -->
*Rocket nozzles: focusing high-temperature exhaust gases from the rocket booster.
*Unmanned Air Vehicles: ceramic engine utilization in aeronautical applications (such as Unmanned Air Vehicles) may result in enhanced performance characteristics and less operational costs.<ref>{{Cite journal | doi = 10.1108/00022661211207884| title = Ceramic engine considerations for future aerospace propulsion| journal = Aircraft Engineering and Aerospace Technology| volume = 84| issue = 2| pages = 75| year = 2012| last1 = Gohardani | first1 = A. S. | last2 = Gohardani | first2 = O. }}</ref>

===Biomedical===
[[File:Hip prosthesis.jpg|thumb|A [[Chemistry:Titanium|titanium]] hip prosthesis, with a ceramic head and polyethylene acetabular cup.]]
*Artificial bone; Dentistry applications, teeth.
*Biodegradable splints; Reinforcing bones recovering from osteoporosis
*Implant material

===Electronics===
*[[Engineering:Capacitor|Capacitor]]s
*[[Engineering:Integrated circuit|Integrated circuit]] packages
*[[Engineering:Transducer|Transducer]]s
*Insulators

=== Optical ===
{{Main|Chemistry:Transparent ceramics}}

*Optical fibers, guided light wave transmission
*Switches
*[[Physics:Laser|Laser]] [[Engineering:Amplifier|amplifier]]s
*[[Physics:Lens (optics)|Lens]]es
*Infrared heat-seeking devices

===Automotive===
*[[Astronomy:Heat shield|Heat shield]]
*Exhaust heat management

==Biomaterials==

[[File:DNA nanostructures.png|thumb|The DNA structure at left (schematic shown) will self-assemble into the structure visualized by [[Physics:Atomic force microscope|atomic force microscopy]] at right.<ref>{{Cite journal | last1 = Strong | first1 = M. | title = Protein Nanomachines | doi = 10.1371/journal.pbio.0020073 | journal = PLOS Biology | volume = 2 | issue = 3 | pages = e73 | year = 2004 | pmid =  15024422| pmc =368168 | doi-access = free }}</ref>]]

Silicification is quite common in the biological world and occurs in bacteria, single-celled organisms, plants, and animals (invertebrates and vertebrates). Crystalline minerals formed in such environment often show exceptional physical properties (e.g. strength, hardness, fracture toughness) and tend to form hierarchical structures that exhibit microstructural order over a range of length or spatial scales. The minerals are crystallized from an environment that is undersaturated with respect to silicon, and under conditions of neutral pH and low temperature (0–40&nbsp;°C). Formation of the mineral may occur either within or outside of the cell wall of an organism, and specific biochemical reactions for mineral deposition exist that include lipids, proteins and carbohydrates.

Most natural (or biological) materials are complex composites whose mechanical properties are often outstanding, considering the weak constituents from which they are assembled. These complex structures, which have risen from hundreds of million years of evolution, are inspiring the design of novel materials with exceptional physical properties for high performance in adverse conditions. Their defining characteristics such as hierarchy, multifunctionality, and the capacity for self-healing, are currently being investigated.<ref>{{cite journal|author=Perry, C.C.|title=Silicification: The Processes by Which Organisms Capture and Mineralize Silica|journal=Rev. Mineral. Geochem.|volume=54|issue=1|page=291|year=2003|doi=10.2113/0540291|bibcode=2003RvMG...54..291P}}</ref>

The basic building blocks begin with the 20 amino acids and proceed to polypeptides, polysaccharides, and polypeptides–saccharides. These, in turn, compose the basic proteins, which are the primary constituents of the 'soft tissues' common to most biominerals. With well over 1000 proteins possible, current research emphasizes the use of collagen, chitin, keratin, and elastin. The 'hard' phases are often strengthened by crystalline minerals, which nucleate and grow in a bio-mediated environment that determines the size, shape and distribution of individual crystals. The most important mineral phases have been identified as hydroxyapatite, silica, and [[Chemistry:Aragonite|aragonite]]. Using the classification of Wegst and Ashby, the principal mechanical characteristics and structures of biological ceramics, polymer composites, elastomers, and cellular materials have been presented. Selected systems in each class are being investigated with emphasis on the relationship between their microstructure over a range of length scales and their mechanical response.

Thus, the crystallization of inorganic materials in nature generally occurs at ambient temperature and pressure. Yet the vital organisms through which these minerals form are capable of consistently producing extremely precise and complex structures. Understanding the processes in which living organisms control the growth of crystalline minerals such as silica could lead to significant advances in the field of materials science, and open the door to novel synthesis techniques for nanoscale composite materials, or nanocomposites.

[[File:NautilusCutawayLogarithmicSpiral.jpg|thumb|The iridescent nacre inside a Nautilus shell.]]
High-resolution [[Physics:Scanning electron microscope|scanning electron microscope]] (SEM) observations were performed of the microstructure of the mother-of-pearl (or [[Biology:Nacre|nacre]]) portion of the [[Biology:Abalone|abalone]] shell. Those shells exhibit the highest mechanical strength and fracture toughness of any non-metallic substance known. The nacre from the shell of the abalone has become one of the more intensively studied biological structures in materials science. Clearly visible in these images are the neatly stacked (or ordered) mineral tiles separated by thin organic sheets along with a macrostructure of larger periodic growth bands which collectively form what scientists are currently referring to as a hierarchical composite structure. (The term hierarchy simply implies that there are a range of structural features which exist over a wide range of length scales).<ref>{{Cite journal | doi = 10.1016/j.pmatsci.2007.05.002| title = Biological materials: Structure and mechanical properties| journal = Progress in Materials Science| volume = 53| pages = 1–206| year = 2008| last1 = Meyers | first1 = M. A. | last2 = Chen | first2 = P. Y. | last3 = Lin | first3 = A. Y. M. | last4 = Seki | first4 = Y. }}</ref>

Future developments reside in the synthesis of bio-inspired materials through processing methods and strategies that are characteristic of biological systems. These involve nanoscale self-assembly of the components and the development of hierarchical structures.<ref name="K"/><ref name="L"/><ref name=ariga/><ref>{{cite journal|author=Heuer, A.H.|title=Innovative Materials Processing Strategies: A Biomimetic Approach|doi=10.1126/science.1546311|pmid=1546311|journal=Science|volume=255|year=1992|bibcode = 1992Sci...255.1098H|issue=5048|pages=1098–105|display-authors=1|last2=Fink|first2=D.|last3=Laraia|first3=V.|last4=Arias|first4=J.|last5=Calvert|first5=P.|last6=Kendall|first6=K|last7=Messing|first7=G.|last8=Blackwell|first8=J|last9=Rieke|first9=P. }}</ref>

==See also==
{{div col}}
*{{annotated link|Chemistry:Ceramic matrix composite}}
*{{annotated link|Chemistry:Chemical engineering}}
*{{annotated link|Physics:Colloid}}
*{{annotated link|Engineering:Glass-ceramic-to-metal seals}}
*{{annotated link|Physics:Materials science}}
*{{annotated link|Engineering:Mechanical engineering}}
*{{annotated link|Physics:Nanoparticle}}
*{{annotated link|Physics:Photonic crystal}}
*{{annotated link|Engineering:Quenching}}
*{{annotated link|Engineering:Three-point flexural test}}
*{{annotated link|Chemistry:Yttria-stabilized zirconia}}
{{div col end}}

==References==
{{Reflist}}

==External links==
*[http://www.ceramics.org The American Ceramic Society]
*[http://www.ctioa.org/ Ceramic Tile Institute of America]

{{Engineering fields}}
{{Branches of materials science}}
{{Branches of chemistry}}

[[Category:Ceramic engineering| ]]
[[Category:Materials science]]
[[Category:Ceramic materials]]
[[Category:Engineering disciplines]]
[[Category:Industrial processes]]

{{Sourceattribution|Ceramic engineering}}