Chemistry:Metal-phenolic network

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A metal-phenolic network (MPN) is a supramolecular coordination compound that is derived from metal ions and polyphenols.[1] [2] MPNs adsorb to a wide variety of surfaces due to noncovalent forces.[3][4] Possible applications of MPN-based materials include drug delivery, bioimaging, biotechnology, controlled-release fertilizers, and electrocatalysis.[5][6][7]

References

  1. Hirotaka Ejima; Joseph J. Richardson; Kang Liang; James P. Best; Martin P. van Koeverden; Georgina K. Such; Jiwei Cui; Frank Caruso (2013). "One-Step Assembly of Coordination Complexes for Versatile Film and Particle Engineering". Science 341 (12): 154–7. doi:10.1126/science.1237265. PMID 23846899. Bibcode2013Sci...341..154E. 
  2. Guo, Junling; Ping, Yuan; Ejima, Hirotaka; Alt, Karen; Meissner, Mirko; Richardson, Joseph J.; Yan, Yan; Peter, Karlheinz et al. (26 May 2014). "Engineering Multifunctional Capsules through the Assembly of Metal-Phenolic Networks". Angewandte Chemie International Edition 53 (22): 5546–5551. doi:10.1002/anie.201311136. PMID 24700671. 
  3. Ejima, Hirotaka; Richardson, Joseph J.; Caruso, Frank (2017-02-01). "Metal-phenolic networks as a versatile platform to engineer nanomaterials and biointerfaces". Nano Today 12: 136–148. doi:10.1016/j.nantod.2016.12.012. 
  4. "Assembly of Metal–Phenolic Networks on Water-Soluble Substrates in Nonaqueous Media". Advanced Functional Materials 32: 2111942. https://onlinelibrary.wiley.com/doi/full/10.1002/adfm.202111942. 
  5. Kim, Nayeong; Lee, Inhui; Choi, Yuri; Ryu, Jungki (2021). "Molecular design of heterogeneous electrocatalysts using tannic acid-derived metal–phenolic networks" (in en). Nanoscale 13 (48): 20374–20386. doi:10.1039/D1NR05901G. ISSN 2040-3364. PMID 34731231. http://xlink.rsc.org/?DOI=D1NR05901G. 
  6. Guo, Junling; Tardy, Blaise L.; Christofferson, Andrew J.; Dai, Yunlu; Richardson, Joseph J.; Zhu, Wei; Hu, Ming; Ju, Yi et al. (10 October 2016). "Modular assembly of superstructures from polyphenol-functionalized building blocks". Nature Nanotechnology 11 (12): 1105–1111. doi:10.1038/nnano.2016.172. PMID 27723730. Bibcode2016NatNa..11.1105G. 
  7. "Solid-State Encapsulation of Urea via Mechanochemistry-Driven Engineering of Metal–Phenolic Networks". Chemistry of Materials 35 (18): 7800–7813. https://pubs.acs.org/doi/abs/10.1021/acs.chemmater.3c01696.