Chemistry:Nickel ternary chalcogenides

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Short description: Class of chemical compounds

The Nickel ternary chalcogenides are a class of chemical compounds that contains nickel, a chalcogenide, and another element. Nickel forms a series of double nickel oxides with other elements, which may be termed "nickelates". These double nickel oxides are not listed on this page. There are also many well defined double compounds with sulfur, selenium and tellurium which are listed here.

formula name colour structure production references
NH4NiS5 ammonium nickel sulphide black NH4 polysulfide+NiSO4 [1][2]
K2Ni3S4 potassium nickel tetrasulfide bronze yellow Fddd a=10.023 b=26.074 c=5.704 NiSO4 K2CO3 S [1][3][4]
K2Ni11S10 potassium nickel decasulfide dark metallic green NiO+KCNS [1] J. Milbauer
Na2Ni3S4 sodium nickel tetrasulfide dark yellow NiSO4 Na2CO3 S [1] R. Schneider
KNi2S2 potassium dinickel disulfide orange yellow Ni foil, S, K at 723K [5][6]
K2Ni3Se4 potassium nickel tetraselenide gold Fddd a=10.468 b=26.496 c=5.995 [7][8]
KNi2Se2 potassium dinickel diselenide purple-red I4/mmmtetragonal a=3.909, c=13.4142 Ni foil, Se shot, K at 723K [5][9]
CsNi2Se2 caesium dinickel diselenide tetragonal a=3.988, c=14.419 heat elements [10]
TlNi2Se2 Thallium dinickel diselenide gold metallic tetragonal heat elements together in closed quartz tube [11]
Rb2Ni3S4 rubidium nickel tetrasulphide metallic greenish gold Fmmm orthorhombic a=9.901 Å, b=13.606 Å and c=5.861 Z=4 layered; ferromagnetic only after water immersion [7][12]
Rb2Ni3Se4 rubidium nickel tetraselenide golden metallic Fddd orthorhombic a = 10.555 Å, b = 27.588 Å, c = 6.031 Å, Z = 8 layered; ferromagnetic only after water immersion Rb2CO3 S Ni [13]
Cs2Ni3S4 cesium nickel tetrasulphide greenish gold Fmmm a=10.038 b=14.552 c=5.934 [8][13]
Cs2Ni3S4 cesium nickel tetrasulphide gold Fmmm a=10.540 b=14.624 c=6.194 [8]
Cs0.9Ni3.1Se3 Hexagonal P63/m a = 9.26301(4) Å and c = 4.34272(2) Å quasi-one-dimensional electric conductor [14]
BaNi4S5 Barium nickel pentasulfide bronze yellow NiSO4 K2CO3 S [1] R. Schneider; I. and L. Bellucci
Pb2Ni3S2 lead nickel disulfide melt 790° PbS Ni [15] W Guertler; W Guertler H Schack
(Ni,Fe)9S8 Pentlandite bronze yellow melt 870 [15] T. Scheerer
Fe2Ni2S4 ferrous nickel tetrasulfide melt 840 [16] K Bornemann
Fe2Ni2S3 ferrous nickel trisulfide stable over 575°, melt 886, [17] K Bornemann
Fe3Ni4S5 ferrous nickel pentasulfide below 575 [17] K Bornemann
Fe4Ni2S5 [17] K Bornemann
Fe2Ni3S4 [17] K Bornemann
Fe3Ni4S5 [17] K Bornemann
Fe2Ni2S3 [17] K Bornemann
FeNi2S4 Violarite dark violet grey mineral oxidate
Ni3Sn2S2 [18]
Ni3Bi2S2 superconducting [18]
Ni3Bi2Se2 superconducting [18]
NiSnS3 nickel thiostannate greenish black orthorhombic a=6.88 b=7.89 c=11.95 Z=8 V=644 NiCl2 + SnS2 [19]
NiGeS33 nickelselenogermanate [20]
Ta2NiS5 Orthorhombic [21]
Ta2NiSe5 monoclinic β=90.53 [21]
Ta2Ni2Te4 [22]
Ta2Ni3Te5 [22]

References

  1. ↑ 1.0 1.1 1.2 1.3 1.4 Mellor p443
  2. ↑ Ephraim, Fritz (17 September 1923). "Über Nickelsulfid" (in de). Berichte der Deutschen Chemischen Gesellschaft (A and B Series) 56 (8): 1885–1886. doi:10.1002/cber.19230560825. 
  3. ↑ Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle" (in de). Zeitschrift für anorganische und allgemeine Chemie 375 (1): 1–7. doi:10.1002/zaac.19703750102. 
  4. ↑ Schneider, R. (1874). "Ueber neue Schwefelsalze". Annalen der Physik und Chemie 227 (3): 437–450. doi:10.1002/andp.18742270306. Bibcode: 1874AnP...227..437S. https://zenodo.org/record/1423736. 
  5. ↑ 5.0 5.1 Hlukhyy, Viktor; Trots, Dmytro; Fässler, Thomas F. (13 January 2017). "First-Order Phase Transition in BaNi2Ge2 and the Influence of the Valence Electron Count on Distortion of the [math]\displaystyle{ \ce{ThCr2 Si2} }[/math] Structure Type". Inorganic Chemistry 56 (3): 1173–1185. doi:10.1021/acs.inorgchem.6b02190. PMID 28085271. 
  6. ↑ Neilson, James R.; McQueen, Tyrel M.; Llobet, Anna; Wen, Jiajia; Suchomel, Matthew R. (24 January 2013). "Charge density wave fluctuations, heavy electrons, and superconductivity in [math]\displaystyle{ \ce{KNi2 S2 } }[/math]". Physical Review B 87 (4): 045124. doi:10.1103/PhysRevB.87.045124. Bibcode: 2013PhRvB..87d5124N. 
  7. ↑ 7.0 7.1 Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie 375 (1): 1–7. doi:10.1002/zaac.19703750102. 
  8. ↑ 8.0 8.1 8.2 Bronger, W.; Rennau, R.; Schmitz, D. (May 1991). "Schichtstrukturen ternärer Chalkogenide [math]\displaystyle{ \ce{A2M3X4} }[/math] (A ? K, Rb, Cs; M ? Ni, Pd, Pt; X ? S, Se)". Zeitschrift für anorganische und allgemeine Chemie 597 (1): 27–32. doi:10.1002/zaac.19915970105. 
  9. ↑ Neilson, James R.; McQueen, Tyrel M. (9 May 2012). "Bonding, Ion Mobility, and Rate-Limiting Steps in Deintercalation Reactions with [math]\displaystyle{ \ce{ThCr2Si2} }[/math] -type [math]\displaystyle{ \ce{KNi2 Se2} }[/math]". Journal of the American Chemical Society 134 (18): 7750–7757. doi:10.1021/ja212012k. PMID 22530571. 
  10. ↑ Huimin Chen; Yang, Jinhu; Cao, Chao; Li, Lin; Su, Qiping; Chen, Bin; Wang, Hangdong; Mao, Qianhui et al. (1 April 2016). "Superconductivity in a new layered nickel selenide [math]\displaystyle{ \ce{CsNi2Se2} }[/math]". Superconductor Science and Technology 29 (4): 045008. doi:10.1088/0953-2048/29/4/045008. Bibcode: 2016SuScT..29d5008C. 
  11. ↑ Wang, Hangdong; Dong, Chiheng; Mao, Qianhui; Khan, Rajwali; Zhou, Xi; Li, Chenxia; Chen, Bin; Yang, Jinhu et al. (12 November 2013). "Multiband Superconductivity of Heavy Electrons in a [math]\displaystyle{ \ce{TlNi2Se2} }[/math] Single Crystal". Physical Review Letters 111 (20): 207001. doi:10.1103/PhysRevLett.111.207001. PMID 24289702. Bibcode: 2013PhRvL.111t7001W. 
  12. ↑ Hasegawa, Takumi; Inui, Mitsutaka; Hondou, Katsuhiro; Fujiwara, Yishihiro; Kato, Tetsuya; Iio, Katsunori (February 2004). "Raman spectroscopy on ternary transition metal chalcogenide [math]\displaystyle{ \ce{Rb2Ni3S4 } }[/math]". Journal of Alloys and Compounds 364 (1–2): 199–207. doi:10.1016/S0925-8388(03)00503-6. 
  13. ↑ 13.0 13.1 Bronger, Welf; Rennau, R. M.; Schmitz, D. (April 1996). "Darstellung und Kristallstruktur von [math]\displaystyle{ \ce{Rb2Ni3Se4} }[/math]". Zeitschrift für anorganische und allgemeine Chemie 622 (4): 627–629. doi:10.1002/zaac.19966220409. 
  14. ↑ Sun, Fan; Guo, Zhongnan; Liu, Ning; Wu, Dan; Lin, Jiawei; Cheng, Erjian; Ying, Tianping; Li, Shiyan et al. (16 March 2018). "[math]\displaystyle{ \ce{Cs}_{0.9}\ce{Ni}_{3.1}\ce{Se3} }[/math] : A Ni-Based Quasi-One-Dimensional Conductor with Spin-Glass Behavior". Inorganic Chemistry 57 (7): 3798–3804. doi:10.1021/acs.inorgchem.7b03143. PMID 29546755. 
  15. ↑ 15.0 15.1 Mellor p444
  16. ↑ Mellor p445
  17. ↑ 17.0 17.1 17.2 17.3 17.4 17.5 Mellor p446
  18. ↑ 18.0 18.1 18.2 Rommel, Stefan Michael; Krach, Alexander; Peter, Philipp; Weihrich, Richard (25 April 2016). "Conversion Reactions of Solids: From a Surprising Three-Step Mechanism towards Directed Product Formation". Chemistry 22 (18): 6333–6339. doi:10.1002/chem.201505209. PMID 26997587. 
  19. ↑ Mamedova, N. A.; Ragimov, S. S.; Sadykhov, F. M.; Aliev, I. I. (17 February 2012). "Preparation and physicochemical study of nickel(II) thiostannate in the [math]\displaystyle{ \ce{NiCl2-SnS2-H2O} }[/math] system". Russian Journal of Inorganic Chemistry 57 (2): 160–162. doi:10.1134/S0036023612020179. 
  20. ↑ Popescu, M. A. (2001-11-30) (in en). Non-Crystalline Chalcogenicides. Springer Science & Business Media. p. 73. ISBN 9781402003592. https://books.google.com/books?id=6RgQf8cPPbIC&pg=PA73. 
  21. ↑ 21.0 21.1 Di Salvo, F.J.; Chen, C.H.; Fleming, R.M.; Waszczak, J.V.; Dunn, R.G.; Sunshine, S.A.; Ibers, James A. (February 1986). "Physical and structural properties of the new layered compounds [math]\displaystyle{ \ce{Ta2NiS5} }[/math] and [math]\displaystyle{ \ce{Ta2NiSe5} }[/math]". Journal of the Less Common Metals 116 (1): 51–61. doi:10.1016/0022-5088(86)90216-X. 
  22. ↑ 22.0 22.1 Tremel, Wolfgang (July 1991). "Isolated and Condensed Ta2Ni2 Clusters in the Layered Tellurides [math]\displaystyle{ \ce{Ta2Ni2Te4} }[/math] and [math]\displaystyle{ \ce{Ta2Ni3Te5} }[/math]". Angewandte Chemie International Edition in English 30 (7): 840–843. doi:10.1002/anie.199108401. 



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