Chemistry:Arsenidostannate

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Arsenidostanates are chemical compounds that contain anions with arsenic bonded to tin. They are in the category of tetrelarsenides, pnictidostancates, or tetrelpnictides. They are distinct from arsenide stannides such as palarstanide, (Pd
8(Sn,As)
3) where the cation charge exceeds that on the tin or arsenic.[1] Other minerals that contain arsenic and tin are erniggliite[2] and coiraite.[3]

name formula formula

weight

crystal

system

space

group

unit cell volume density comments ref
Li1–xSn2+xAs2, 0.2 < x < 0.4 trigonal R3m a=3.991-4.0244 c=25.592-25.632 Z=3 353.6-358.9 [4]
Na2SnAs2 I41/acd a=14.166, c=21.191, Z = 32 metallic grey [5]
NaSn2As2 rhombohedral R3m a=4.000 c=27.562 metallic; layers [6]
KSn3As3 orthorhombic Pnma Z=4 band gap 0.50 eV [7]
RbSn3As3 orthorhombic Pnma a=10.321, b=4.0917, c=19.570 [7]
Ca5Sn2As6 orthorhombic Pbam a = 13.643, b = 11.830, c = 4.121 Z=2 [8]
α-Sr3Sn2As4 orthorhombic Cmca a = 25.798, b = 12.888, c = 19.124, Z = 24 6358.8 melt 1185K; band gap 0.9 eV [9]
β-Sr3Sn2As4 monoclinic P21/c a = 7.705, b = 19.118, c = 7.688, β = 112.003°, Z = 4 1049.9 dec>800K; band gap 0.9 eV [9]
Sr14Sn3As12 trigonal R3 Z=3 [10]
Ba3Sn4As6 monoclinic P21/n a=8.637, b=18.354, c=9.721, β=90.05°, Z=4 [11]
BaCu6Sn2As4−x tetragonal I4/mmm a = 4.164, c = 24.088 [12]
Ba13Si6Sn8As22 4551.72 tetragonal I42m a = 14.4857, c = 13.5506 Z=2 2843.4 5.316 black; Si4As10 units; band gap 1.0 eV [13]
EuSn2As2 trigonal [14]
Eu14Sn3As12 trigonal R3 Z=3 [10]
Eu11Zn4Sn2As12 3069.46 monoclinic C2/c a = 7.5679, b = 13.0883, c = 31.305, β = 94.8444 Z=4 3089.7 6.599 silver; band gap 0.04 eV; ferromagnetic below 15K; negative colossal magnetoresistance [15]

References

  1. ↑ "Palarstanide Mineral Data". http://webmineral.com/data/Palarstanide.shtml. 
  2. ↑ "Erniggliite Mineral Data". http://webmineral.com/data/Erniggliite.shtml. 
  3. ↑ "Coiraite Mineral Data". http://webmineral.com/data/Coiraite.shtml. 
  4. ↑ Lee, Kathleen; Kaseman, Derrick; Sen, Sabyasachi; Hung, Ivan; Gan, Zhehong; Gerke, Birgit; Pöttgen, Rainer; Feygenson, Mikhail et al. (2015-03-18). "Intricate Short-Range Ordering and Strongly Anisotropic Transport Properties of Li 1– x Sn 2+ x As 2" (in en). Journal of the American Chemical Society 137 (10): 3622–3630. doi:10.1021/jacs.5b00237. ISSN 0002-7863. PMID 25702752. https://pubs.acs.org/doi/10.1021/jacs.5b00237. 
  5. ↑ Asbrand, Matthias; Eisenmann, Brigitte (1993). [ISSN: 0932-0776 "Na2[SnAs2], the first Zintl phase with a [SnAs2] framework based on adamantane analogous [Sn4As10] units"]. Zeitschrift für Naturforschung, B: Chemical Sciences 48: 452–456. doi:10.1515/znb-1993-0409. ISSN: 0932-0776. 
  6. ↑ Arguilla, Maxx Q.; Katoch, Jyoti; Krymowski, Kevin; Cultrara, Nicholas D.; Xu, Jinsong; Xi, Xiaoxiang; Hanks, Amanda; Jiang, Shishi et al. (2016-10-25). "NaSn 2 As 2 : An Exfoliatable Layered van der Waals Zintl Phase" (in en). ACS Nano 10 (10): 9500–9508. doi:10.1021/acsnano.6b04609. ISSN 1936-0851. PMID 27700035. https://pubs.acs.org/doi/10.1021/acsnano.6b04609. 
  7. ↑ 7.0 7.1 Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt3As3 (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry 238: 229–235. doi:10.1016/j.jssc.2016.03.035. Bibcode: 2016JSSCh.238..229K. 
  8. ↑ Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (November 1985). "Ca5Sn2As6, das erste Inoarsenidostannat(IV)" (in de). Zeitschrift für anorganische und allgemeine Chemie 530 (11): 74–78. doi:10.1002/zaac.19855301108. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19855301108. 
  9. ↑ 9.0 9.1 Liu, Xiao-Cun; Pan, Ming-Yan; Li, Xin; Xia, Sheng-Qing; Tao, Xu-Tang (2014). "Synthesis, polymorphism, and electronic structures of Sr 3 Sn 2 As 4" (in en). Inorg. Chem. Front. 1 (9): 689–694. doi:10.1039/C4QI00106K. ISSN 2052-1553. http://xlink.rsc.org/?DOI=C4QI00106K. 
  10. ↑ 10.0 10.1 Liu, Xiao-Cun; Pan, Ming-Yan; Xia, Sheng-Qing; Tao, Xu-Tang (21 September 2015). "Sr 14 Sn 3 As 12 and Eu 14 Sn 3 As 12 : Enantiomorph-like Zintl Compounds". Inorganic Chemistry 54 (18): 8875–8877. doi:10.1021/acs.inorgchem.5b01145. PMID 26361335. 
  11. ↑ Lam, Robert; Mar, Arthur (May 2001). "The metallic Zintl phase Ba3Sn4As6" (in en). Solid State Sciences 3 (4): 503–512. doi:10.1016/S1293-2558(01)01155-4. Bibcode: 2001SSSci...3..503L. https://linkinghub.elsevier.com/retrieve/pii/S1293255801011554. 
  12. ↑ Wu, Hanlin; Li, Sheng; Wang, Xiqu; Kwon, Sunah; Liu, Wenhao; Ofenstein, Gareth A.; Kim, Moon J.; Lv, Bing (February 2022). "New layered quaternary BaCu6Sn2As4−x and BaCu6Sn2P4−x phases: Crystal growth and physical properties" (in en). Journal of Alloys and Compounds 892: 162111. doi:10.1016/j.jallcom.2021.162111. https://linkinghub.elsevier.com/retrieve/pii/S0925838821035210. 
  13. ↑ Liu, Xiao-Cun; Lin, Na; Wang, Jian; Pan, Ming-Yan; Zhao, Xian; Tao, Xu-Tang; Xia, Sheng-Qing (2013-10-21). "Ba 13 Si 6 Sn 8 As 22 : A Quaternary Zintl Phase Containing Adamantane-Like [Si 4 As 10 Clusters"] (in en). Inorganic Chemistry 52 (20): 11836–11842. doi:10.1021/ic402023z. ISSN 0020-1669. PMID 24079277. https://pubs.acs.org/doi/10.1021/ic402023z. 
  14. ↑ Pakhira, Santanu; Tanatar, M. A.; Heitmann, Thomas; Vaknin, David; Johnston, D. C. (2021-11-19). "A -type antiferromagnetic order and magnetic phase diagram of the trigonal Eu spin- 7 2 triangular-lattice compound EuSn 2 As 2" (in en). Physical Review B 104 (17): 174427. doi:10.1103/PhysRevB.104.174427. ISSN 2469-9950. Bibcode: 2021PhRvB.104q4427P. https://link.aps.org/doi/10.1103/PhysRevB.104.174427. 
  15. ↑ Devlin, Kasey P.; Kazem, Nasrin; Zaikina, Julia V.; Cooley, Joya A.; Badger, Jackson R.; Fettinger, James C.; Taufour, Valentin; Kauzlarich, Susan M. (2018-10-23). "Eu 11 Zn 4 Sn 2 As 12 : A Ferromagnetic Zintl Semiconductor with a Layered Structure Featuring Extended Zn 4 As 6 Sheets and Ethane-like Sn 2 As 6 Units" (in en). Chemistry of Materials 30 (20): 7067–7076. doi:10.1021/acs.chemmater.8b02749. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.8b02749. 



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