Chemistry:Chain propagation

Short description: Propagation of a chemical chain reaction by continuously regenerating a reactive species

IUPAC definition

(in a chain polymerization) Chemical reaction between a chain carrier
and a monomer that results in the growth of a polymer chain and the
regeneration of at least one chain carrier.

Note 1: The recommended symbol for the rate constant for chain
propagation in a homopolymerization is k_p.

Penczek S.; Moad, G. Pure Appl. Chem., 2008, 80(10), 2163-2193

Chain propagation (sometimes referred to as propagation) is a process in which a reactive intermediate is continuously regenerated during the course of a chemical chain reaction. For example, in the chlorination of methane, there is a two-step propagation cycle involving as chain carriers a chlorine atom and a methyl radical which are regenerated alternately:

^•Cl + CH₄ → HCl + ^•CH₃

^•CH₃ + Cl₂ → CH₃Cl + ^•Cl

The two steps add to give the equation for the overall chain reaction:

CH₄ + Cl₂ → CH₃Cl + HCl.

Polymerization

In a chain-growth polymerization reaction, the reactive end-groups of a polymer chain react in each propagation step with a new monomer molecule transferring the reactive group to the last unit. Here the chain carrier is the polymer molecule with a reactive end-group, and at each step it is regenerated with the addition of one monomer unit:

[math]\displaystyle{ (-M-)_n (polymer) + M (monomer) \rightarrow (-M-)_{n+1} }[/math]

External links

• IUPAC Gold Book definition: chain-propagating reaction