Chemistry:Dilbit

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Short description: Diluted bitumen (asphalt)

Dilbit (diluted bitumen) is a bitumen diluted with one or more lighter petroleum products, typically natural-gas condensates such as naphtha. Diluting bitumen makes it much easier to transport, for example in pipelines. Per the Alberta Oil Sands Bitumen Valuation Methodology, "Dilbit Blends" means "Blends made from heavy crudes and/or bitumens and a diluent, usually natural-gas condensate, for the purpose of meeting pipeline viscosity and density specifications, where the density of the diluent included in the blend is less than 800 kg/m3."[1] If the diluent density is greater than or equal to 800 kg/m3, the diluent is typically synthetic crude and accordingly the blend is called synbit.[2]

Reasons for dilution

Bitumen and heavy oils are often produced from remote deposits such as the Athabasca oil sands in Alberta, Canada and the Orinoco tar sands in Venezuela. Before 1980, most produced bitumen was transported by truck, but trucking is seasonally restricted and relatively inefficient and expensive compared to pipeline transport. However, bitumen in its undiluted state is too viscous and dense to be transported by pipeline. To create a fluid capable of transportation by pipeline, bitumen must be mixed with a fluid that has much lower viscosity and will keep bitumen from precipitating out of the mixture. By 1985, Alberta Energy Company was operating dual pipelines to transport diluent from Edmonton to the Cold Lake oil sands and dilbit from Cold Lake to Edmonton.[3] Dilbit is now also transported by rail.[4]

Methods of dilution

The most common diluent used to dilute bitumen is natural gas condensate (NGC), especially the naphtha component.[5] Due to insufficient quantity of natural gas condensate in Alberta, bitumen shippers also use refined naptha and synthetic crude oil (SCO) as diluent, and import a considerable amount from the U.S.[6] Although SCO requires a higher volume percentage to achieve the same viscosity, at least one study found that SCO provides better blend stability than NGC.[7] Shippers dilute bitumen before shipment in order to meet viscosity and density requirements found in common carrier pipeline tariff rules. A National Energy Board study assumed a standard dilbit containing 33% condensate (resulting in product with "21.5 °API and sulphur content of 3.3 percent") and synbit containing 50% SCO.[8][9][10][11] By selecting different diluent types and blend ratios, bitumen shippers attempt to lower component costs, increase blend value, and maintain pipeline transportability. The blend ratio may consist of 25 to 55% diluent by volume, depending on characteristics of the bitumen and diluent, pipeline specifications, operating conditions, and refinery requirements.[3]

Froth treatment which removes heavy constituents rather than adding lighter ones is another method.[12]

Refinement process

Diluent can be removed from dilbit by distillation and reused. Alternatively, the entire dilbit can be refined. Dilbit and synbit are typically processed by refineries as heavy or medium crudes, respectively.[8] Since dilbit contains hydrocarbons at extreme ends of the viscosity range, it can be more difficult to process than typical crude oil.[13]

Risks and failures

Enbridge pipeline dilbit spill

The Kalamazoo River oil spill was a major spill from a ruptured Enbridge dilbit pipeline in 2010.[14] Cleanup took five years. The EPA ordered Enbridge to dredge the heavy bitumen out of hundreds of acres of Talmadge Creek and the Kalamazoo River.

Separation and oil spill risks

Unlike conventional crude, unstabilized dilbit floats briefly in water but heavier components sink as light components evaporate. The remaining bitumen can make cleaning up a dilbit spill more difficult than a conventional oil spill, particularly if dredging is considered too ecologically damaging.[15] During the 2010 Kalamazoo River oil spill, the heavier components combined with silt and sank to the bottom of the water column, making cleanup difficult.[16] Cleanup of the spill was still underway three years after the event, and officials at the Michigan Department of Natural Resources' Fishery Division stated that it will "be many more years before the agency can measure the full impact on fish and other animals' reproductive cycles."[17] However, studies show that dilbit does not increase the risk of corrosion occurring within a pipeline or otherwise increase the risk of a release occurring.[18][19][20][21]

In 2013, opening on the Keystone XL pipeline proposal, the EPA recommended to the State Department that pipelines that carry dilbit (such as the proposed Keystone XL) should no longer be treated just like pipelines that carry any other oil. "We have learned from the 2010 Enbridge spill of oil sands crude in Michigan that spills of diluted bitumen (dilbit) may require different response actions or equipment from response actions for conventional oil spills. These spills can also have different impacts than spills of conventional oil. ... We recommend that the Final EIS more clearly acknowledge that in the event of a spill to water, it is possible that large portions of dilbit will sink and that submerged oil significantly changes spill response and impacts. We also recommend that the Final EIS include means to address the additional risks of releases that may be greater for spills of dilbit than other crudes. For example, in the Enbridge spill, the local health department issued voluntary evacuation notices based on the level of benzene measured in the air."[22]

Oil spills in aquatic ecosystems

Pipelines are a major source of dilbit transportation and of revenue in Canada and the United States .[23] The effects of dilbit spills on freshwater ecosystems is an active area of research, and much remains unknown.

In coastal marine ecosystems, such as those found in British Columbia, Canada, dilbit floats on the surface because it is too light to sink, unless it is significantly weathered.[24] Weathering breaks down the lighter components. Dilbit is harmful to a wide range of marine animals, including sea otters, baleen whales, fish embryos, and juvenile salmon.[24]

The effects of dilbit on freshwater ecosystems have come into focus in the late 2010s, particularly by researchers at the Experimental Lakes Area and Queen’s University, both in Ontario, Canada. Environmental factors such as temperature and light change dilbit’s physical properties, so whole-lake ecosystem experiments are crucial in understanding the potential effects of dilbit leaks and spills.[25] Oil spills were simulated in limnocorrals, which are effectively giant test tubes in a lake.[25] The results of these studies show greater than 70% reduction in most phytoplankton and zooplankton in response to oil spills, although nano- and microphytoplankton populations recovered as the oil sank to the bottom of the lake.[26] Total insect emergence also decreased with increasing dilbit concentration, and the oil likely drove water strider immobility and death.[27]

Alternatives to diluent

  • Heated pipelines
  • Constructing upgraders closer to production

See also

  • Canadian Centre for Energy Information
  • History of the petroleum industry in Canada (oil sands and heavy oil)
  • Syncrude
  • Suncor
  • CNRL
  • Kalamazoo River oil spill

References

  1. ↑ (pdf) Alberta Oil Sands Bitumen Valuation Methodology, 2008-9995, Calgary, Alberta: Canadian Association of Petroleum Producers, Dec 2008, http://www.capp.ca/getdoc.aspx?DocId=144465&DT=NTV, retrieved 2011-06-18 
  2. ↑ Canada's Oil Sands: Opportunities and Challenges to 2015 (Energy Market Assessment). Calgary, Alberta: National Energy Board. May 2004. pp. 115–118. ISBN 0-662-36880-0. http://www.neb.gc.ca/clf-nsi/rnrgynfmtn/nrgyrprt/lsnd/pprtntsndchllngs20152004/pprtntsndchllngs20152004-eng.pdf. Retrieved 14 Mar 2012.  Condensate: "A mixture comprised mainly of pentanes and heavier hydrocarbons recovered as a liquid from field separators, scrubbers or other gathering facilities or at the inlet of a natural gas processing plant before the gas is processed." Dilbit: "Bitumen that has been reduced in viscosity through addition of a diluent (or solvent) such as condensate or naphtha." Diluent: "Any lighter hydrocarbon, usually pentanes plus, added to heavy crude oil or bitumen in order to facilitate its transport on crude oil pipelines." Synbit: "A blend of bitumen and synthetic crude oil that has similar properties to medium sour crude." "Synthetic crude oil is a mixture of hydrocarbons generally similar to light sweet crude oil, derived by upgrading crude bitumen or heavy crude oil."
  3. ↑ 3.0 3.1 Walker, Ian C. (1998), Marketing Challenges for Canadian Bitumen, Tulsa, OK: International Centre for Heavy Hydrocarbons, p. 2, http://www.oildrop.org/Info/Centre/Lib/7thConf/19980101.pdf 
  4. ↑ Harrison, Lynda (September 2011). "Riding the Rails, Oil companies climb aboard potential alternative to pipelines". Oil & Gas Inquirer (Calgary, Alberta: JuneWarren-Nickle's Energy Group). http://www.oilandgasinquirer.com/printer.asp?article=magazine%2F110912%2FMAG2011_SC0000.html. 
  5. ↑ "Altex model". Altex Energy Ltd.. http://altex-energy.com/our_model.html. "On December 2, 2009, Purvin and Gertz reported that Alberta produces about 80,000 bbls/d of natural gasoline (primarily pentane and hexane) and another 65,000 bbls/d of Naphtha from its indigenous natural gas. These hydrocarbons have been added to bitumen (typically a 10–12 API product) to produce a pipelinable product called dilbit (19–21 API). In recent years the indigenous supply of natural gasoline not been sufficient to meet the demand. To meet bitumen producer’s requirements, about 40,000 bbls/d of natural gasoline has been imported into Alberta, primarily using rail road tank cars. The National Energy Board (“NEB”) tracks these volumes and in a recent publication shows that it expects the demand for natural gasoline to grow by about 27,000 bpd each year for the next ten years." 
  6. ↑ Ross, Elsie (13 Sep 2012). "New Diluent Sources Needed For Forecast Growth In Bitumen". The Daily Oil Bulletin (Junewarren-Nickle’s Energy Group). "Oilsands operators have been importing diluent since about 2004 as the required volumes of pentanes plus and condensate have significantly outpaced domestic production capacity, says the CERI study. In 2010, an estimated 260,000 bbls per day of diluent was required while total Canadian domestic production was about 160,000 bbls per day, indicating that close to 40 per cent (100,000 bbls per day) of the required diluent needed to be imported, says the study." 
  7. ↑ Rahimi, Parviz; Alem, Teclemariam (10 Feb 2010). "Crude Oil Compatibility and Diluent Evaluation for Pipelining". Joint CCQTA/COQA meeting (New Orleans). Devon, Alberta: National Centre for Upgrading Technology. http://geoscan.ess.nrcan.gc.ca/text/geoscan/fulltext/NCUT2009_Paper28.pdf. Retrieved 18 Jun 2011. 
  8. ↑ 8.0 8.1 Canada's Oil Sands: Opportunities and Challenges to 2015 (Energy Market Assessment). Calgary, Alberta: National Energy Board. May 2004. ISBN 0-662-36880-0. http://www.neb.gc.ca/clf-nsi/rnrgynfmtn/nrgyrprt/lsnd/pprtntsndchllngs20152004/pprtntsndchllngs20152004-eng.pdf. Retrieved 14 Mar 2012. 
  9. ↑ Crude Oil Forecast, Markets and Pipeline Expansions, Calgary, Alberta: Canadian Association of Petroleum Producers, June 2007, p. 5, http://tothetarsands.ca/wp-content/uploads/2007/08/capp-2007-forecast.pdf, retrieved 16 June 2012, "The DilBit blend is typically made up of three parts bitumen and one part condensate. SynBit blend is comprised of roughly fifty percent synthetic and fifty percent bitumen." 
  10. ↑ Segato, Randy, Quality Guidelines for Western Canadian Condensate, Calgary, Alberta: Canadian Association of Petroleum Producers, p. 6, http://www.coqa-inc.org/Segato0608.pdf, retrieved 16 June 2012, "Bitumen and Heavy Crude Oil must be diluted to meet pipeline viscosity and density specifications. Two blend type conventions
     •upgraded light synthetic blends (SYNBIT, ~50/50 ratio) or
     •heavy and bitumen diluted with condensate (DILBIT, ~25/75 ratio)"     
  11. ↑ Crandall, G. R. (17 Dec 2004), Phase II―Refined Products and Petrochemicals from Bitumen, R. A. McKetta, G. A. Houlton, J. D. Wright, O. Malbec, Purvin & Gertz, Inc., p. 52, http://www.energy.alberta.ca/EnergyProcessing/pdfs/PhaseII_Report.pdf, retrieved 16 June 2012, "We assumed that the bitumen delivered to the Alberta upgrader would be diluted with C5+ condensate with a blend ratio of 26% C5+ and 74% bitumen needed to achieve the pipeline viscosity specification of 350 cst and 940 kg/m3 density."  Athabasca bitumen has a density of 8.4 API and 4.8 weight % sulfur. SCO has a density of 35 API and 0.1 weight % sulfur.
  12. ↑ Jeff Lewis (November 8, 2011). "SNC-Lavalin to build $650 million froth treatment plant: Client not disclosed, but reported to be CNRL". Alberta Oil. http://www.albertaoilmagazine.com/2011/11/snc-lavalin-to-build-650-froth-treatment-plant/. 
  13. ↑ Song, Lisa (June 26, 2012). "A Dilbit Primer: How It's Different from Conventional Oil". InsideClimate News. https://insideclimatenews.org/news/26062012/dilbit-primer-diluted-bitumen-conventional-oil-tar-sands-alberta-kalamazoo-keystone-xl-enbridge/. 
  14. ↑ McGowan, Elizabeth; Song, Lisa (June 26, 2012). "The Dilbit Disaster: Inside The Biggest Oil Spill You've Never Heard Of". InsideClimate News. https://insideclimatenews.org/news/26062012/dilbit-diluted-bitumen-enbridge-kalamazoo-river-marshall-michigan-oil-spill-6b-pipeline-epa/. 
  15. ↑ "Kalamazoo River Spill Yields Record Fine", Living on Earth, July 6, 2012. Lisa Song, a reporter for InsideClimate News, interviewed by Bruce Gellerman. Retrieved 2013-01-01.
  16. ↑ Elizabeth Shogren (August 16, 2012). "When This Oil Spills, It's 'A Whole New Monster'". NPR All Things Considered. https://www.npr.org/2012/08/16/158025375/when-this-oil-spills-its-a-whole-new-monster. "Tar sands oil has to be diluted to make it liquid enough to flow through a pipeline. But once it's back out in the environment, the chemicals that liquefied it evaporate. That leaves the heavy stuff behind." 
  17. ↑ Smith, Lindsey (July 25, 2013). "3 years and nearly $1 billion later, cleanup of Kalamazoo River oil spill continues". Michigan Radio: The Environment Report. http://michiganradio.org/post/3-years-and-nearly-1-billion-later-cleanup-kalamazoo-river-oil-spill-continues. 
  18. ↑ A Review of the Pipeline Safety, Regulatory Certainty, and Job Creation Act of 2011: Hearing Before the Subcommittee on Railroads, Pipelines, and Hazardous Materials of the Committee on Transportation and Infrastructure, House of Representatives, One Hundred Thirteenth Congress, Second Session. United States Government Publishing Office. May 20, 2014. https://books.google.com/books?id=4fPdZM0EiSIC&pg=PR7. 
  19. ↑ Been, Jenny (Sep 2011), Comparison of the Corrosivity of Dilbit and Conventional Crude, Alberta: Alberta Innovates Energy and Environmental Solutions, p. 25, http://www.ai-ees.ca/media/6860/1919_corrosivity_of_dilbit_vs_conventional_crude-nov28-11_rev1.pdf, retrieved 8 Mar 2014, "the Alberta systems (with a large percentage of dilbit lines) experienced comparable internal corrosion failure rates than the U.S. systems (predominantly conventional crude lines)." 
  20. ↑ Dettman, Heather D. (23 Oct 2012), "Diluted Bitumen Chemical & Physical Properties", NAS Committee for a Study of Pipeline Transportation of Diluted Bitumen - Second Meeting (Toronto, Canada: Natural Resources Canada), http://onlinepubs.trb.org/onlinepubs/dilbit/Dettman102312.pdf, retrieved 8 Mar 2014  Dilbit has low corrosivity under pipeline conditions.
  21. ↑ A Safer World Through Corrosion Knowledge: How Corrosive is Heavy Crude?, NACE Northern Area Eastern Conference, Toronto, Ontario, Canada: Transportation Research Board, National Academy of Sciences, Oct 2012, Slide 43 ("Overall Summary from the Conference"), http://onlinepubs.trb.org/onlinepubs/dilbit/Papavinasam013113.pdf, retrieved 8 Mar 2014, "Under pipeline operating conditions[, d]ilbit is no different than other crude oils" 
  22. ↑ "EPA Comment Letter - US Environmental Protection Agency". April 22, 2013. http://www.epa.gov/compliance/nepa/keystone-xl-project-epa-comment-letter-20130056.pdf. 
  23. ↑ "Exploring What Oil Spills Do to Fresh Water | IISD-ELA". 2017-11-07. https://www.iisd.org/ela/blog/research-highlights/exploring-oil-spills/. 
  24. ↑ 24.0 24.1 Johannessen, Sophia C.; Greer, Charles W.; Hannah, Charles G.; King, Thomas L.; Lee, Kenneth; Pawlowicz, Rich; Wright, Cynthia A. (2020-01-01). "Fate of diluted bitumen spilled in the coastal waters of British Columbia, Canada" (in en). Marine Pollution Bulletin 150: 110691. doi:10.1016/j.marpolbul.2019.110691. ISSN 0025-326X. PMID 31744609. 
  25. ↑ 25.0 25.1 "Deliberating on dilbit" (in en). 2019-09-24. https://www.queensu.ca/research/features/deliberating-dilbit. 
  26. ↑ Cederwall, Jeffrey; Black, Tyler A.; Blais, Jules M.; Hanson, Mark L.; Hollebone, Bruce P.; Palace, Vince P.; Rodríguez-Gil, José Luis; Greer, Charles W. et al. (May 2020). "Life under an oil slick: response of a freshwater food web to simulated spills of diluted bitumen in field mesocosms". Canadian Journal of Fisheries and Aquatic Sciences 77 (5): 779–788. doi:10.1139/cjfas-2019-0224. ISSN 0706-652X. https://www.nrcresearchpress.com/doi/pdf/10.1139/cjfas-2019-0224. 
  27. ↑ Black, Tyler (December 2019). "The effects of a simulated spill of diluted bitumen on invertebrates in a boreal lake environment". MSC Thesis. https://mspace.lib.umanitoba.ca/handle/1993/34475. 

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