Chemistry:K-selectride
From HandWiki
K-selectride is the organoboron compound with the formula KBH(C
4H
9)
3. It is the potassium salt of tri(sec-butyl)borohydride. The compound is sold as solution in THF. It is a strong reducing agent. Solutions are pyrophoric and highly reactive toward water and protic compounds. It is handled using air-free technique. It is produced by the reaction of tri(sec-butyl)borane with potassium hydride. The reagent is used to reduce ketones to alcohols.[1]
Related compounds
- Lithium trisiamylborohydride[2]
- Lithium triethylborohydride ("Super hydride")
- L-selectride Li[(CH
3CH
2CH(CH
3))
3BH]
References
- ↑ Hubbard, John L. (2001). "Potassium Tri- sec -butylborohydride". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rp253. ISBN 0-471-93623-5.
- ↑ Zaidlewicz, Marek; Brown, Herbert C. (2001). "Lithium Trisiamylborohydride". Encyclopedia of Reagents for Organic Synthesis (EROS). doi:10.1002/047084289X.rl151. ISBN 0-471-93623-5.
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