Chemistry:Kynal
Kynal was a brand name for a series of aluminium alloys developed and originally produced by the British chemical manufacturer Imperial Chemical Industries (ICI).[1] The name was derived from Kynoch, an existing ICI trademark for ammunition, and aluminium. It was largely used as substitute for Alclad, a popular corrosion-resistant aluminium alloy.
ICI produced Kynal in quantity at a facility in Waunarlwydd, outside Swansea. The material was extensively used by the British aviation industry during the Second World War, being recognised as a strategic resource. Numerous variations upon the material were devised by ICI around this time. During the 1950s, British Railways became a key consumer of Kynal, using the material on numerous members of its new fleet of diesel traction, including the first generation diesel multiple units (DMUs). By the twenty-first century, the material was largely considered to be obsolete, while the Waunarlwydd chemical works was permanently closed during the 2000s.
History
A key facility involved in the production of Kynal was the Ministry of Aircraft Production's factory at Waunarlwydd,[2] near Swansea. ICI built and operated the plant on the government's behalf.[3] Functionally, Kynal was similar to, and could be a substitute for, Alclad.[4] Applications included various forged items, including pipework, vessels, and heat exchangers, as well as fuselage elements of aircraft.[5][6] By 1938, the material was being producing at a very high volume as a consequence of the European powers having entered a period of rearmament around the time of Munich crisis, which led into the Second World War.[7]
During the postwar era, Kynal continued to hold its strategic importance.[8] The material proliferated throughout British engineering throughout the 1950s and 1960s; it began to be used in the frames of road vehicles during the mid 1950s.[9] Kynal was used extensively for British Railways' modernisation of the 1950s, specifically in the construction of the publicly-owned organisation's new diesel fleet.[10] The majority of the 'lightweight' diesel multiple units (DMUs) featured the material.[11] Around the same era, the company was also involved in studies into the use of Kynal as a roofing material.[12]
By the twenty-first century, Kynal was largely considered to be obsolete as a material.[13] During the 2000s, the original Waunarlwydd plant, which was by then owned by Alcoa, was closed down.[14][15] Despite this, research efforts into fields such as battery technology have involved the use of Kynal.[16]
Table
Al | Cu | Mg | Si | Mn | Ni | Zn | Others | ||
---|---|---|---|---|---|---|---|---|---|
% | |||||||||
Kynal P5 | ≥99.5 | Pure aluminium [17] | |||||||
Kynal P10 | ≥99 | ||||||||
Aluminium–silicon alloys | |||||||||
Kynal PA15 | 12 | Brazing wire [18][19] | |||||||
Kynal PA16 | 5 | ||||||||
Kynal PA17 | 5 | ||||||||
Aluminium–manganese alloys | |||||||||
Kynal PA19 | 1.25 | [20] | |||||||
Aluminium–magnesium alloys | |||||||||
Kynal M35/1 | 2 | [21] | |||||||
Kynal M35/2 | 3 | ||||||||
Kynal M36 | 5 | ||||||||
Kynal M37 | 7 | ||||||||
Aluminium–magnesium–silicon alloys | |||||||||
Kynal M39/1 | 0.7 | 0.5 | [22] | ||||||
Kynal M39/2 | 0.7 | 1 | |||||||
Aluminium–copper alloys | |||||||||
Kynal 90 | 2.2 | 0.3 | [23] | ||||||
Kynal C65 | 4 | 0.6 | 0.5 | [23] | |||||
Kynal C66 | 4.4 | 0.6 | 0.7 | 0.6 | |||||
Kynal C67 | 4.4 | 0.6 | 0.7 | 0.6 | |||||
Kynal C69 | 1 | 1 | [22] | ||||||
Nickel–aluminium alloys | |||||||||
Kynal Y88 | 2.6 | 1 | 1 | 1 | 0.1% Ti | [23] | |||
Kynal Y92 | 4 | 1.5 | 2 | ||||||
Aluminium–zinc alloys | |||||||||
Kynal Z93 | 0.4 | 2.7 | 5.3 | [24] | |||||
Kynal-Core C65A | Pure aluminium-clad forms of the corresponding alloys [25] | ||||||||
Kynal-Core C66A | |||||||||
Kynal-Core C67A | |||||||||
Kynal-Core C68A | |||||||||
Kynal-Core Z93A |
See also
- Kycube, a similarly named series of copper beryllium alloys produced by IMI.
References
Citations
- ↑ "ICI Metals Division". http://www.gracesguide.co.uk/ICI_Metals_Division.
- ↑ Template:Location
- ↑ "ICI Metal Works; Alcoa Aluminium Factory, Waunarlwydd, Gowerton". http://www.coflein.gov.uk/en/site/414966/details/ici-metal-worksalcoa-aluminium-factory-waunarlwydd-gowertonwith-camouflage-scheme.
- ↑ Ross 2013, p. 50.
- ↑ J. H. Argyris; S. Kelsey (1 May 1959). "The Analysis of Fuselages of Arbitrary Cross‐section and Taper: A DSIR Sponsored Research Programme on the Development and Application of the Matrix Force Method and the Digital Computer". Aircraft Engineering and Aerospace Technology. doi:10.1108/eb033113. ISSN 0002-2667. https://www.emerald.com/insight/content/doi/10.1108/eb033113/full/html?skipTracking=true.
- ↑ "Curtailing Corrosion in Chemical and Petroleum Engineering". Anti-Corrosion Methods and Materials 5 (6): 195–196. 1 August 1958. doi:10.1108/eb019457. ISSN 0003-5599. https://www.emerald.com/insight/content/doi/10.1108/eb019457/full/html.
- ↑ "ICI Advertisement". Flight: 14. 9 June 1938. https://www.flightglobal.com/pdfarchive/view/1938/1938%20-%201624.html.
- ↑ "The British Light-alloy Industry". Flight: 808–811. 10 June 1955. https://www.flightglobal.com/pdfarchive/view/1955/1955%20-%200813.html.
- ↑ "Kynal lightens". The Automobile Engineer. 1956. p. 125. https://books.google.com/books?id=hLknAAAAMAAJ&q=%22Kynal.
- ↑ Carter, R. S. (1963). British Railways Main-Line Diesels. Ian Allan Publishing. pp. 28–29.
- ↑ "Going Ahead with 'Kynal'". http://www.gracesguide.co.uk/File:Im1958v206-p434da.jpg.
- ↑ Kynal, p. 173, at Google Books
- ↑ Ross 2013, pp. 9, 50.
- ↑ "Jobs cut at metal plant". BBC News. 21 January 2003. http://news.bbc.co.uk/1/hi/wales/2680369.stm.
- ↑ "298 jobs to go as factory shuts". BBC News. 21 November 2006. http://news.bbc.co.uk/1/hi/wales/6170326.stm.
- ↑ "JP3363910B2: Non-aqueous thin battery". Google =. 1998. https://patents.google.com/patent/JP3363910B2/en.
- ↑ Metallic Materials Specification, p. 9.
- ↑ Metallic Materials Specification, p. 17.
- ↑ 'Kynal' Solders and 'Kynal' Flux for Soldering Aluminium. ICI. 1953.
- ↑ Metallic Materials Specification, p. 12.
- ↑ Metallic Materials Specification, p. 26.
- ↑ 22.0 22.1 Metallic Materials Specification, p. 34.
- ↑ 23.0 23.1 23.2 Metallic Materials Specification, p. 41.
- ↑ Metallic Materials Specification, p. 47.
- ↑ Metallic Materials Specification, p. 50.
Bibliography
- Ross, R. B. (2013). Metallic Materials Specification Handbook (4 ed.). Springer Science & Business Media. ISBN 9781461534822.
- Frick, John P., ed (2000). Woldman's Engineering Alloys. Materials data series. ASM International. pp. 667–668. ISBN 9780871706911.
External links
Original source: https://en.wikipedia.org/wiki/Kynal.
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