Chemistry:Michaelis–Becker reaction
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Short description: Chemical reaction
The Michaelis–Becker reaction is the reaction of a hydrogen (thio)phosphonate with a base, followed by a nucleophilic substitution of phosphorus on a haloalkane, to give an alkyl (thio)phosphonate.[1] Yields of this reaction are often lower than the corresponding Michaelis–Arbuzov reaction.[2][3]
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Further reading
- Savignac, Philippe; Iorga, Bogdan (2003). Modern phosphonate chemistry. CRC Press. ISBN 978-0-8493-1099-7. https://books.google.com/books?id=iH5PBtf3_MQC&pg=PA411.
References
- ↑ Almasi, Lucreţia (1971). "The Sulfur–Phosphorus Bond". in Senning, Alexander. Sulfur in Organic and Inorganic Chemistry. 1. New York: Marcel Dekker. p. 56. ISBN 0-8247-1615-9.
- ↑ Fletcher, M.D. Organophosphorus Reagents; Murphy, P.J. Ed.; University Press: Oxford, 2002; pp. 185.
- ↑ Murphy, Dr. Patrick J (2004). Organophosphorus reagents: a practical approach in chemistry. Oxford University Press. ISBN 978-0-19-850262-3. https://books.google.com/books?id=mBfS8kNZA5gC&pg=PA185.
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