Physics:Perpendicular paramagnetic bond

From HandWiki

A perpendicular paramagnetic bond is a type of chemical bond (in contrast to covalent or ionic bonds) that does not exist under normal, atmospheric conditions.[1] Such a phenomenon was first hypothesized through simulation to exist in the atmospheres of white dwarf stars[2] whose magnetic fields, on the order of 105 teslas,[1] could allow such interactions to exist. In a very strong magnetic field, excited electrons in molecules may be stabilized, causing these molecules to abandon their original orientations parallel to the magnetic field and instead lie perpendicular to it.[3] Normally, at such intense temperatures as those near a white dwarf, more common molecular bonds cannot form and existing ones decompose.[2]

References

  1. 1.0 1.1 Lange, K. K.; Tellgren, E. I.; Hoffmann, M. R.; Helgaker, T. (19 July 2012). "A Paramagnetic Bonding Mechanism for Diatomics in Strong Magnetic Fields". Science 337 (6092): 327–331. doi:10.1126/science.1219703. PMID 22822146. Bibcode2012Sci...337..327L. 
  2. 2.0 2.1 Yirka, Bob (July 20, 2012). "Chemists discover new type of molecular bond near white dwarf stars" (in en-us). https://phys.org/news/2012-07-chemists-molecular-bond-white-dwarf.html. 
  3. Merali, Zeeya (19 July 2012). "Magnetic fields boost atoms' bonding skills". Nature. doi:10.1038/nature.2012.11045. https://www.nature.com/articles/nature.2012.11045.