View source for Physics:Energy

{{Short description|Property that makes changes possible}}
{{pp-semi-indef}}
{{Infobox physical quantity
| name = Energy
| image = Energy Arc (central electrode of a Plasma Lamp).jpg
| caption = A [[Physics:Plasma globe|plasma globe]], using [[Physics:Electrical energy|electrical energy]] to create [[Physics:Plasma|plasma]], [[Physics:Light|light]], [[Physics:Heat|heat]], [[Physics:Kinetic energy|movement]] and a faint [[Physics:Sound|sound]]
| unit = [[Joule|joule]]
| otherunits = [[Kilowatt-hour|kW⋅h]], BTU, [[Calorie|calorie]], [[Physics:Electronvolt|eV]], [[Physics:Erg|erg]], [[Foot-pound (energy)|foot-pound]]
| symbols = ''E''
| baseunits = J = kg⋅m<sup>2</sup>⋅s<sup>−2</sup>
| dimension = '''M''' '''L'''<sup>2</sup> '''T'''<sup>−2</sup>
| extensive = yes
| conserved = yes
| derivations =
|image_upright=1.15}}
{{Thermodynamics}}
In [[Physics:Physics|physics]], '''energy''' ({{etymology|grc|''{{wikt-lang|grc|ἐνέργεια}}'' ({{grc-transl|ἐνέργεια}})|activity}}) is the [[Physics:Physical quantity|quantitative]] [[Physics:Physical property|property]] that is transferred to a [[Philosophy:Physical body|body]] or to a [[Physics:Physical system|physical system]], recognizable in the performance of [[Physics:Work (thermodynamics)|work]] and in the form of [[Physics:Heat|heat]] and [[Physics:Light|light]]. Energy is a [[Conservation law|conserved quantity]]—the law of [[Physics:Conservation of energy|conservation of energy]] states that energy can be [[Physics:Energy transformation|converted]] in form, but not created or destroyed. The unit of [[Measurement|measurement]] for energy in the [[International System of Units]] (SI) is the [[Joule|joule]] (J).

Common forms of energy include the [[Physics:Kinetic energy|kinetic energy]] of a moving object, the [[Physics:Potential energy|potential energy]] stored by an object (for instance due to its position in a [[Physics:Classical field theory|field]]), the [[Physics:Elastic energy|elastic energy]] stored in a solid object, [[Chemistry:Chemical energy|chemical energy]] associated with [[Chemistry:Chemical reaction|chemical reaction]]s, the [[Physics:Radiant energy|radiant energy]] carried by [[Physics:Electromagnetic radiation|electromagnetic radiation]], and the [[Physics:Internal energy|internal energy]] contained within a [[Physics:Thermodynamic system|thermodynamic system]]. All living organisms constantly take in and release energy.

Due to [[Mass–energy equivalence|mass–energy equivalence]], any object that has [[Physics:Mass|mass]] when stationary (called [[Physics:Rest mass|rest mass]]) also has an equivalent amount of energy whose form is called [[Physics:Rest mass#Rest energy|rest energy]], and any additional energy (of any form) acquired by the object above that rest energy will increase the object's total mass just as it increases its total energy. 

Human civilization requires energy to function, which it gets from energy resources such as fossil fuels, [[Physics:Nuclear fuel|nuclear fuel]], or [[Engineering:Renewable energy|renewable energy]]. The Earth's [[Earth:Climate|climate]] and [[Earth:Ecosystem|ecosystem]]s processes are driven by the energy the planet receives from the Sun (although a small amount is also contributed by [[Earth:Geothermal energy|geothermal energy]]).

==Forms==

[[File:Lightning over Oradea Romania zoom.jpg|thumb|In a typical [[Astronomy:Lightning|lightning]] strike, 500 megajoules of electric potential energy is converted into the same amount of energy in other forms, mostly light energy, sound energy and thermal energy.]]
[[File:Hot metalwork.jpg|thumb|[[Physics:Thermal energy|Thermal energy]] is energy of microscopic constituents of matter, which may include both kinetic and potential energy.]]

The total energy of a [[Philosophy:System|system]] can be subdivided and classified into potential energy, kinetic energy, or combinations of the two in various ways. [[Physics:Kinetic energy|Kinetic energy]] is determined by the [[Physics:Motion|movement]] of an object – or the [[Physics:Statistical mechanics|composite motion]] of the components of an object – and [[Physics:Potential energy|potential energy]] reflects the potential of an object to have motion, and generally is a function of the position of an object within a [[Physics:Field|field]] or may be stored in the field itself.

While these two categories are sufficient to describe all forms of energy, it is often convenient to refer to particular combinations of potential and kinetic energy as its own form. For example, the sum of translational and [[Rotational energy|rotational]] kinetic and potential energy within a system is referred to as [[Physics:Mechanical energy|mechanical energy]], whereas nuclear energy refers to the combined potentials within an atomic nucleus from either the [[Physics:Nuclear force|nuclear force]] or the [[Physics:Weak force|weak force]], among other examples.<ref>{{Cite web |title=Nuclear Energy {{!}} Definition, Formula & Examples {{!}} nuclear-power.com |url=https://www.nuclear-power.com/nuclear-power/nuclear-energy/ |access-date=2022-07-06 |website=Nuclear Power |language=en-us |archive-date=2022-07-06 |archive-url=https://web.archive.org/web/20220706153815/https://www.nuclear-power.com/nuclear-power/nuclear-energy/ |url-status=live }}</ref>

{| class="wikitable" style="text-align:center;"
|+Some forms of energy (that an object or system can have as a measurable property)
! Type of energy !! Description
|-
|[[Physics:Mechanical energy|Mechanical]]
|the sum of [[Physics:Macroscopic|macroscopic]] translational and rotational kinetic and potential energies
|-
|[[Physics:Electrical energy|Electric]]
|potential energy due to or stored in electric fields
|-
|[[Physics:Magnetic energy|Magnetic]]
|potential energy due to or stored in magnetic fields
|-
|[[Physics:Gravitational energy|Gravitational]]
|potential energy due to or stored in gravitational fields
|-
|[[Chemistry:Chemical energy|Chemical]]
|potential energy due to chemical bonds
|-
|[[Physics:Ionization energy|Ionization]]
|potential energy that [[Physics:Binding energy|binds]] an electron to its atom or molecule
|-
|[[Physics:Nuclear binding energy|Nuclear]]
|potential energy that [[Physics:Binding energy|binds]] nucleons to form the [[Physics:Atomic nucleus|atomic nucleus]] (and nuclear reactions)
|-
|[[Physics:Quantum chromodynamics binding energy|Chromodynamic]]
|potential energy that [[Physics:Binding energy|binds]] [[Physics:Quark|quark]]s to form [[Physics:Hadron|hadron]]s
|-
|[[Physics:Elastic energy|Elastic]]
|potential energy due to the deformation of a material (or its container) exhibiting a restorative force as it returns to its original shape
|-
|[[Physics:Mechanical wave|Mechanical wave]]
|kinetic and potential energy in an elastic material due to a propagating [[Oscillation|oscillation]] of matter
|-
|[[Physics:Sound energy|Sound wave]]
|kinetic and potential energy in a material due to a sound propagated wave (a particular type of mechanical wave)
|-
|[[Physics:Radiant energy|Radiant]]
|[[Physics:Photon energy|potential energy]] stored in the fields of waves propagated by [[Physics:Electromagnetic radiation|electromagnetic radiation]], including [[Physics:Light|light]]
|-
|Rest
|potential energy due to an object's rest mass
|-
|[[Physics:Heat|Thermal]] 
|kinetic energy of the microscopic motion of particles, a kind of disordered equivalent of mechanical energy 
|-
|}

==History==
[[File:Thomas Young (scientist).jpg|thumb|upright|Thomas Young, the first person to use the term "energy" in the modern sense]]
The word ''energy'' derives from the {{lang-grc|ἐνέργεια|energeia|activity, operation}},<ref>{{cite web |url=http://www.etymonline.com/index.php?term=energy |title=Energy |work=Online Etymology Dictionary |last=Harper |first=Douglas |access-date=May 1, 2007 |url-status=live |archive-url=https://web.archive.org/web/20071011122441/http://etymonline.com/index.php?term=energy |archive-date=October 11, 2007 }}</ref> which possibly appears for the first time in the work of [[Biography:Aristotle|Aristotle]] in the 4th century BC. In contrast to the modern definition, energeia was a qualitative philosophical concept, broad enough to include ideas such as happiness and pleasure.

In the late 17th century, Gottfried Leibniz proposed the idea of the {{lang-lat|[[Physics:Vis viva|vis viva]]}}, or living force, which defined as the product of the mass of an object and its velocity squared; he believed that total ''vis viva'' was conserved. To account for slowing due to friction, Leibniz theorized that thermal energy consisted of the motions of the constituent parts of matter, although it would be more than a century until this was generally accepted. The modern analog of this property, [[Physics:Kinetic energy|kinetic energy]], differs from ''vis viva'' only by a factor of two. Writing in the early 18th century, [[Biography:Émilie du Châtelet|Émilie du Châtelet]] proposed the concept of [[Physics:Conservation of energy|conservation of energy]] in the marginalia of her French language translation of Newton's ''[[Physics:Philosophiæ Naturalis Principia Mathematica|Principia Mathematica]]'', which represented the first formulation of a conserved measurable quantity that was distinct from [[Physics:Momentum|momentum]], and which would later be called "energy".

In 1807, [[Biography:Thomas Young (scientist)|Thomas Young]] was possibly the first to use the term "energy" instead of ''vis viva'', in its modern sense.<ref>{{Cite book| last = Smith | first = Crosbie | title = The Science of Energy – a Cultural History of Energy Physics in Victorian Britain | publisher = The University of Chicago Press | year = 1998 | isbn = 978-0-226-76420-7}}</ref> Gustave-Gaspard Coriolis described "[[Physics:Kinetic energy|kinetic energy]]" in 1829 in its modern sense, and in 1853, [[Biography:William John Macquorn Rankine|William Rankine]] coined the term "[[Physics:Potential energy|potential energy]]". The law of [[Physics:Conservation of energy|conservation of energy]] was also first postulated in the early 19th century, and applies to any [[Physics:Isolated system|isolated system]]. It was argued for some years whether heat was a physical substance, dubbed the [[Physics:Caloric theory|caloric]], or merely a physical quantity, such as [[Physics:Momentum|momentum]]. In 1845 [[Biography:James Prescott Joule|James Prescott Joule]] discovered the link between mechanical work and the generation of heat.

These developments led to the theory of conservation of energy, formalized largely by William Thomson ([[Biography:Lord Kelvin|Lord Kelvin]]) as the field of [[Physics:Thermodynamics|thermodynamics]]. Thermodynamics aided the rapid development of explanations of chemical processes by [[Biography:Rudolf Clausius|Rudolf Clausius]], [[Biography:Josiah Willard Gibbs|Josiah Willard Gibbs]], and [[Biography:Walther Nernst|Walther Nernst]]. It also led to a mathematical formulation of the concept of [[Physics:Entropy|entropy]] by Clausius and to the introduction of laws of [[Physics:Radiant energy|radiant energy]] by Jožef Stefan. According to [[Physics:Noether's theorem|Noether's theorem]], the conservation of energy is a consequence of the fact that the laws of physics do not change over time.<ref name="jphysics">{{Cite book| last =Lofts| first =G|author2=O'Keeffe D |display-authors=0 | title=Jacaranda Physics 1| publisher =John Wiley & Sons Australia Ltd. | year =2004| location = Milton, Queensland, Australia| page = 286| chapter=11 – Mechanical Interactions| edition=2| isbn=978-0-7016-3777-4}}</ref> Thus, since 1918, theorists have understood that the law of [[Physics:Conservation of energy|conservation of energy]] is the direct mathematical consequence of the [[Physics:Translational symmetry|translational symmetry]] of the quantity [[Physics:Conjugate variables|conjugate]] to energy, namely time.

==Units of measure==
[[File:Joule's Apparatus (Harper's Scan).png|thumb|right|Joule's apparatus for measuring the mechanical equivalent of heat. A descending weight attached to a string causes a paddle immersed in water to rotate.]]
{{Main|Units of energy}}

In 1843, James Prescott Joule independently discovered the mechanical equivalent in a series of experiments. The most famous of them used the "Joule apparatus": a descending weight, attached to a string, caused rotation of a paddle immersed in water, practically insulated from heat transfer. It showed that the gravitational [[Physics:Potential energy|potential energy]] lost by the weight in descending was equal to the [[Physics:Internal energy|internal energy]] gained by the water through [[Physics:Friction|friction]] with the paddle.

In the [[International System of Units]] (SI), the unit of energy is the joule, named after Joule. It is a [[SI derived unit|derived unit]]. It is equal to the energy expended (or [[Physics:Work|work]] done) in applying a force of one newton through a distance of one metre. However energy is also expressed in many other units not part of the SI, such as [[Physics:Erg|erg]]s, [[Calorie|calorie]]s, [[British thermal unit]]s, [[Kilowatt-hour|kilowatt-hour]]s and kilocalories, which require a conversion factor when expressed in SI units.

The SI unit of energy rate (energy per unit time) is the [[Watt|watt]], which is a joule per second. Thus, one joule is one watt-second, and 3600 joules equal one watt-hour. The CGS energy unit is the [[Physics:Erg|erg]] and the [[Imperial and US customary measurement systems|imperial and US customary]] unit is the foot pound. Other energy units such as the [[Physics:Electronvolt|electronvolt]], food calorie or thermodynamic kcal (based on the temperature change of water in a heating process), and [[British thermal unit|BTU]] are used in specific areas of science and commerce.

==Scientific use==

===Classical mechanics===
{{Classical mechanics}}

In classical mechanics, energy is a conceptually and mathematically useful property, as it is a [[Conserved quantity|conserved quantity]]. Several formulations of mechanics have been developed using energy as a core concept.

[[Physics:Work|Work]], a function of energy, is force times distance.

: <math> W = \int_C \mathbf{F} \cdot \mathrm{d} \mathbf{s}</math>

This says that the work (<math>W</math>) is equal to the [[Line integral|line integral]] of the [[Physics:Force|force]] '''F''' along a path ''C''; for details see the mechanical work article. Work and thus energy is frame dependent. For example, consider a ball being hit by a bat. In the center-of-mass reference frame, the bat does no work on the ball. But, in the reference frame of the person swinging the bat, considerable work is done on the ball.

The total energy of a system is sometimes called the Hamiltonian, after [[Biography:William Rowan Hamilton|William Rowan Hamilton]]. The classical equations of motion can be written in terms of the Hamiltonian, even for highly complex or abstract systems. These classical equations have remarkably direct analogs in nonrelativistic quantum mechanics.<ref>[https://web.archive.org/web/20071011135413/http://www.sustech.edu/OCWExternal/Akamai/18/18.013a/textbook/HTML/chapter16/section03.html The Hamiltonian] MIT OpenCourseWare website 18.013A Chapter 16.3 Accessed February 2007</ref>

Another energy-related concept is called the [[Lagrangian mechanics|Lagrangian]], after [[Biography:Joseph-Louis Lagrange|Joseph-Louis Lagrange]]. This formalism is as fundamental as the Hamiltonian, and both can be used to derive the equations of motion or be derived from them. It was invented in the context of [[Physics:Classical mechanics|classical mechanics]], but is generally useful in modern physics. The Lagrangian is defined as the kinetic energy ''minus'' the potential energy. Usually, the Lagrange formalism is mathematically more convenient than the Hamiltonian for non-conservative systems (such as systems with friction).

[[Physics:Noether's theorem|Noether's theorem]] (1918) states that any differentiable symmetry of the action of a physical system has a corresponding conservation law. Noether's theorem has become a fundamental tool of modern theoretical physics and the calculus of variations. A generalisation of the seminal formulations on constants of motion in Lagrangian and Hamiltonian mechanics (1788 and 1833, respectively), it does not apply to systems that cannot be modeled with a Lagrangian; for example, dissipative systems with continuous symmetries need not have a corresponding conservation law.

===Chemistry===<!-- courtesy note per WP:LINK2SECT: redirect Energy (chemistry) links here -->
In the context of [[Chemistry:Chemistry#Energy|chemistry]], [[Chemistry:Chemical energy|energy]] is an attribute of a substance as a consequence of its atomic, molecular, or aggregate structure. Since a chemical transformation is accompanied by a change in one or more of these kinds of structure, it is usually accompanied by a decrease, and sometimes an increase, of the total energy of the substances involved. Some energy may be transferred between the surroundings and the reactants in the form of heat or light; thus the products of a reaction have sometimes more but usually less energy than the reactants. A reaction is said to be [[Physics:Exothermic process|exothermic]] or exergonic if the final state is lower on the energy scale than the initial state; in the less common case of [[Physics:Endothermic process|endothermic]] reactions the situation is the reverse. [[Chemistry:Chemical reaction|Chemical reaction]]s are usually not possible unless the reactants surmount an energy barrier known as the [[Chemistry:Activation energy|activation energy]]. The ''speed'' of a chemical reaction (at a given temperature&nbsp;''T'') is related to the activation energy&nbsp;''E'' by the Boltzmann's population factor&nbsp;e<sup>−''E''/''kT''</sup>; that is, the probability of a molecule to have energy greater than or equal to&nbsp;''E'' at a given temperature&nbsp;''T''. This exponential dependence of a reaction rate on temperature is known as the [[Arrhenius equation]]. The activation energy necessary for a chemical reaction can be provided in the form of thermal energy.

===Biology<!-- courtesy note per WP:LINK2SECT: redirect Energy (biology) links here -->===
[[File:Energy and life.svg|thumb|Basic overview of [[Biology:Bioenergetics|energy and human life]]]]
{{anchor|Biology}}In [[Biology:Biology#Energy|biology]], energy is an attribute of all biological systems, from the biosphere to the smallest living organism. Within an organism it is responsible for growth and development of a biological [[Biology:Cell|cell]] or [[Biology:Organelle|organelle]] of a biological organism. Energy used in [[Biology:Respiration (physiology)|respiration]] is stored in substances such as [[Chemistry:Carbohydrate|carbohydrate]]s (including sugars), [[Chemistry:Lipid|lipid]]s, and [[Biology:Protein|protein]]s stored by [[Biology:Cell|cells]]. In human terms, the [[Human equivalent|human equivalent]] (H-e) (Human energy conversion) indicates, for a given amount of energy expenditure, the relative quantity of energy needed for human [[Biology:Metabolism|metabolism]], using as a standard an average human energy expenditure of 12,500&nbsp;kJ per day and a [[Basal metabolic rate|basal metabolic rate]] of 80 watts. For example, if our bodies run (on average) at 80 watts, then a light bulb running at 100 watts is running at 1.25 human equivalents (100 ÷ 80) i.e. 1.25 H-e. For a difficult task of only a few seconds' duration, a person can put out thousands of watts, many times the 746 watts in one official horsepower. For tasks lasting a few minutes, a fit human can generate perhaps 1,000 watts. For an activity that must be sustained for an hour, output drops to around 300; for an activity kept up all day, 150 watts is about the maximum.<ref>{{cite web |url=http://www.uic.edu/aa/college/gallery400/notions/human%20energy.htm |title=Retrieved on May-29-09 |publisher=Uic.edu |access-date=2010-12-12 |url-status=live |archive-url=https://web.archive.org/web/20100604191319/http://www.uic.edu/aa/college/gallery400/notions/human%20energy.htm |archive-date=2010-06-04 }}</ref> The human equivalent assists understanding of energy flows in physical and biological systems by expressing energy units in human terms: it provides a "feel" for the use of a given amount of energy.<ref>Bicycle calculator – speed, weight, wattage etc. {{cite web |url=http://bikecalculator.com/ |title=Bike Calculator |access-date=2009-05-29 |url-status=live |archive-url=https://web.archive.org/web/20090513091201/http://bikecalculator.com/ |archive-date=2009-05-13 }}.</ref>

Sunlight's radiant energy is also captured by plants as ''chemical potential energy'' in [[Earth:Photosynthesis|photosynthesis]], when carbon dioxide and water (two low-energy compounds) are converted into carbohydrates, lipids, proteins and oxygen. Release of the energy stored during photosynthesis as heat or light may be triggered suddenly by a spark in a forest fire, or it may be made available more slowly for animal or human metabolism when organic molecules are ingested and [[Biology:Catabolism|catabolism]] is triggered by [[Biology:Enzyme|enzyme]] action.

All living creatures rely on an external source of energy to be able to grow and reproduce – radiant energy from the Sun in the case of green plants and chemical energy (in some form) in the case of animals. The daily 1500–2000&nbsp;Calories (6–8&nbsp;MJ) recommended for a human adult are taken as food molecules, mostly carbohydrates and fats, of which [[Chemistry:Glucose|glucose]] (C<sub>6</sub>H<sub>12</sub>O<sub>6</sub>) and [[Chemistry:Stearin|stearin]] (C<sub>57</sub>H<sub>110</sub>O<sub>6</sub>) are convenient examples. The food molecules are oxidized to [[Chemistry:Carbon dioxide|carbon dioxide]] and [[Chemistry:Water (molecule)|water]] in the [[Biology:Mitochondrion|mitochondria]]
<chem display="block">C6H12O6 + 6O2 -> 6CO2 + 6H2O</chem>
<chem display="block">C57H110O6 + (81 1/2) O2 -> 57CO2 + 55H2O</chem>
and some of the energy is used to convert [[Chemistry:Adenosine diphosphate|ADP]] into [[Chemistry:Adenosine triphosphate|ATP]]:
{{block indent|em=1.6|text=ADP + HPO<sub>4</sub><sup>2−</sup> → ATP + H<sub>2</sub>O}}
The rest of the chemical energy of the carbohydrate or fat are converted into heat: the ATP is used as a sort of "energy currency", and some of the chemical energy it contains is used for other [[Biology:Metabolism|metabolism]] when ATP reacts with OH groups and eventually splits into ADP and phosphate (at each stage of a [[Biology:Metabolic pathway|metabolic pathway]], some chemical energy is converted into heat). Only a tiny fraction of the original chemical energy is used for [[Physics:Work|work]]:<ref group=note>These examples are solely for illustration, as it is not the energy available for work which limits the performance of the athlete but the [[Physics:Power|power]] output (in case of a sprinter) and the [[Physics:Force|force]] (in case of a weightlifter).</ref>
:gain in kinetic energy of a sprinter during a 100&nbsp;m race: 4&nbsp;kJ
:gain in gravitational potential energy of a 150&nbsp;kg weight lifted through 2&nbsp;metres: 3&nbsp;kJ
:Daily food intake of a normal adult: 6–8&nbsp;MJ

It would appear that living organisms are remarkably [[Physics:Energy conversion efficiency|inefficient (in the physical sense)]] in their use of the energy they receive (chemical or radiant energy); most machines manage higher efficiencies. In growing organisms the energy that is converted to heat serves a vital purpose, as it allows the organism tissue to be highly ordered with regard to the molecules it is built from. The [[Physics:Second law of thermodynamics|second law of thermodynamics]] states that energy (and matter) tends to become more evenly spread out across the universe: to concentrate energy (or matter) in one specific place, it is necessary to spread out a greater amount of energy (as heat) across the remainder of the universe ("the surroundings").<ref group=note>[[Earth:Crystal|Crystal]]s are another example of highly ordered systems that exist in nature: in this case too, the order is associated with the transfer of a large amount of heat (known as the [[Physics:Lattice energy|lattice energy]]) to the surroundings.</ref> Simpler organisms can achieve higher energy efficiencies than more complex ones, but the complex organisms can occupy [[Biology:Ecological niche|ecological niche]]s that are not available to their simpler brethren. The conversion of a portion of the chemical energy to heat at each step in a metabolic pathway is the physical reason behind the pyramid of biomass observed in [[Earth:Ecology|ecology]]. As an example, to take just the first step in the food chain: of the estimated 124.7&nbsp;Pg/a of carbon that is [[Earth:Carbon fixation|fixed]] by [[Earth:Photosynthesis|photosynthesis]], 64.3&nbsp;Pg/a (52%) are used for the metabolism of green plants,<ref>Ito, Akihito; Oikawa, Takehisa (2004). "[http://www.terrapub.co.jp/e-library/kawahata/pdf/343.pdf Global Mapping of Terrestrial Primary Productivity and Light-Use Efficiency with a Process-Based Model.] {{webarchive|url=https://web.archive.org/web/20061002083948/http://www.terrapub.co.jp/e-library/kawahata/pdf/343.pdf |date=2006-10-02 }}" in Shiyomi, M. et al. (Eds.) ''Global Environmental Change in the Ocean and on Land.'' pp.&nbsp;343–58.</ref> i.e. reconverted into carbon dioxide and heat.

===Earth sciences===
In [[Earth:Earth science#earth's energy|geology]], [[Earth:Continental drift|continental drift]], [[Earth:Mountain|mountain ranges]], [[Earth:Volcano|volcano]]es, and [[Earth:Earthquake|earthquake]]s are phenomena that can be explained in terms of energy transformations in the Earth's interior,<ref>{{cite web |url=http://okfirst.ocs.ou.edu/train/meteorology/EnergyBudget.html |title=Earth's Energy Budget |publisher=Okfirst.ocs.ou.edu |access-date=2010-12-12 |url-status=live |archive-url=https://web.archive.org/web/20080827194704/http://okfirst.ocs.ou.edu/train/meteorology/EnergyBudget.html |archive-date=2008-08-27 }}</ref> while meteorological phenomena like wind, rain, [[Earth:Hail|hail]], snow, lightning, [[Earth:Tornado|tornado]]es and [[Physics:Tropical cyclone|hurricanes]] are all a result of energy transformations in our [[Astronomy:Atmosphere|atmosphere]] brought about by [[Physics:Solar energy|solar energy]].

Sunlight is the main input to [[Earth:Earth's energy budget|Earth's energy budget]] which accounts for its temperature and climate stability. Sunlight may be stored as gravitational potential energy after it strikes the Earth, as (for example when) water evaporates from oceans and is deposited upon mountains (where, after being released at a hydroelectric dam, it can be used to drive turbines or generators to produce electricity). Sunlight also drives most weather phenomena, save a few exceptions, like those generated by volcanic events for example. An example of a solar-mediated weather event is a hurricane, which occurs when large unstable areas of warm ocean, heated over months, suddenly give up some of their thermal energy to power a few days of violent air movement.

In a slower process, [[Physics:Radioactive decay|radioactive decay]] of atoms in the core of the Earth releases heat. This thermal energy drives [[Earth:Plate tectonics|plate tectonics]] and may lift mountains, via orogenesis. This slow lifting represents a kind of gravitational potential [[Engineering:Energy storage|energy storage]] of the thermal energy, which may later be transformed into active kinetic energy during landslides, after a triggering event. Earthquakes also release stored elastic potential energy in rocks, a store that has been produced ultimately from the same radioactive heat sources. Thus, according to present understanding, familiar events such as landslides and earthquakes release energy that has been stored as potential energy in the Earth's gravitational field or elastic strain (mechanical potential energy) in rocks. Prior to this, they represent release of energy that has been stored in heavy atoms since the collapse of long-destroyed supernova stars (which created these atoms).

===Cosmology===<!-- courtesy note per WP:LINK2SECT: redirect Energy (cosmology) links here -->
In [[Astronomy:Physical cosmology#Energy of the cosmos|cosmology and astronomy]] the phenomena of [[Astronomy:Star|star]]s, [[Astronomy:Nova|nova]], [[Astronomy:Supernova|supernova]], [[Astronomy:Quasar|quasar]]s and [[Astronomy:Gamma-ray burst|gamma-ray burst]]s are the universe's highest-output energy transformations of matter. All stellar phenomena (including solar activity) are driven by various kinds of energy transformations. Energy in such transformations is either from gravitational collapse of matter (usually molecular hydrogen) into various classes of astronomical objects (stars, black holes, etc.), or from nuclear fusion (of lighter elements, primarily hydrogen). The [[Physics:Nuclear fusion|nuclear fusion]] of hydrogen in the Sun also releases another store of potential energy which was created at the time of the [[Astronomy:Big Bang|Big Bang]]. At that time, according to theory, space expanded and the universe cooled too rapidly for hydrogen to completely fuse into heavier elements. This meant that hydrogen represents a store of potential energy that can be released by fusion. Such a fusion process is triggered by heat and pressure generated from gravitational collapse of hydrogen clouds when they produce stars, and some of the fusion energy is then transformed into sunlight.

{{anchor|Physics}}<!-- courtesy note per WP:LINK2SECT: Energy (physics) links here -->

===Quantum mechanics===
{{Main|Physics:Energy operator}}
In [[Physics:Quantum mechanics|quantum mechanics]], energy is defined in terms of the [[Physics:Hamiltonian (quantum mechanics)|energy operator]]
(Hamiltonian) as a time derivative of the [[Wave function|wave function]]. The [[Physics:Schrödinger equation|Schrödinger equation]] equates the energy operator to the full energy of a particle or a system. Its results can be considered as a definition of measurement of energy in quantum mechanics. The Schrödinger equation describes the space- and time-dependence of a slowly changing (non-relativistic) [[Wave function|wave function]] of quantum systems. The solution of this equation for a bound system is discrete (a set of permitted states, each characterized by an [[Physics:Energy level|energy level]]) which results in the concept of [[Physics:Quantum|quanta]]. In the solution of the Schrödinger equation for any oscillator (vibrator) and for electromagnetic waves in a vacuum, the resulting energy states are related to the frequency by Planck's relation: <math>E = h\nu</math> (where <math>h</math> is the [[Physics:Planck constant|Planck constant]] and <math>\nu</math> the frequency). In the case of an electromagnetic wave these energy states are called quanta of light or [[Physics:Photon|photon]]s.

===Relativity===
When calculating kinetic energy (work to accelerate a [[Physics:Mass|massive body]] from zero [[Physics:Speed|speed]] to some finite speed) relativistically – using Lorentz transformations instead of [[Physics:Newtonian mechanics|Newtonian mechanics]] – Einstein discovered an unexpected by-product of these calculations to be an energy term which does not vanish at zero speed. He called it rest energy: energy which every massive body must possess even when being at rest. The amount of energy is directly proportional to the mass of the body:

<math display="block"> E_0 = m_0 c^2 ,</math>
where
*''m''<sub>0</sub> is the rest mass of the body,
*''c'' is the [[Physics:Speed of light|speed of light]] in vacuum,
*<math>E_0</math> is the rest energy.

For example, consider [[Physics:Electron|electron]]–[[Physics:Positron|positron]] annihilation, in which the rest energy of these two individual particles (equivalent to their rest mass) is converted to the radiant energy of the photons produced in the process. In this system the [[Physics:Matter|matter]] and [[Physics:Antimatter|antimatter]] (electrons and positrons) are destroyed and changed to non-matter (the photons). However, the total mass and total energy do not change during this interaction. The photons each have no rest mass but nonetheless have radiant energy which exhibits the same inertia as did the two original particles. This is a reversible process – the inverse process is called pair creation – in which the rest mass of particles is created from the radiant energy of two (or more) annihilating photons.

In general relativity, the [[Stress–energy tensor|stress–energy tensor]] serves as the source term for the gravitational field, in rough analogy to the way mass serves as the source term in the non-relativistic Newtonian approximation.<ref name="MTW"/>

Energy and mass are manifestations of one and the same underlying physical property of a system. This property is responsible for the inertia and strength of gravitational interaction of the system ("mass manifestations"), and is also responsible for the potential ability of the system to perform work or heating ("energy manifestations"), subject to the limitations of other physical laws.

In [[Physics:Classical physics|classical physics]], energy is a scalar quantity, the canonical conjugate to time. In [[Physics:Special relativity|special relativity]] energy is also a scalar (although not a [[Physics:Lorentz scalar|Lorentz scalar]] but a time component of the energy–momentum 4-vector).<ref name="MTW">{{Cite book|author=Misner, Thorne, Wheeler |title=Gravitation |year=1973 |publisher=W.H. Freeman |location=San Francisco |isbn=978-0-7167-0344-0}}</ref> In other words, energy is invariant with respect to rotations of [[Space|space]], but not invariant with respect to rotations of [[Physics:Spacetime|spacetime]] (= boosts).

==Transformation==
{{Main|Physics:Energy transformation}}
{| class="wikitable" style="text-align:center;"
|+Some forms of [[Physics:Energy#Energy transfer|transfer]] of energy ("energy in transit") from one object or system to another
! Type of transfer [[Physics:Thermodynamic process|process]]!! Description
|-
|[[Physics:Heat|Heat]]
|equal amount of [[Physics:Thermal energy#Differentiation from heat|thermal energy]] in transit spontaneously towards a lower-[[Physics:Temperature|temperature]] object
|-
|[[Physics:Work|Work]]
|equal amount of energy in transit due to a displacement in the direction of an applied [[Physics:Force|force]]
|-
|Transfer of material
|equal amount of energy carried by [[Physics:Matter|matter]] that is moving from one system to another
|-
|}

[[File:Turbogenerator01.jpg|thumb|A [[Engineering:Turbo generator|turbo generator]] transforms the energy of pressurized steam into electrical energy.]]
Energy may be [[Physics:Energy transformation|transformed]] between different forms at various [[Physics:Energy conversion efficiency|efficiencies]]. Items that transform between these forms are called [[Engineering:Transducer|transducer]]s. Examples of transducers include a battery (from [[Chemistry:Chemical energy|chemical energy]] to electric energy), a dam (from gravitational potential energy to [[Physics:Kinetic energy|kinetic energy]] of moving water (and the blades of a [[Physics:Turbine|turbine]]) and ultimately to electric energy through an [[Engineering:Electric generator|electric generator]]), and a [[Physics:Heat engine|heat engine]] (from heat to work).

Examples of energy transformation include generating electric energy from heat energy via a steam turbine, or lifting an object against gravity using electrical energy driving a crane motor. Lifting against gravity performs mechanical work on the object and stores gravitational potential energy in the object. If the object falls to the ground, gravity does mechanical work on the object which transforms the potential energy in the gravitational field to the kinetic energy released as heat on impact with the ground. The Sun transforms nuclear potential energy to other forms of energy; its total mass does not decrease due to that itself (since it still contains the same total energy even in different forms) but its mass does decrease when the energy escapes out to its surroundings, largely as [[Physics:Radiant energy|radiant energy]].

There are strict limits to how efficiently heat can be converted into [[Physics:Work|work]] in a cyclic process, e.g. in a heat engine, as described by [[Physics:Carnot's theorem (thermodynamics)|Carnot's theorem]] and the [[Physics:Second law of thermodynamics|second law of thermodynamics]]. However, some energy transformations can be quite efficient. The direction of transformations in energy (what kind of energy is transformed to what other kind) is often determined by [[Physics:Entropy|entropy]] (equal energy spread among all available [[Chemistry:Degrees of freedom (physics and chemistry)|degrees of freedom]]) considerations. In practice all energy transformations are permitted on a small scale, but certain larger transformations are not permitted because it is statistically unlikely that energy or matter will randomly move into more concentrated forms or smaller spaces.

Energy transformations in the universe over time are characterized by various kinds of potential energy, that has been available since the [[Astronomy:Big Bang|Big Bang]], being "released" (transformed to more active types of energy such as kinetic or radiant energy) when a triggering mechanism is available. Familiar examples of such processes include [[Physics:Nucleosynthesis|nucleosynthesis]], a process ultimately using the gravitational potential energy released from the [[Astronomy:Gravitational collapse|gravitational collapse]] of [[Astronomy:Supernova|supernova]]e to "store" energy in the creation of heavy isotopes (such as [[Chemistry:Uranium|uranium]] and [[Chemistry:Thorium|thorium]]), and nuclear decay, a process in which energy is released that was originally stored in these heavy elements, before they were incorporated into the Solar System and the Earth. This energy is triggered and released in nuclear fission bombs or in civil nuclear power generation. Similarly, in the case of a [[Chemistry:Chemical explosive|chemical explosion]], [[Chemistry:Chemical potential|chemical potential]] energy is transformed to [[Physics:Kinetic energy|kinetic]] and [[Physics:Thermal energy|thermal energy]] in a very short time.

Yet another example is that of a [[Physics:Pendulum|pendulum]]. At its highest points the [[Physics:Kinetic energy|kinetic energy]] is zero and the gravitational potential energy is at its maximum. At its lowest point the [[Physics:Kinetic energy|kinetic energy]] is at its maximum and is equal to the decrease in [[Physics:Potential energy|potential energy]]. If one (unrealistically) assumes that there is no [[Physics:Friction|friction]] or other losses, the conversion of energy between these processes would be perfect, and the [[Physics:Pendulum|pendulum]] would continue swinging forever.

Energy is also transferred from potential energy (<math>E_p</math>) to kinetic energy (<math>E_k</math>) and then back to potential energy constantly. This is referred to as conservation of energy. In this [[Physics:Isolated system|isolated system]], energy cannot be created or destroyed; therefore, the initial energy and the final energy will be equal to each other. This can be demonstrated by the following:
{{NumBlk||<math display="block">E_{pi} + E_{ki} = E_{pF} + E_{kF}</math>|{{EquationRef|4}}}}

The equation can then be simplified further since <math>E_p = mgh</math> (mass times acceleration due to gravity times the height) and <math display="inline">E_k = \frac{1}{2} mv^2</math> (half&nbsp;mass times velocity squared). Then the total amount of energy can be found by adding <math>E_p + E_k = E_\text{total}</math>.

===Conservation of energy and mass in transformation===
Energy gives rise to weight when it is trapped in a system with zero momentum, where it can be weighed. It is also equivalent to mass, and this mass is always associated with it. Mass is also equivalent to a certain amount of energy, and likewise always appears associated with it, as described in [[Mass–energy equivalence|mass–energy equivalence]]. The formula ''E''&nbsp;=&nbsp;''mc''², derived by [[Biography:Albert Einstein|Albert Einstein]] (1905) quantifies the relationship between [[Physics:Relativistic mass|relativistic mass]] and energy within the concept of special relativity. In different theoretical frameworks, similar formulas were derived by J.J. Thomson (1881), [[Biography:Henri Poincaré|Henri Poincaré]] (1900), Friedrich Hasenöhrl (1904) and others (see [[Mass–energy equivalence]] for further information).

Part of the rest energy (equivalent to rest mass) of [[Physics:Matter|matter]] may be converted to other forms of energy (still exhibiting mass), but neither energy nor mass can be destroyed; rather, both remain constant during any process. However, since <math>c^2</math> is extremely large relative to ordinary human scales, the conversion of an everyday amount of rest mass (for example, 1&nbsp;kg) from rest energy to other forms of energy (such as kinetic energy, thermal energy, or the radiant energy carried by light and other radiation) can liberate tremendous amounts of energy (~<math>9\times 10^{16}</math> joules = 21 megatons of TNT), as can be seen in [[Physics:Nuclear reactor|nuclear reactor]]s and nuclear weapons. Conversely, the mass equivalent of an everyday amount energy is minuscule, which is why a loss of energy (loss of mass) from most systems is difficult to measure on a weighing scale, unless the energy loss is very large. Examples of large transformations between rest energy (of matter) and other forms of energy (e.g., kinetic energy into particles with rest mass) are found in [[Physics:Nuclear physics|nuclear physics]] and [[Physics:Particle physics|particle physics]]. Often, however, the complete conversion of matter (such as atoms) to non-matter (such as photons) is forbidden by [[Conservation law|conservation laws]].

===Reversible and non-reversible transformations===
Thermodynamics divides energy transformation into two kinds: [[Physics:Reversible process (thermodynamics)|reversible processes]] and [[Physics:Irreversible process|irreversible process]]es. An irreversible process is one in which energy is dissipated (spread) into empty energy states available in a volume, from which it cannot be recovered into more concentrated forms (fewer quantum states), without degradation of even more energy. A reversible process is one in which this sort of dissipation does not happen. For example, conversion of energy from one type of potential field to another is reversible, as in the pendulum system described above. In processes where heat is generated, quantum states of lower energy, present as possible excitations in fields between atoms, act as a reservoir for part of the energy, from which it cannot be recovered, in order to be converted with 100% efficiency into other forms of energy. In this case, the energy must partly stay as thermal energy and cannot be completely recovered as usable energy, except at the price of an increase in some other kind of heat-like increase in disorder in quantum states, in the universe (such as an expansion of matter, or a randomization in a crystal).

As the universe evolves with time, more and more of its energy becomes trapped in irreversible states (i.e., as heat or as other kinds of increases in disorder). This has led to the hypothesis of the inevitable thermodynamic [[Astronomy:Heat death of the universe|heat death of the universe]]. In this heat death the energy of the universe does not change, but the fraction of energy which is available to do work through a [[Physics:Heat engine|heat engine]], or be transformed to other usable forms of energy (through the use of generators attached to heat engines), continues to decrease.

==Conservation of energy==
{{Main|Physics:Conservation of energy}}
The fact that energy can be neither created nor destroyed is called the law of [[Physics:Conservation of energy|conservation of energy]]. In the form of the [[Physics:First law of thermodynamics|first law of thermodynamics]], this states that a [[Closed system|closed system]]'s energy is constant unless energy is transferred in or out as [[Physics:Work (thermodynamics)|work]] or [[Physics:Heat|heat]], and that no energy is lost in transfer. The total inflow of energy into a system must equal the total outflow of energy from the system, plus the change in the energy contained within the system. Whenever one measures (or calculates) the total energy of a system of particles whose interactions do not depend explicitly on time, it is found that the total energy of the system always remains constant.<ref>Berkeley Physics Course Volume 1. Charles Kittel, Walter D Knight and Malvin A Ruderman</ref>

While heat can always be fully converted into work in a reversible isothermal expansion of an ideal gas, for cyclic processes of practical interest in [[Physics:Heat engine|heat engine]]s the [[Physics:Second law of thermodynamics|second law of thermodynamics]] states that the system doing work always loses some energy as [[Astronomy:Waste heat|waste heat]]. This creates a limit to the amount of heat energy that can do work in a cyclic process, a limit called the available energy. Mechanical and other forms of energy can be transformed in the other direction into [[Physics:Thermal energy|thermal energy]] without such limitations.<ref name="thermo-laws"/> The total energy of a system can be calculated by adding up all forms of energy in the system.

[[Biography:Richard Feynman|Richard Feynman]] said during a 1961 lecture:<ref name="RPF1"/>
{{Blockquote|There is a fact, or if you wish, a ''law'', governing all natural phenomena that are known to date. There is no known exception to this law – it is exact so far as we know. The law is called the ''[[Physics:Conservation of energy|conservation of energy]]''. It states that there is a certain quantity, which we call energy, that does not change in manifold changes which nature undergoes. That is a most abstract idea, because it is a mathematical principle; it says that there is a numerical quantity which does not change when something happens. It is not a description of a mechanism, or anything concrete; it is just a strange fact that we can calculate some number and when we finish watching nature go through her tricks and calculate the number again, it is the same.|''[[Physics:The Feynman Lectures on Physics|The Feynman Lectures on Physics]]''}}

Most kinds of energy (with gravitational energy being a notable exception)<ref>{{cite web|url=http://www.physics.ucla.edu/~cwp/articles/noether.asg/noether.html |title=E. Noether's Discovery of the Deep Connection Between Symmetries and Conservation Laws |publisher=Physics.ucla.edu |date=1918-07-16 |access-date=2010-12-12 |url-status=dead |archive-url=https://web.archive.org/web/20110514080739/http://www.physics.ucla.edu/~cwp/articles/noether.asg/noether.html |archive-date=2011-05-14 }}</ref> are subject to strict local conservation laws as well. In this case, energy can only be exchanged between adjacent regions of space, and all observers agree as to the volumetric density of energy in any given space. There is also a global law of conservation of energy, stating that the total energy of the universe cannot change; this is a corollary of the local law, but not vice versa.<ref name="thermo-laws">[http://www.av8n.com/physics/thermo-laws.htm ''The Laws of Thermodynamics''] {{webarchive|url=https://web.archive.org/web/20061215201900/http://www.av8n.com/physics/thermo-laws.htm |date=2006-12-15 }} including careful definitions of energy, free energy, et cetera.</ref><ref name="RPF1">{{Cite book|first=Richard|last=Feynman|title=The Feynman Lectures on Physics; Volume 1|url=https://feynmanlectures.caltech.edu/I_04.html#Ch4-S1-p2|year=1964|publisher=Addison Wesley|location=US|isbn=978-0-201-02115-8|access-date=2022-05-04|archive-date=2022-07-30|archive-url=https://web.archive.org/web/20220730093042/https://www.feynmanlectures.caltech.edu/I_04.html#Ch4-S1-p2|url-status=live}}</ref>

This law is a fundamental principle of physics. As shown rigorously by [[Physics:Noether's theorem|Noether's theorem]], the conservation of energy is a mathematical consequence of [[Physics:Translational symmetry|translational symmetry]] of time,<ref>{{cite web |url=http://ptolemy.eecs.berkeley.edu/eecs20/week9/timeinvariance.html |title=Time Invariance |publisher=Ptolemy.eecs.berkeley.edu |access-date=2010-12-12 |url-status=live |archive-url=https://web.archive.org/web/20110717210455/http://ptolemy.eecs.berkeley.edu/eecs20/week9/timeinvariance.html |archive-date=2011-07-17 }}</ref> a property of most phenomena below the cosmic scale that makes them independent of their locations on the time coordinate. Put differently, yesterday, today, and tomorrow are physically indistinguishable. This is because energy is the quantity which is canonical conjugate to time. This mathematical entanglement of energy and time also results in the uncertainty principle – it is impossible to define the exact amount of energy during any definite time interval (though this is practically significant only for very short time intervals). The uncertainty principle should not be confused with energy conservation – rather it provides mathematical limits to which energy can in principle be defined and measured.

Each of the basic forces of nature is associated with a different type of potential energy, and all types of potential energy (like all other types of energy) appear as system [[Physics:Mass|mass]], whenever present. For example, a compressed spring will be slightly more massive than before it was compressed. Likewise, whenever energy is transferred between systems by any mechanism, an associated mass is transferred with it.

In [[Physics:Quantum mechanics|quantum mechanics]] energy is expressed using the [[Physics:Hamiltonian operator|Hamiltonian operator]]. On any time scales, the uncertainty in the energy is by

: <math>\Delta E \Delta t \ge \frac { \hbar } {2 } </math>

which is similar in form to the Heisenberg Uncertainty Principle (but not really mathematically equivalent thereto, since ''H'' and ''t'' are not dynamically conjugate variables, neither in classical nor in quantum mechanics).

In [[Physics:Particle physics|particle physics]], this inequality permits a qualitative understanding of virtual particles, which carry [[Physics:Momentum|momentum]]. The exchange of virtual particles with real particles is responsible for the creation of all known [[Physics:Fundamental forces|fundamental forces]] (more accurately known as fundamental interactions). Virtual photons are also responsible for the electrostatic interaction between [[Physics:Electric charge|electric charge]]s (which results in [[Physics:Coulomb's law|Coulomb's law]]), for [[Physics:Spontaneous fission|spontaneous]] radiative decay of excited atomic and nuclear states, for the Casimir force, for the [[Physics:Van der Waals force|Van der Waals force]] and some other observable phenomena.

==Energy transfer==

===Closed systems===
Energy transfer can be considered for the special case of systems which are [[Closed system|closed]] to transfers of matter. The portion of the energy which is transferred by [[Physics:Conservative force|conservative force]]s over a distance is measured as the [[Physics:Work (thermodynamics)|work]] the source system does on the receiving system. The portion of the energy which does not do work during the transfer is called [[Physics:Heat|heat]].<ref group=note>Although heat is "wasted" energy for a specific energy transfer (see: [[Astronomy:Waste heat|waste heat]]), it can often be harnessed to do useful work in subsequent interactions. However, the maximum energy that can be "recycled" from such recovery processes is limited by the [[Physics:Second law of thermodynamics|second law of thermodynamics]].</ref> Energy can be transferred between systems in a variety of ways. Examples include the transmission of electromagnetic energy via photons, physical collisions which transfer [[Physics:Kinetic energy|kinetic energy]],<ref group=note>The mechanism for most macroscopic physical collisions is actually [[Physics:Electromagnetism|electromagnetic]], but it is very common to simplify the interaction by ignoring the mechanism of collision and just calculate the beginning and end result.</ref> tidal interactions,<ref>{{cite book | title=The Physics of Energy | first1=Robert L. | last1=Jaffe | first2=Washington | last2=Taylor | date=2018 | isbn=9781107016651 | page=611 | publisher=Cambridge University Press | url=https://books.google.com/books?id=drZDDwAAQBAJ&pg=PA611 | access-date=2022-05-22 | archive-date=2022-07-30 | archive-url=https://web.archive.org/web/20220730093040/https://www.google.com/books/edition/The_Physics_of_Energy/drZDDwAAQBAJ?gbpv=1&pg=PA611 | url-status=live }}</ref> and the conductive transfer of [[Physics:Thermal energy|thermal energy]].

Energy is strictly conserved and is also locally conserved wherever it can be defined. In thermodynamics, for closed systems, the process of energy transfer is described by the [[Physics:First law of thermodynamics|first law]]:<ref group=note>There are several [[Physics:First law of thermodynamics#Description|sign conventions for this equation]]. Here, the signs in this equation follow the IUPAC convention.</ref>

{{NumBlk|:|<math>\Delta{}E = W + Q </math>|{{EquationRef|1}}}}

where <math>E</math> is the amount of energy transferred, <math>W</math>&nbsp; represents the work done on or by the system, and <math>Q</math> represents the heat flow into or out of the system. As a simplification, the heat term, <math>Q</math>, can sometimes be ignored, especially for fast processes involving gases, which are poor conductors of heat, or when the [[Physics:Thermal efficiency|thermal efficiency]] of the transfer is high. For such [[Physics:Adiabatic process|adiabatic processes]],

{{NumBlk|:|<math>\Delta{}E = W</math>|{{EquationRef|2}}}}

This simplified equation is the one used to define the [[Joule|joule]], for example.

===Open systems===
Beyond the constraints of closed systems, [[Physics:Thermodynamic system#Open system|open systems]] can gain or lose energy in association with matter transfer (this process is illustrated by injection of an air-fuel mixture into a car engine, a system which gains in energy thereby, without addition of either work or heat). Denoting this energy by <math>E_\text{matter}</math>, one may write

{{NumBlk|:|<math>\Delta E = W + Q + E_\text{matter} .</math>|{{EquationRef|3}}}}

==Thermodynamics==

===Internal energy===
[[Physics:Internal energy|Internal energy]] is the sum of all microscopic forms of energy of a system. It is the energy needed to create the system. It is related to the potential energy, e.g., molecular structure, crystal structure, and other geometric aspects, as well as the motion of the particles, in form of kinetic energy. Thermodynamics is chiefly concerned with changes in internal energy and not its absolute value, which is impossible to determine with thermodynamics alone.<ref name=klotz>I. Klotz, R. Rosenberg, ''Chemical Thermodynamics – Basic Concepts and Methods'', 7th ed., Wiley (2008), p. 39</ref>

===First law of thermodynamics===
The [[Physics:First law of thermodynamics|first law of thermodynamics]] asserts that the total energy of a system and its surroundings (but not necessarily [[Physics:Thermodynamic free energy|thermodynamic free energy]]) is always conserved<ref name="KK">{{Cite book|author=Kittel and Kroemer|title=Thermal Physics |year=1980|publisher=W.H. Freeman |location=New York| isbn=978-0-7167-1088-2}}</ref> and that heat flow is a form of energy transfer. For homogeneous systems, with a well-defined temperature and pressure, a commonly used corollary of the first law is that, for a system subject only to [[Physics:Pressure|pressure]] forces and heat transfer (e.g., a cylinder-full of gas) without chemical changes, the differential change in the internal energy of the system (with a ''gain'' in energy signified by a positive quantity) is given as

:<math>\mathrm{d}E = T\mathrm{d}S - P\mathrm{d}V\,</math>,

where the first term on the right is the heat transferred into the system, expressed in terms of [[Physics:Temperature|temperature]] ''T'' and [[Physics:Entropy|entropy]] ''S'' (in which entropy increases and its change d''S'' is positive when heat is added to the system), and the last term on the right hand side is identified as work done on the system, where pressure is ''P'' and volume ''V'' (the negative sign results since compression of the system requires work to be done on it and so the volume change, d''V'', is negative when work is done on the system).

This equation is highly specific, ignoring all chemical, electrical, nuclear, and gravitational forces, effects such as [[Advection|advection]] of any form of energy other than heat and ''PV''-work. The general formulation of the first law (i.e., conservation of energy) is valid even in situations in which the system is not homogeneous. For these cases the change in internal energy of a ''closed'' system is expressed in a general form by

:<math>\mathrm{d}E=\delta Q+\delta W</math>

where <math>\delta Q</math> is the heat supplied to the system and <math>\delta W</math> is the work applied to the system.

===Equipartition of energy===
The energy of a mechanical [[Physics:Harmonic oscillator|harmonic oscillator]] (a mass on a spring) is alternately [[Physics:Kinetic energy|kinetic]] and [[Physics:Potential energy|potential energy]]. At two points in the oscillation [[Physics:Frequency|cycle]] it is entirely kinetic, and at two points it is entirely potential. Over a whole cycle, or over many cycles, average energy is equally split between kinetic and potential. This is an example of the equipartition principle: the total energy of a system with many degrees of freedom is equally split among all available degrees of freedom, on average.

This principle is vitally important to understanding the behavior of a quantity closely related to energy, called [[Physics:Entropy|entropy]]. Entropy is a measure of evenness of a [[Distribution (mathematics)|distribution]] of energy between parts of a system. When an isolated system is given more degrees of freedom (i.e., given new available energy states that are the same as existing states), then total energy spreads over all available degrees equally without distinction between "new" and "old" degrees. This mathematical result is part of the [[Physics:Second law of thermodynamics|second law of thermodynamics]]. The second law of thermodynamics is simple only for systems which are near or in a physical equilibrium state. For non-equilibrium systems, the laws governing the systems' behavior are still debatable. One of the guiding principles for these systems is the principle of [[Principle of maximum entropy|maximum entropy production]].<ref>{{cite journal|last1=Onsager|first1=L.|title=Reciprocal relations in irreversible processes.|journal=Phys. Rev. |volume=37|issue=4|date=1931|pages=405–26|bibcode=1931PhRv...37..405O|doi=10.1103/PhysRev.37.405|doi-access=free}}</ref><ref>{{cite journal|last1=Martyushev|first1=L.M.|last2=Seleznev|first2=V.D.|title=Maximum entropy production principle in physics, chemistry and biology|journal=Physics Reports|date=2006|volume=426|issue=1|pages=1–45|doi=10.1016/j.physrep.2005.12.001|bibcode=2006PhR...426....1M}}</ref> It states that nonequilibrium systems behave in such a way as to maximize their entropy production.<ref>{{cite journal|last1=Belkin|first1=A.|last2=et.|first2=al.|title=Self-Assembled Wiggling Nano-Structures and the Principle of Maximum Entropy Production|journal=Sci. Rep. |volume=5|pages=8323|date=2015|doi=10.1038/srep08323|pmid=25662746|pmc=4321171|bibcode=2015NatSR...5E8323B}}</ref>

==See also==
{{cols}}
* [[Physics:Combustion|Combustion]]
* [[Social:Energy democracy|Energy democracy]]
* [[Physics:Index of energy articles|Index of energy articles]]
* [[Index of wave articles]]
* [[Orders of magnitude (energy)]]
* [[Chemistry:Power station|Power station]]
* [[Engineering:Spaceflight#Transfer energy|Transfer energy]]
{{colend}}
{{clear}}

==Notes==
{{Reflist|group=note}}

==References==
{{Reflist}}

==Further reading==
{{refbegin}}
* {{Cite book |first=G.N. |last=Alekseev |title=Energy and Entropy |url=https://archive.org/details/EnergyAndEntropy |year=1986 |publisher=Mir Publishers |location=Moscow |ref=none}}
* ''The [[Biology:Biosphere|Biosphere]]'' (A ''Scientific American'' Book), San Francisco, W.H. Freeman and Co., 1970, {{ISBN|0-7167-0945-7}}. This book, originally a 1970 ''Scientific American'' issue, covers virtually every major concern and concept since debated regarding materials and energy resources, [[Social:Population|population]] trends, and environmental degradation.
* {{Citation|title=Light and Matter|last=Crowell|first=Benjamin|year=2011|chapter=ch. 11|publisher=Light and Matter|location=Fullerton, California|chapter-url=http://www.lightandmatter.com/lm|access-date=2017-04-12|archive-date=2011-05-19|archive-url=https://web.archive.org/web/20110519093054/http://lightandmatter.com/lm/|url-status=live |ref=none}}
* ''Energy and Power'' (A ''Scientific American'' Book), San Francisco, W.H. Freeman and Co., 1971, {{ISBN|0-7167-0938-4}}.
* {{cite web|last=Ross|first=John S.|title=Work, Power, Kinetic Energy|url=http://www.physnet.org/modules/pdf_modules/m20.pdf|work=Project PHYSNET|publisher=Michigan State University|date=23 April 2002|access-date=10 April 2009|archive-date=26 April 2011|archive-url=https://web.archive.org/web/20110426160837/http://www.physnet.org/modules/pdf_modules/m20.pdf|url-status=live |ref=none}}
* Santos, Gildo M. "Energy in Brazil: a historical overview," ''The Journal of Energy History'' (2018), [http://www.energyhistory.eu/en/panorama/energy-brazil-historical-overview online] {{Webarchive|url=https://web.archive.org/web/20190209180117/http://www.energyhistory.eu/en/panorama/energy-brazil-historical-overview |date=2019-02-09 |ref=none}}
* {{Cite book|author=Smil, Vaclav|title=Energy in nature and society: general energetics of complex systems |year=2008 |publisher=MIT Press |location=Cambridge, US |isbn=978-0-262-19565-2 |ref=none}}
* {{Cite book|author1=Walding, Richard |author2=Rapkins, Greg |author3=Rossiter, Glenn |title=New Century Senior Physics |date=1999|publisher=Oxford University Press |location=Melbourne, Australia |isbn=978-0-19-551084-3 |ref=none}}
{{refend}}

===Journals===
* [http://www.energyhistory.eu/en ''The Journal of Energy History / Revue d'histoire de l'énergie'' (JEHRHE), 2018– ]

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* [http://www.biocab.org/Heat.html Differences between Heat and Thermal energy] ({{Webarchive|url=https://web.archive.org/web/20160827224418/http://www.biocab.org/Heat.html |date=2016-08-27 }}) – BioCab
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