Chemistry:Stibole
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| Names | |||
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| Preferred IUPAC name
1H-Stibole | |||
| Identifiers | |||
3D model (JSmol)
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PubChem CID
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| Properties | |||
| C4H5Sb | |||
| Molar mass | 174.844 g·mol−1 | ||
| Related compounds | |||
Related compounds
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Pyrrole, phosphole, arsole, bismole | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
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Tracking categories (test):
Stibole is a theoretical heterocyclic organic compound, a five-membered ring with the formula C4H4SbH. It is classified as a metallole. It can be viewed as a structural analog of pyrrole, with antimony replacing the nitrogen atom of pyrrole. Substituted derivatives, which have been synthesized, are called stiboles.
Reactions
2,5-Dimethyl-1-phenyl-1H-stibole, for example, can be formed by the reaction of 1,1-dibutyl-2,5-dimethylstannole and dichlorophenylstibine.[1] Stiboles can be used to form ferrocene-like sandwich compounds.[2]
See also
- Organoantimony chemistry
References
- ↑ Dictionary of Organic Compounds, 3 (6 ed.), Chapman & Hall, 1996, pp. 2710, ISBN 978-0-412-54090-5, https://books.google.com/books?id=C3Uo1co4Wv0C&pg=PA2710, retrieved 2010-03-04
- ↑ Comprehensive Organic Functional Group Transformations, 4, Elsevier, 1995, pp. 1038–1040, ISBN 978-0-08-042325-8, https://books.google.com/books?id=0RQEsfYCuBcC&pg=PA1038, retrieved 2010-03-04
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