Chemistry:Muldamine

Muldamine
Names
	IUPAC name 3β-Hydroxy-16,28-seco-22β-solanid-5-en-16α-yl acetate
	Systematic IUPAC name (1R,2R,3aS,3bS,7S,9aR,9bS,11aS)-7-Hydroxy-9a,11a-dimethyl-1-{(1S)-1-[(2S,5S)-5-methylpiperidin-2-yl]ethyl}-2,3,3a,3b,4,6,7,8,9,9a,9b,10,11,11a-tetradecahydro-1H-cyclopenta[a]phenanthren-2-yl acetate
	Other names Alkaloid Q; Teinemine 16-acetate; 5-Veratranine-3β,11α-diol 11-acetate
Identifiers
CAS Number	36069-45-1 ;
3D model (JSmol)	Interactive image;
ChemSpider	10183538 ;
MeSH	Muldamine
PubChem CID	21575037;
UNII	Q683N7457H ;
	InChI InChI=1S/C29H47NO3/c1-17-6-9-25(30-16-17)18(2)27-26(33-19(3)31)15-24-22-8-7-20-14-21(32)10-12-28(20,4)23(22)11-13-29(24,27)5/h7,17-18,21-27,30,32H,6,8-16H2,1-5H3 Key: ZVYUDNWAHWVPPN-UHFFFAOYSA-N ;
	SMILES CC(C1C(CC2C3CC=C4CC(O)CCC4(C)C3CCC12C)OC(C)=O)C1CCC(C)CN1;
Properties
Chemical formula	C29H47NO3
Molar mass	457.699 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Short description: Organic compound, phytosterol alkaloid

Muldamine is a phytosterol alkaloid isolated from Veratrum californicum.^[1] It is the acetate ester of the piperidine steroid teinemine.^[2]

References

↑ Keeler R F (1971). "Teratogenic compounds of Veratrum californicum (Durand). 13. Structure of muldamine". Steroids 18 (6): 741–752. doi:10.1016/0039-128X(71)90033-X. PMID 5135731.
↑ Gaffield, William; Wong, Rosalind Y.; Lundin, Robert E.; Keeler, Richard F. (1982). "Structure of the steroidal alkaloid muldamine and its deacetyl derivative". Phytochemistry 21 (9): 2397–2400. doi:10.1016/0031-9422(82)85214-X. Bibcode: 1982PChem..21.2397G.

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Names


IUPAC name 3β-Hydroxy-16,28-seco-22β-solanid-5-en-16α-yl acetate
Systematic IUPAC name (1R,2R,3aS,3bS,7S,9aR,9bS,11aS)-7-Hydroxy-9a,11a-dimethyl-1-{(1S)-1-[(2S,5S)-5-methylpiperidin-2-yl]ethyl}-2,3,3a,3b,4,6,7,8,9,9a,9b,10,11,11a-tetradecahydro-1H-cyclopenta[a]phenanthren-2-yl acetate
Other names Alkaloid Q Teinemine 16-acetate 5-Veratranine-3β,11α-diol 11-acetate
Identifiers
CAS Number	36069-45-1^Y
3D model (JSmol)	Interactive image
ChemSpider	10183538^Y
MeSH	Muldamine
PubChem CID	21575037
UNII	Q683N7457H^Y
InChI InChI=1S/C29H47NO3/c1-17-6-9-25(30-16-17)18(2)27-26(33-19(3)31)15-24-22-8-7-20-14-21(32)10-12-28(20,4)23(22)11-13-29(24,27)5/h7,17-18,21-27,30,32H,6,8-16H2,1-5H3^Y Key: ZVYUDNWAHWVPPN-UHFFFAOYSA-N^Y
SMILES CC(C1C(CC2C3CC=C4CC(O)CCC4(C)C3CCC12C)OC(C)=O)C1CCC(C)CN1
Properties
Chemical formula	C₂₉H₄₇NO₃
Molar mass	457.699 g·mol⁻¹
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references