Chemistry:Triumphene
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Triumphene is a fluorinated and phenylated fullerene derivative.[1][2] It was first synthesized in 1998 by Boltalina, Street, and Taylor by reaction of C60F18 in a benzene-FeCl3 solution for two weeks at room temperature. It is the first trefoil-shaped phenylated [60]fullerene, providing a unique scaffold for the potential use in nanoscale imaging agents.
References
- ↑ O. V. Boltalina; R. Taylor; J. M. Street (1998). "Formation of triumphene, C60F15Ph3: first member of a new trefoil-shaped class of phenylated [60]fullerenes". Chem. Commun. (17): 1827–1828. doi:10.1039/a805340e.
- ↑ A. D. Darwish, A. G. Avent, A. K. Abdul-Sada, I. V. Goldt, P. B. Hitchcock, I. V. Kuvytchko, R. Taylor (2004). "Electrophilic Aromatic Substitution by the Fluorofullerene C60F18". Chemistry: A European Journal 10 (18): 4523–4531. doi:10.1002/chem.200400036. PMID 15378631.
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