Chemistry:(Cyclooctatetraene)iron tricarbonyl
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(CO)3.png)
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(CO)3.jpg)
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| Names | |
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| Other names
Tricarbonyl(cyclooctatetraene)iron
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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| Properties | |
| C11H8FeO3 | |
| Molar mass | 244.027 g·mol−1 |
| Appearance | orange solid |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Warning |
| H302, H312, H332 | |
| P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
(Cyclooctatetraene)iron tricarbonyl is the organoiron compound with the formula (C8H8)Fe(CO)3. Like other examples of (diene)Fe(CO)3 complexes, it is an orange, diamagnetic solid. Although several isomers are possible, only the η4-C8H8 complex is observed. The complex is an example of a ring-whizzer, since, on the NMR time-scale, the Fe(CO)3 center migrates around the rim of the cyclooctatetraene ligand.[1]
References
- ↑ Cotton, F. Albert; Hunter, Douglas L. (1976). "Carbon-13 Nuclear Magnetic Resonance Study of the Fluxional Behavior of Cyclooctatetraenetricarbonyliron and -Ruthenium". Journal of the American Chemical Society 98 (6): 1413–1417. doi:10.1021/ja00422a022.
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