Chemistry:2-(Diphenylphosphino)anisole
From HandWiki
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| Names | |
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| Preferred IUPAC name
(2-Methoxyphenyl)di(phenyl)phosphane | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| EC Number |
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PubChem CID
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| Properties | |
| C19H17OP | |
| Molar mass | 292.318 g·mol−1 |
| Appearance | white solid |
| Density | 1.188 g/cm3[1] |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Warning |
| H315, H319, H335 | |
| P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
2-(Diphenylphosphino)anisole is the organophosphorus compound with the formula (C6H5)2PC6H4-2-OCH3. It is a white solid that is soluble in organic solvents. The compound is used as a ligand in organometallic chemistry and homogeneous catalysis. It is the prototypical hemilabile ligand.[2] This compound is prepared from 2-bromoanisole.
Related ligands
References
- ↑ Suomalainen, Pekka; Jääskeläinen, Sirpa; Haukka, Matti; Laitinen, Riitta H.; Pursiainen, Jouni; Pakkanen, Tapani A. (2000). "Structural and Theoretical Studies ofortho-Substituted Triphenylphosphane Ligands and Their Rhodium(I) Complexes". European Journal of Inorganic Chemistry 2000 (12): 2607–2613. doi:10.1002/1099-0682(200012)2000:12<2607::AID-EJIC2607>3.0.CO;2-R.
- ↑ Jeffrey, J. C.; Rauchfuss, T. B. (1979). "Metal Complexes of Hemilabile Ligands. Reactivity and Structure of Dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II)". Inorganic Chemistry 18 (10): 2658–2666. doi:10.1021/ic50200a004.
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