Chemistry:Actinium oxyfluoride
From HandWiki
| Identifiers | |
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3D model (JSmol)
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| Properties | |
| AcOF | |
| Molar mass | 262.03 |
| Appearance | solid |
| Density | 8.280 g·cm−1[1] |
| Structure[2] | |
| cubic | |
a = 0.5931 nm
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Actinium oxyfluoride is an inorganic compound, with the chemical formula AcOF. It is radioactive. It crystallises in a calcium fluoride structure.[3] It can be obtained by reacting actinium fluoride with ammonia and water:[4]
- AcF3 + 2 NH3 + H2O → AcOF + 2 NH4F[lower-greek 1]
The reaction proceeds completely at 1200 °C, and unreacted AcF3 will remain at lower temperatures.[5]
Notes
- ↑ Ammonium fluoride decomposes into NH3 and HF at high temperature and recombines at low temperature
References
- ↑ Yaws, C. (2015). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics. Elsevier Science. p. 685. ISBN 978-0-12-801146-1. https://books.google.com/books?id=GutDBAAAQBAJ&pg=PA685. Retrieved 2022-02-01.
- ↑ Perry, D.L. (2016). Handbook of Inorganic Compounds. CRC Press. p. 527. ISBN 978-1-4398-1462-8. https://books.google.com/books?id=SFD30BvPBhoC&pg=PA527. Retrieved 2022-02-01.
- ↑ 无机化学丛书 第十卷 锕系 锕系后元素. 科学出版社. pp 92-93. 5. 卤氧化物
- ↑ Sherman Fried, French Hagemann, W. H. Zachariasen (Feb 1950). "The Preparation and Identification of Some Pure Actinium Compounds 1" (in en). Journal of the American Chemical Society 72 (2): 771–775. doi:10.1021/ja01158a034. ISSN 0002-7863. https://pubs.acs.org/doi/abs/10.1021/ja01158a034. Retrieved 2022-02-01.
- ↑ W. H. Zachariasen (1951-05-01). "Crystal chemical studies of the 5 f -series of elements. XIV. Oxyfluorides, X OF". Acta Crystallographica 4 (3): 231–236. doi:10.1107/S0365110X51000787. ISSN 0365-110X. Bibcode: 1951AcCry...4..231Z. http://scripts.iucr.org/cgi-bin/paper?S0365110X51000787. Retrieved 2022-02-01.
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