Chemistry:Barking dog reaction
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The "Barking Dog" is an exothermic chemical reaction that results from the ignition of a mixture of carbon disulfide and nitrous oxide.[1] When ignited in a cylindrical tube, the reaction produces a bright flash and a loud "woof" - reminiscent of a barking dog.
In simple terms, the 'Barking Dog' reaction is a combustion process, in which a fuel (carbon disulfide, CS2) reacts with an oxidizing agent (nitrous oxide, N2O), producing heat and elemental sulfur. The flame front in the reaction is a zone of very hot, luminous gas, produced by the reactants decomposing.
- 8 N2O + 4 CS2 → S8 + 4 CO2 + 8 N2
In April 1853, Justus von Liebig performed the demonstration in front of the Bavarian royal family; however, the glass container shattered, and shards of glass inflicted minor injuries on the faces of Queen Therese, her son Prince Luitpold, and Liebig himself.[2][3]
References
- ↑ Seabourne, Ché Royce; Maxwell, George; Wallace, James (2006). "Taming the Barking Dog". Journal of Chemical Education 83 (5): 751. doi:10.1021/ed083p751. http://jchemed.chem.wisc.edu/Journal/Issues/2006/May/abs751.html.
- ↑ Brock, William H. (1997). Justus Von Liebig: The Chemical Gatekeeper. Cambridge, England: Cambridge University Press. p. 111. ISBN 9780521524735. https://books.google.com/books?id=VugoemP2th0C&pg=PA111.
- ↑ Volhard, Jakob (1909) (in German). Justus von Liebig, vol. 2. Liebig, Germany: Johann Ambrosius Barth. pp. 349–350. https://babel.hathitrust.org/cgi/pt?id=njp.32101030650988;view=1up;seq=367.
External links
- Barking Dog (slow motion) - Periodic Table of Videos, University of Nottingham
- University of Leeds Barking Dog site
- Elementary Productions: Small scale Barking Dog reaction @ youtube
- Barking Dog Reaction How to Do the Barking Dog Chemistry Demonstration
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