Chemistry:Calcium ferrocyanide

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Short description: Chemical compound
Calcium ferrocyanide
Calcium ferrocyanide.svg
Names
Other names
Dicalcium hexakis(cyano-κC)ferrate(4-)
Identifiers
3D model (JSmol)
EC Number
  • 237-508-9
UNII
Properties
C6Ca2FeN6
Molar mass 292.109 g·mol−1
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H302, H312, H315, H319, H332, H335
P261, P280, P301+312, P302+352, P304+340, P305+351+338, P332+313
NFPA 704 (fire diamond)
Flammability code 0: Will not burn. E.g. waterHealth (blue): no hazard codeReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no codeNFPA 704 four-colored diamond
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Calcium ferrocyanide is an inorganic compound with the formula Ca2[Fe(CN)6]. It is the Ca2+ salt of [Fe(CN)6]4-, ferrocyanide complex ion. A yellow solid, it is used as a precursor to the pigment Prussian blue.[1]

Safety

It was listed in 2012 by the EU as a "Food Improvement Agent".

In the EU, ferrocyanides (E 535–538) were, as of 2018, solely authorised in two food categories as salt substitutes. Kidneys are the organ for ferrocyanide toxicity.[2]

References

  1. Gail, E.; Gos, S.; Kulzer, R.; Lorösch, J.; Rubo, A.; Sauer, M.; Kellens, R.; Reddy, J. et al. (2011). "Ullmann's Encyclopedia of Industrial Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a08_159.pub3. 
  2. Peter Aggett, Fernando Aguilar, Riccardo Crebelli, Birgit Dusemund, Metka Filipič, Maria Jose Frutos, Pierre Galtier, David Gott, Ursula Gundert‐Remy, Gunter Georg Kuhnle, Claude Lambré, Jean‐Charles Leblanc, Inger Therese Lillegaard, Peter Moldeus, Alicja Mortensen, Agneta Oskarsson, Ivan Stankovic, Ine Waalkens‐Berendsen, Rudolf Antonius Woutersen, Matthew Wright and Maged Younes. (2018). "Re‐evaluation of sodium ferrocyanide (E 535), potassium ferrocyanide (E 536) and calcium ferrocyanide (E 538) as food additives". EFSA Journal 16 (7): 5374. doi:10.2903/j.efsa.2018.5374. PMID 32626000. PMC 7009536. https://www.efsa.europa.eu/en/efsajournal/pub/5374.