Chemistry:Chromotropic acid

Chromotropic acid

Names
Preferred IUPAC name 4,5-Dihydroxynaphthalene-2,7-disulfonic acid
Identifiers
CAS Number	148-25-4 Y
3D model (JSmol)	Interactive image
Beilstein Reference	1827764
ChEBI	CHEBI:1751 Y
ChEMBL	ChEMBL144298 Y
ChemSpider	60557 Y
KEGG	C11323 Y
PubChem CID	67221
UNII	S596OD720M
InChI InChI=1S/C10H8O8S2/c11-8-3-6(19(13,14)15)1-5-2-7(20(16,17)18)4-9(12)10(5)8/h1-4,11-12H,(H,13,14,15)(H,16,17,18) Y Key: HLVXFWDLRHCZEI-UHFFFAOYSA-N Y InChI=1/C10H8O8S2/c11-8-3-6(19(13,14)15)1-5-2-7(20(16,17)18)4-9(12)10(5)8/h1-4,11-12H,(H,13,14,15)(H,16,17,18) Key: HLVXFWDLRHCZEI-UHFFFAOYAH
SMILES O=S(=O)(O)c1cc(O)c2c(c1)cc(cc2O)S(=O)(=O)O
Properties
Chemical formula	C10H8O8S2
Molar mass	320.29 g·mol−1
Acidity (pKa)	5.36, 15.6
Hazards
GHS pictograms
GHS Signal word	Warning
GHS hazard statements	H315, H319, H335
GHS precautionary statements	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Tracking categories (test):

• SizeSet

Chromotropic acid is a chemical compound with the formula (HO)₂C₁₀H₄(SO₃H)₂.

It can be used for as a reagent in the quantitative determination of the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D).

Chromotropic acid is also used for testing for the presence of formaldehyde. The usefulness of this reagent in quantitative determination is the formation of a red coloration (peaking at 580 nm wavelength) when chromotropic acid in 50% sulfuric acid reacts with formaldehyde. The coloration is specific to this aldehyde and is not produced from other organic species such as other aldehydes, ketones and carboxylic acids. The NIOSH Formaldehyde method #3500 is the reference analytical standard that uses chromotropic acid.