Chemistry:Cobalt oleate

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Cobalt oleate
Cobalt oleate.svg
Names
IUPAC name
Cobalt (Z)-octadec-9-enoate
Other names
Cobaltous oleate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 242-865-9
UNII
Properties
C36H66CoO4
Molar mass 621.853 g·mol−1
Appearance Purple powder
Solubility Soluble in benzene, carbon tetrachloride, pyridine, chloroform, quinoline[1]
Hazards
GHS pictograms GHS07: Harmful GHS09: Environmental hazard
GHS Signal word Warning
H317, H411, H412
P261, P272, P273, P280, P302+352, P321, P333+313, P362+364Script error: No such module "Preview warning".Category:GHS errors, P391, P501
Related compounds
Other cations
Sodium oleate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Cobalt oleate is an organometallic compound with the formula Co(C18H33O2)2. When cobalt oleate is added to non-polar solvents, the viscosity rapidly increases, and then continues increasing over time. This unusual viscosity effect is caused by the formation of a weak coordination complex with the solvent molecules.[1]

Preparation

Cobalt oleate can be synthesized by heating a solution of sodium oleate and cobalt(II) chloride to 70 °C.[2]

[math]\ce{ 2NaC18H33O2 + CoCl2 -> 2NaCl + Co(C18H33O2)2 }[/math]

See also

References

  1. 1.0 1.1 Funakoshi, Hideo; Matuura, Ryohei (October 1964). "Peptizing Action of Some Polar Substances on the Benzene Solution of Cobalt Oleate" (in en). Nature 204 (4954): 186. doi:10.1038/204186a0. ISSN 0028-0836. Bibcode1964Natur.204..186F. https://www.nature.com/articles/204186a0. 
  2. An, Kwangjin; Lee, Nohyun; Park, Jongnam; Kim, Sung Chul; Hwang, Yosun; Park, Je-Geun; Kim, Jae-Young; Park, Jae-Hoon et al. (2006-08-01). "Synthesis, Characterization, and Self-Assembly of Pencil-Shaped CoO Nanorods" (in en). Journal of the American Chemical Society 128 (30): 9753–9760. doi:10.1021/ja0608702. ISSN 0002-7863. PMID 16866531. https://pubs.acs.org/doi/10.1021/ja0608702.