Chemistry:Continuous reactor

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Continuous reactors (alternatively referred to as flow reactors) carry material as a flowing stream. Reactants are continuously fed into the reactor and emerge as continuous stream of product. Continuous reactors are used for a wide variety of chemical and biological processes within the food, chemical and pharmaceutical industries. A survey of the continuous reactor market will throw up a daunting variety of shapes and types of machine. Beneath this variation however lies a relatively small number of key design features which determine the capabilities of the reactor. When classifying continuous reactors, it can be more helpful to look at these design features rather than the whole system.

Batch versus continuous

Reactors can be divided into two broad categories, batch reactors and continuous reactors. Batch reactors are stirred tanks sufficiently large to handle the full inventory of a complete batch cycle. In some cases, batch reactors may be operated in semi batch mode where one chemical is charged to the vessel and a second chemical is added slowly. Continuous reactors are generally smaller than batch reactors and handle the product as a flowing stream. Continuous reactors may be designed as pipes with or without baffles or a series of interconnected stages. The advantages of the two options are considered below.

Benefits of batch reactors

  • Batch reactors are very versatile and are used for a variety for different unit operations (batch distillation, storage, crystallisation, liquid-liquid extraction etc.) in addition to chemical reactions.
  • There is a large installed base of batch reactors within industry and their method of use is well established.
  • Batch reactors are excellent at handling difficult materials like slurries or products with a tendency to foul.
  • Batch reactors represent an effective and economic solution for many types of slow reactions.

Benefits of continuous reactors

  • The rate of many chemical reactions is dependent on reactant concentration. Continuous reactors are generally able to cope with much higher reactant concentrations due to their superior heat transfer capacities. Plug flow reactors have the additional advantage of greater separation between reactants and products giving a better concentration profile.
  • The small size of continuous reactors makes higher mixing rates possible.
  • The output from a continuous reactor can be altered by varying the run time. This increases operating flexibility for manufacturers.

Heat transfer capacity

The rate of heat transfer within a reactor can be determined from the following relationship:

[math]\displaystyle{ q_x = UA(T_p-T_j) }[/math]

where:

qx: the heat liberated or absorbed by the process (W)
U: the heat transfer coefficient of the heat exchanger (W/(m2K))
A: the heat transfer area (m2)
Tp: process temperature (K)
Tj: jacket temperature (K)

From a reactor design perspective, heat transfer capacity is heavily influenced by channel size since this determines the heat transfer area per unit volume. Channel size can be categorised in various ways however in broadest terms, the categories are as follows:

Industrial batch reactors : 1 – 10 m2/m3 (depending on reactor capacity)

Laboratory batch reactors : 10 – 100 m2/m3 (depending on reactor capacity)

Continuous reactors (non micro) : 100 - 5,000 m2/m3 (depending on channel size)

Micro reactors : 5,000 - 50,000 m2/m3 (depending on channel size)

Small diameter channels have the advantage of high heat transfer capacity. Against this however they have lower flow capacity, higher pressure drop and an increased tendency to block. In many cases, the physical structure and fabrication techniques for micro reactors make cleaning and unblocking very difficult to achieve.

Temperature control

Temperature control is one of key functions of a chemical reactor. Poor temperature control can severely affect both yield and product quality. It can also lead to boiling or freezing within the reactor which may stop the reactor from working altogether. In extreme cases, poor temperature control can lead to severe over pressure which can be destructive on the equipment and potentially dangerous.

Single stage systems with high heating or cooling flux

In a batch reactor, good temperature control is achieved when the heat added or removed by the heat exchange surface (qx) equals the heat generated or absorbed by the process material (qp). For flowing reactors made up of tubes or plates, satisfying the relationship qx = qp does not deliver good temperature control since the rate of process heat liberation/absorption varies at different points within the reactor. Controlling the outlet temperature does not prevent hot/cold spots within the reactor. Hot or cold spots caused by exothermic or endothermic activity can be eliminated by relocating the temperature sensor (T) to the point where the hot/cold spots exists. This however leads to overheating or overcooling downstream of the temperature sensor.

  • Hot/cold spots are created when the reactor is treated as a single stage for temperature control

  • Hot/cold spots can be eliminated by moving the temperature sensor. This however causes overcooling or overheating downstream of the temperature sensor.

Many different types of plate or tube reactors use simple feed back control of the product temperature. From a user’s perspective, this approach is only suitable for processes where the effects of hot/cold spots do not compromise safety, quality or yield.

Single stage systems with low heating or cooling flux

Micro reactors can be tube or plates and have the key feature of small diameter flow channels (typically less than <1 mm). The significance of micro reactors is that the heat transfer area (A) per unit volume (of product) is very large. A large heat transfer area means that high values of qx can be achieved with low values of Tp – Tj. The low value of Tp – Tj limits the extent of over cooling that can occur. Thus the product temperature can be controlled by regulating the temperature of the heat transfer fluid (or the product).

  • Overheating/overcooling is prevented by the limited temperature difference between the product and heat transfer fluid.

The feedback signal for controlling the process temperature can be the product temperature or the heat transfer fluid temperature. It is often more practical to control the temperature of the heat transfer fluid.

Although micro reactors are efficient heat transfer devices, the narrow channels can result in high pressure drops, limited flow capacity and a tendency to block. They are also often fabricated in a manner which makes cleaning and dismantling difficult or impossible.

Multistage systems with high heating or cooling flux

Conditions within a continuous reactor change as the product passes along the flow channel. In an ideal reactor the design of the flow channel is optimised to cope with this change. In practice, this is achieved by breaking the reactor into a series of stages. Within each stage the ideal heat transfer conditions can be achieved by varying the surface to volume ratio or the cooling/heating flux. Thus stages where process heat output is very high either use extreme heat transfer fluid temperatures or have high surface to volume ratios (or both). By tackling the problem as a series of stages, extreme cooling/heating conditions to be employed at the hot/cold spots without suffering overheating or overcooling elsewhere. The significance of this is that larger flow channels can be used. Larger flow channels are generally desirable as they permit higher rate, lower pressure drop and a reduced tendency to block.

Mixing

Mixing is another important classifying feature for continuous reactors. Good mixing improves the efficiency of heat and mass transfer.

In terms of trajectory through the reactor, the ideal flow condition for a continuous reactor is plug flow (since this delivers uniform residence time within the reactor). There is however a measure of conflict between good mixing and plug flow since mixing generates axial as well as radial movement of the fluid. In tube type reactors (with or without static mixing), adequate mixing can be achieved without seriously compromising plug flow. For this reason, these types of reactor are sometimes referred to as plug flow reactors.

Continuous reactors can be classified in terms of the mixing mechanism as follows:

Mixing by diffusion

Diffusion mixing relies on concentration or temperature gradients within the product. This approach is common with micro reactors where the channel thicknesses are very small and heat can be transmitted to and from the heat transfer surface by conduction. In larger channels and for some types of reaction mixture (especially immiscible fluids), mixing by diffusion is not practical.

  • A simple tube can be used as a reactor. Small bore systems usually rely on mixing by diffusion

Mixing with the product transfer pump

In a continuous reactor, the product is continuously pumped through the reactor. This pump can also be used to promote mixing. If the fluid velocity is sufficiently high, turbulent flow conditions exist (which promotes mixing). The disadvantage with this approach is that it leads to long reactors with high pressure drops and high minimum flow rates. This is particularly true where the reaction is slow or the product has high viscosity. This problem can be reduced with the use of static mixers. Static mixers are baffles in the flow channel which are used to promote mixing. They are able to work with or without turbulent conditions. Static mixers can be effective but still require relatively long flow channels and generate relatively high pressure drops. The oscillatory baffled reactor is specialised form of static mixer where the direction of process flow is cycled. This permits static mixing with low net flow through the reactor. This has the benefit of allowing the reactor to be kept comparatively short.

  • The static mixer permits mixing with or without turbulent conditions

  • The oscillatory baffled reactor uses a combination of static mixing and cycling of flow direction.

Mixing with a mechanical agitator

Some continuous reactors use mechanical agitation for mixing (rather than the product transfer pump). Whilst this adds complexity to the reactor design, it offers significant advantages in terms of versatility and performance. With independent agitation, efficient mixing can be maintained irrespective of product throughput or viscosity. It also eliminates the need for long flow channels and high pressure drops.

One less desirable feature associated with mechanical agitators is the strong axial mixing they generate. This problem can be managed by breaking up the reactor into a series of mixed stages separated by small plug flow channels.

The most familiar form of continuous reactor of this type is the continuously stirred tank reactor (CSTR). This is essentially a batch reactor used in a continuous flow. The disadvantage with a single stage CSTR is that it can be relatively wasteful on product during start up and shutdown. The reactants are also added to a mixture which is rich in product. For some types of process, this can affect quality and yield. These problems are managed by using multi stage CSTRs. At the large scale, conventional batch reactors can be used for the CSTR stages.

See also

External links



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