Chemistry:Copper salicylate

From HandWiki
Structure of a hydrated copper(II) salicylate.[1] Color code: red = O, blue = Cu, gray = C, white = H.

Copper salicylate describes a range of compounds containing copper(II) and salicylate. Many compounds are known. They are generally blue. Simple species include:

  • Cu(O
    2
    C
    6
    H
    4
    OH)
    2
    (H
    2
    O)
    2
     · H2O
    .[2][3]
  • Cu
    2
    (
    2
    O
    2
    C
    6
    H
    4
    OH)
    4
    (H
    2
    O)
    2
     · L)
    (L = diverse solvent.[4]

Many copper(II) salicylates are known with amines and N-hetrerocyclic ligands. None appear to have commercial applications.

References

  1. Lutz, Martin; Kroon-Batenburg, Loes M. J. (2018). "Order-Disorder in Diaquobis(salicylato)copper(II) Revisited". Croatica Chemica Acta 91 (2). doi:10.5562/cca3362. 
  2. Jagner, S.; Hazell, R. G.; Larsen, K. P. (1976). "The crystal structure of diaquabis(salicylato)copper(II), Cu[C6H4(OH)COO]2(H2O)2". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 32 (2): 548–554. doi:10.1107/S0567740876003397. Bibcode1976AcCrB..32..548J. 
  3. Hanic, F.; Michalov, J. (1960). "Die Kristallstruktur von Kupfersalicylat-Tetrahydrat Cu(OH.C6H4.COO)2.4H2O". Acta Crystallographica 13 (4): 299–302. doi:10.1107/S0365110X60000753. Bibcode1960AcCry..13..299H. 
  4. V.V.Gorinchoy, Yu.A.Simonov, S.G.Shova, Y.N.Szafranski, K.I.Turta (2009). Zh.Strukt.Khim.(Russ.)(J.Struct.Chem.) 50: 1196.