Chemistry:Dienyl radical

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Short description: Organic chemical


Dienyl radicals are free radicals that can be formed by the oxidation of polyunsaturated fatty acids. These can combine with oxygen to form cis-trans lipid peroxyl radicals.[1]

Benzene can be oxidized using a photocatalyst, QuCN+ to produce benzene radical cation. This benzene radical cation can produce a dienyl radical through nucleophilic reagent.[2]

References

  1. ↑ Lemke, Thomas L.; Williams, David A. (24 January 2012). Foye's Principles of Medicinal Chemistry - Google Books. ISBN 9781609133450. https://books.google.com/books?id=Sd6ot9ul-bUC&q=dienyl+radical&pg=PA1461. Retrieved January 28, 2016. 
  2. ↑ Wang, Huamin; Gao, Xinlong; Lv, Zongchao; Abdelilah, Takfaoui; Lei, Aiwen (2019-06-26). "Recent Advances in Oxidative R 1 -H/R 2 -H Cross-Coupling with Hydrogen Evolution via Photo-/Electrochemistry: Focus Review" (in en). Chemical Reviews 119 (12): 6769–6787. doi:10.1021/acs.chemrev.9b00045. ISSN 0009-2665. PMID 31074264. https://pubs.acs.org/doi/10.1021/acs.chemrev.9b00045. 




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