Chemistry:Dithiooxamide
From HandWiki
Dithiooxamide, also known as rubeanic acid, is an organic compound. It is the sulfur analog of oxamide. It acts as a chelating agent, e.g. in the detection or determination of copper.[1][2] It has also been used as a building block in the synthesis of cyclen.[3]
Materials chemistry
Rubeanic acid has received much attention as a precursor to photonic or electroactive materials. It is a precursor to inorganic C-S-N rings.[4] It condenses with acid chlorides to thiazoles.[5] It forms coordination polymers.[6]
References
- ↑ "Stainsfile - Howell's rubeanic acid for copper". http://stainsfile.info/StainsFile/stain/pigment/rubeanic-howell.htm.
- ↑ "Strengthen science. Advance justice". http://www.ojp.usdoj.gov/nij/training/firearms-training/module12/fir_m12_t05_03_f.htm.
- ↑ David P. Reed and Gary R. Weisman (2004). "1,4,7,10-Tetraazacyclododecane". Organic Syntheses. http://www.orgsyn.org/demo.aspx?prep=v78p0073.; Collective Volume, 10, pp. 667
- ↑ McManus, Gordon D.; Rawson, Jeremy M.; Feeder, Neil; Van Duijn, Joost; McInnes, Eric J. L.; Novoa, Juan J.; Burriel, Ramon; Palacio, Fernando et al. (2001). "Synthesis, crystal structures, electronic structure and magnetic behaviour of the trithiatriazapentalenyl radical, C2S3N3". Journal of Materials Chemistry 11 (8): 1992–2003. doi:10.1039/b103303b.
- ↑ Sayresmith, Nickolas A.; Saminathan, Anand; Sailer, Joshua K.; Patberg, Shannon M.; Sandor, Kristin; Krishnan, Yamuna; Walter, Michael G. (2019). "Photostable Voltage-Sensitive Dyes Based on Simple, Solvatofluorochromic, Asymmetric Thiazolothiazoles". Journal of the American Chemical Society 141 (47): 18780–18790. doi:10.1021/jacs.9b08959. PMID 31660737.
- ↑ Kanaizuka, Katsuhiko; Haruki, Rie; Sakata, Osami; Yoshimoto, Mamoru; Akita, Yasuyuki; Kitagawa, Hiroshi (2008). "Construction of Highly Oriented Crystalline Surface Coordination Polymers Composed of Copper Dithiooxamide Complexes". Journal of the American Chemical Society 130 (47): 15778–15779. doi:10.1021/ja806799t. PMID 18983147.
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