Chemistry:E-diesel

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E-diesel is a synthetic diesel fuel created by Audi for use in automobiles. Currently, e-diesel is created by an Audi research facility in partnership with a company named Sunfire. The fuel is created from carbon dioxide, water, and electricity with a process powered by renewable energy sources to create a liquid energy carrier called blue crude (in contrast to regular crude oil) which is then refined to generate e-diesel. E-diesel is considered to be a carbon-neutral fuel as it does not extract new carbon and the energy sources to drive the process are from carbon-neutral sources. As of April 2015, an Audi A8 driven by Federal Minister of Education and Research in Germany is using the e-diesel fuel.[1][2]

Catalytic conversions

WaterCO2
Electrolysis of Water
OxygenHydrogen
Conversion Reactor
WaterHydrogenCO
F-T Reactor
Sunfire power-to-liquids system

Sunfire, a clean technology company, operates a pilot plant in Dresden, Germany. The current process involves high-temperature electrolysis powered by electricity generated from renewable energy sources to split water into hydrogen and oxygen. The next two chemical processes to create a liquid energy carrier called blue crude are done at a temperature of 220 °C (428 °F) and a pressure of 25 bars (2,500 kPa). In a conversion step, hydrogen and carbon dioxide are used to create syngas with water as byproduct. The syngas, which contains carbon monoxide and hydrogen, reacts to generate the blue crude.

  • Sunfire power-to-liquids system: Base products are carbon dioxide (CO2) and water (H2O)[3]
1st step: Electrolysis of Water (SOEC) −water is split into hydrogen and oxygen.
2nd step: Conversion Reactor (RWGSR) −hydrogen and carbon dioxide are inputs to the Conversion Reactor that outputs hydrogen, carbon monoxide, and water.
3rd step: F-T Reactor −hydrogen and carbon monoxide are inputs[4][5] to the F-T Reactor that outputs paraffinic and olefinic hydrocarbons, ranging from methane to high molecular weight waxes.[6]

The final step is also known as Fischer–Tropsch process which was first developed in 1925 by German chemists Franz Fischer and Hans Tropsch. After the blue crude is produced, it can be refined to create e-diesel on site, saving the fuel and other infrastructure costs on crude transportation.[7] As of April 2015, Sunfire has a capability to produce a limited amount of fuel at 160 litres (35 imp gal; 42 US gal) a day. There is a plan to increase the production to an industrial scale.[8]

Audi also partners with a company named Climeworks which manufactures Direct Air Capture technology. Climeworks technologies can absorb atmospheric carbon dioxide which is chemically captured at the surface of a sorbent until it becomes saturated. At that point, the sorbent is introduced with 95 °C (203 °F) heat in a desorption cycle to drive out the high-purity carbon dioxide that can be used during the conversion step of the blue crude generation process. The atmospheric carbon dioxide capturing process has 90% of energy demand in the form of low-temperature heat and the rest from electrical energy for pumping and control. The combined plant of Climeworks and Sunfire in Dresden became operational in November 2014.[7] A plant on Herøya in Norway, producing 10 million liters per year, is being considered, as CO
2 from a fertilizer plant is readily available and electricity is relatively cheap in Norway.[9]

Properties

As much as eighty percent of blue crude can be converted into e-diesel. The fuel contains no sulfur or aromatics, and has a high cetane number. These properties allow it to be blended with typical fossil diesel and used as a replacement fuel in automobiles with diesel engines.[7]

Oxygen by-product

In future designs,[10][11] the oxygen by-product may be combined with renewable natural gas in the oxidative coupling of methane to ethylene:[12][13]

2CH4 + O2 → C2H4 + 2H2O

The reaction is exothermic (∆H = -280 kJ/mol) and occurs at high temperatures (750–950 ˚C).[14] The yield of the desired C2 products is reduced by non-selective reactions of methyl radicals with the reactor surface and oxygen, which produces carbon monoxide and carbon dioxide by-products. Another ethylene production initiative developed by the European Commission through the Seventh Framework Programme for Research and Technological Development is the OCMOL process, which is the Oxidative Coupling of Methane (OCM) and simultaneous Reforming of Methane (RM) in a fully integrated reactor.[15]

Biocatalytic conversions

Helioculture combines brackish water (or graywater), nutrients, photosynthetic organisms, carbon dioxide, and sunlight to create fuel.

Audi also partnered with a now-defunct United States company, Joule, to develop Sunflow-D as e-diesel for Audi. Joule's planned plant in New Mexico involved the use of genetically modified microorganisms in bright sunlight to act as catalyst for the conversion of carbon dioxide and salty water into hydrocarbons.[7][16] The process could be modified for longer molecular chains to produce alkanes in order to create synthetic diesel.[17][18][19][20]

Joule was the first company to patent a modified organism that continuously secretes hydrocarbon fuel. The organism is a single-celled cyanobacterium, also known as blue-green algae, although it is technically not an algae. It produces the fuel using photosynthesis, the same process that multi-cellular green plants use, to make sugars and other materials from water, carbon dioxide, and sunlight.[21]

Similar initiatives

There are other initiatives to create synthetic fuel from carbon dioxide and water, however they are not part of Audi's initiatives and the fuels are not called e-diesel. The water splitting methods vary.

The U.S. Naval Research Laboratory (NRL) is designing a power-to-liquids system using the Fischer-Tropsch Process to create fuel on board a ship at sea,[57] with the base products carbon dioxide (CO2) and water (H2O) being derived from sea water via "An Electrochemical Module Configuration For The Continuous Acidification Of Alkaline Water Sources And Recovery Of CO2 With Continuous Hydrogen Gas Production".[58][59]

See also


References

  1. ↑ Palmer, Ewan (27 April 2015). "Audi creates green 'e-diesel fuel of the future' using just carbon dioxide and water". International Business Times. http://www.ibtimes.co.uk/audi-creates-green-e-diesel-fuel-future-using-just-carbon-dioxide-water-1498524. 
  2. ↑ McSpadden, Kevin (28 April 2005). "Audi Just Invented Fuel Made From CO2 and Water". Time. http://time.com/3837814/audi-environmental-protection-green-energy-climate-change-cars/. Retrieved 29 April 2015. 
  3. ↑ "Fuels from solar energy, CO
    2     and water"    . Sunfire GmbH. http://www.sunfire.de/en/produkte/fuel/power-to-liquids.     
  4. ↑ Ciferno, Jared; Marano, John (June 2002). "Benchmarking Biomass Gasification Technologies for Fuels, Chemicals and Hydrogen Production". National Energy Technology Laboratory. http://www.netl.doe.gov/File%20Library/research/coal/energy%20systems/gasification/BMassGasFinal.pdf. 
  5. ↑ "Syngas Optimized for Intended Products". U.S. DEPARTMENT OF ENERGY. http://www.netl.doe.gov/research/coal/energy-systems/gasification/gasifipedia/syngas-optimization. 
  6. ↑ Sang-Eon Park; Jong-San Chang; Kyu-Wan Lee (27 October 2004). Carbon Dioxide Utilization for Global Sustainability: Proceedings of the 7th International Conference on Carbon Dioxide Utilization, Seoul, Korea, October 12-16, 2003. Elsevier. p. 18. ISBN 978-0-08-047217-1. https://books.google.com/books?id=RX6kgpBaR_AC&pg=PA18. "Traditional Fischer-Tropsch synthesis using CO/H2 feedgas produces paraffinic and olefinic hydrocarbons, ranging from methane to high molecular weight waxes." 
  7. ↑ 7.0 7.1 7.2 7.3 "Audi in new e-fuels project: synthetic diesel from water, air-captured CO2 and green electricity; "Blue Crude"". Green Car Congress.. 14 November 2014. http://www.greencarcongress.com/2014/11/20141114-audibluecrude.html. 
  8. ↑ MacDonald, Fiona (27 April 2015). "Audi has successfully made diesel fuel from carbon dioxide and water". Science Alert. https://www.sciencealert.com/audi-have-successfully-made-diesel-fuel-from-air-and-water. 
  9. ↑ "Norsk selskap kan bli først i verden til å produsere Audis "vidunderdiesel"". Teknisk Ukeblad. 2016-06-10. http://www.tu.no/artikler/norsk-selskap-kan-bli-forst-i-verden-til-a-produsere-audis-vidunderdiesel/348424. 
  10. ↑ "HELMETH EU: A Project in the Amount of EUR 3.8 Million for More Efficient Methane Gas Production from Regenerative Power by Thermal Interlinkage of Chemical Processes". Karlsruhe Institute of Technology. 10 April 2014. http://www.kit.edu/kit/english/pi_2014_14950.php. 
  11. ↑ Kondratenko, Evgenii V.; Rodemerck, Uwe (9 January 2013). "A Dual-Reactor Concept for the High-Yielding Conversion of Methane into Higher Hydrocarbons". ChemCatChem 5 (3): 697–700. doi:10.1002/cctc.201200779. 
  12. ↑ Zhang, Q. (2003). "Recent Progress in Direct Partial Oxidation of Methane to Methanol". J. Natural Gas Chem. 12: 81–89. 
  13. ↑ Olah, G., Molnar, A. "Hydrocarbon Chemistry" John Wiley & Sons, New York, 2003. ISBN:978-0-471-41782-8.
  14. ↑ Lunsford, J.H. (1995). "The catalytic coupling of methane". Angew. Chem. Int. Ed. Engl. 34 (9): 970–980. doi:10.1002/anie.199509701. 
  15. ↑ "OCMOL: Oxidative Coupling of Methane followed by Oligomerization to Liquids". http://www.ocmol.eu/uploads/media/OCMOL_brochure.pdf. 
  16. ↑ "A Transformative Production Platform for Liquid Fuel from the Sun". Joule. http://www.sae.org/events/gim/presentations/2013/glass_david.pdf. 
  17. ↑ Kacher, Georg (29 July 2013). "CAR tech: Audi's miracle e-fuel (2013)". Car Magazine. http://www.carmagazine.co.uk/car-news/industry-news/audi/car-tech-audis-miracle-e-fuel-2013/. 
  18. ↑ "Joule and Audi partner on sustainable liquid transportation fuels". Green Car Congress. 17 September 2012. http://www.greencarcongress.com/2012/09/joule-audi-20120917.html. 
  19. ↑ "Audi e-diesel and e-ethanol". Audi. http://www.audi-technology-portal.de/en/mobility-for-the-future/audi-future-lab-mobility_en/audi-future-energies_en/audi-e-diesel-and-e-ethanol. 
  20. ↑ Casey, Tina (May 12, 2015). "Buh-Bye, Corn Ethanol: Joule Makes The Same Thing From Recycled CO
    2    "    . Sustainable Enterprises Media, Inc.. http://cleantechnica.com/2015/05/12/buh-bye-corn-ethanol-joule-makes-thing-recycled-co2/.     
  21. ↑ WALD, MATTHEW L. (September 13, 2010). "Biotech Company to Patent Fuel-Secreting Bacterium". NYTimes.com. The New York Times Company. https://www.nytimes.com/2010/09/14/science/earth/14fuel.html. 
  22. ↑ "Sunshine to Petrol". United States Department of Energy (DOE). http://energy.sandia.gov/energy/renewable-energy/solar-energy/sunshine-to-petrol/. 
  23. ↑ SNL: Sunshine to Petrol - Solar Recycling of Carbon Dioxide into Hydrocarbon Fuels
  24. ↑ "Sandia and Sunshine-to-Petrol: Renewable Drop-in Transportation Fuels". U.S. Federal Government. Oct 29, 2013. https://www.fbo.gov/index?s=opportunity&mode=form&id=698e254d2c8fea2fc478add76d2aac1c&tab=core&_cview=0. 
  25. ↑ Biello, David (September 23, 2010). "Reverse Combustion: Can CO
    2     Be Turned Back into Fuel?"    . http://www.scientificamerican.com/article/turning-carbon-dioxide-back-into-fuel/.     
  26. ↑ Lavelle, Marianne (August 11, 2011). "Carbon Recycling: Mining the Air for Fuel". National Geographic Society. http://news.nationalgeographic.com/news/energy/2011/08/110811-turning-carbon-emissions-into-fuel/. 
  27. ↑ "Bright Way to Convert Greenhouse Gas to Biofuel". Weizmann UK. Registered Charity No. 232666. 18 December 2012. http://web.weizmann.org.uk/2012/12/18/bright-way-to-convert-greenhouse-gas-to-biofuel/. [yes|permanent dead link|dead link}}]
  28. ↑ "CO2 & H2O Dissociation Process". New CO
    2     Fuels Ltd. http://www.newco2fuels.co.il/technology/1/process.     
  29. ↑ Newsletter NewCO2Fuels, Issue 1, September 2012
  30. ↑ From challenge to opportunity New CO2 Fuels: An Introduction...
  31. ↑ "SOLAR-JET Project". SOLAR-JET Project Office: ARTTIC. http://www.solar-jet.aero/page/about-solar-jet/objectives.php. 
  32. ↑ "Sunlight to jet fuel". Eidgenössische Technische Hochschule Zürich. https://www.ethz.ch/en/news-and-events/eth-news/news/2014/04/sunlight-to-jet-fuel.html. 
  33. ↑ Alexander, Meg (May 1, 2014). ""Solar" jet fuel created from water and carbon dioxide". Gizmag. http://www.gizmag.com/sunlight-carbon-dioxide-jet-fuel/31872/. 
  34. ↑ "SOLARJET demonstrates full process for thermochemical production of renewable jet fuel from H2O & CO2". BioAge Group, LLC. 28 April 2015. http://www.greencarcongress.com/2015/04/20150428-solarjet.html. 
  35. ↑ "Aldo Steinfeld - Solar Syngas". Google Inc.. https://b60099084-dev-blakely-dot-google-solveforx.appspot.com/moonshots/aldo-steinfeld-solar-syngas. [yes|permanent dead link|dead link}}]
  36. ↑ "Brewing fuels in a solar furnace". http://www.psi.ch/lst/BooksEN/MRS_Bulletin_-_Energy_Quarterly,_Vol_38,_2013.pdf. 
  37. ↑ "Syntrolysis, Synthetic Fuels from Carbon Dioxide, Electricity and Steam". http://www4vip.inl.gov/factsheets/docs/syntrolysis.pdf. 
  38. ↑ "Synthetic Fuel (syntrolysis)". Thoughtware.TV. June 17, 2008. http://www.thoughtware.tv/test/show/2274. 
  39. ↑ Stoots C M; O'Brien J E; Hartvigsen J (January 1, 2007). "Carbon neutral production of syngas via high temperature electrolytic reduction of steam and CO2". ASME 2007 International Mechanical Engineering Congress and Exposition. 15: Sustainable Products and Processes. ASME. pp. 185–194. doi:10.1115/IMECE2007-43667. ISBN 978-0-7918-4309-3. http://proceedings.asmedigitalcollection.asme.org/proceeding.aspx?articleid=1601044. 
  40. ↑ Nuclear Hydrogen Initiative Overview
  41. ↑ Nuclear Hydrogen Production Technology
  42. ↑ "Electrolysis For Synthetic Fuel Production". http://www.topsoe.com/sites/default/files/topsoe_scot_electrolysis_synthetic_fuel_production.pdf. 
  43. ↑ "The WindFuels Primer - Basic Explanation for the Non-scientist". Doty Energy. http://dotyenergy.com/Introduction/primer.htm. 
  44. ↑ Securing Our Energy Future by Efficiently Recycling CO2 into Transportation Fuels
  45. ↑ "The AFS Process - turning air into a sustainable fuel". Air Fuel Synthesis Limited. http://www.airfuelsynthesis.com/technology/technical-review.html. 
  46. ↑ Case Study: AFS demonstrator unit[yes|permanent dead link|dead link}}]
  47. ↑ "Cars Fueled by Air?". Planet Forward. http://www.planetforward.org/tv-segments/cars-fueled-by-air. 
  48. ↑ Rapier, Robert (October 31, 2012). "Investors Beware of Fuel from Thin Air". Investing Daily, a division of Capitol Information Group, Inc.. http://www.investingdaily.com/15833/investors-beware-of-fuel-from-thin-air/. 
  49. ↑ K.R. WILLIAMS AND N. VAN LOOKEREN CAMPAGNE, SYNTHETIC FUELS FROM ATMOSPHERIC CARBON DIOXIDE
  50. ↑ "BGU Researchers invent Green Alternative to Crude Oil". Ben-Gurion University of the Negev. 13 November 2013. http://in.bgu.ac.il/en/Pages/news/oil_greenalternative.aspx. 
  51. ↑ "Recent Success Story: Converting carbon dioxide, a damaging greenhouse gas, into fuel that may be used for transportation". Israel Strategic Alternative Energy Foundation. http://www.i-saef.org/early-success.html. 
  52. ↑ "BGU Researchers Develop New Type of Crude Oil Using Carbon Dioxide and Hydrogen". American Associates (AABGU). http://www.bgustudyabroad.org/media-center/news-releases/bgu-crude-oil.html. 
  53. ↑ "BGU researchers developing more efficient process for hydrogenation of CO
    2     to synthetic crude"    . BioAge Group, LLC. 21 November 2013. http://www.greencarcongress.com/2013/11/20131121-bgu.html.     
  54. ↑ "Fuel of the future: Research facility in Dresden produces first batch of Audi e-diesel". Ingolstadt/Berlin: AUDI AG.. 2015-04-21. https://www.audi-mediaservices.com/publish/ms/content/en/public/pressemitteilungen/2015/04/21/fuel_of_the_future.html. 
  55. ↑ Rapier, Robert. "Is Audi's Carbon-Neutral Diesel a Game-Changer?". Energy Trends Insider. http://www.energytrendsinsider.com/2015/04/30/is-audis-carbon-neutral-diesel-a-game-changer/. 
  56. ↑ Novella, Steven (28 April 2015). "Apr 28 2015 Audi's E-Diesel". Steven Novella, MD. http://theness.com/neurologicablog/index.php/audis-e-diesel/. 
  57. ↑ "How the United States Navy Plans to Turn Seawater into Jet Fuel". altenergy.org. http://www.altenergy.org/new_energy/seawater-into-jet-fuel.html. 
  58. ↑ "Patent: US 20140238869 A1". Google Inc.. http://www.google.com/patents/US20140238869?cl=en. 
  59. ↑ The total carbon content of the world's oceans is roughly 38,000 GtC. Over 95% of this carbon is in the form of dissolved bicarbonate ion (HCO3 −). (Cline 1992, The Economics of Global Warming; Institute for International Economics: Washington D.C.). The dissolved bicarbonate and carbonate of the ocean is essentially bound CO2 and the sum of these species along with gaseous CO2, shown in the following equation, represents the total carbon dioxide concentration [CO2]T, of the world's oceans. Σ[CO2]T=[CO2(g)]l+[HCO3 −]+[CO3 2−]
  60. ↑ E-benzin

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