Chemistry:Fluoroformic acid
From HandWiki
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| Names | |
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| IUPAC name
Fluoroformic acid
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| Other names
Carbonofluoridic acid
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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| Properties | |
| CHFO2 | |
| Molar mass | 64.015 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Fluoroformic acid is a fluoride derivative of formic acid that has been the subject of a number of theoretical studies in chemistry.[1][2][3] As of 1985, elementary textbooks generally state that it does not exist due to its rapid decomposition into carbon dioxide and hydrofluoric acid, although some experiments have attempted to isolate it.[1][needs update]
The anion, fluoroformate, is has been confirmed to exist and be stable.[4] Its structure has been characterized.[4]
See also
- Formyl fluoride
References
- ↑ 1.0 1.1 Havlas, Zdenek; Kovar, Tomas; Zahradnik, Rudolf (1985). "Does Fluoroformic Acid Exist?". American Chemical Society (78): 7243. http://electronicsandbooks.com/edt/manual/Magazine/J/Journal%20of%20the%20American%20Chemical%20Society%20US/1985%20%20(vol%20107)/25%20%20(7239-7804)/7243-7246.pdf.
- ↑ Wiedmann, Fred A.; Wesdemiotis, Chrys (1994-03-01). "Experimental evidence for the existence of fluoroformic acid and its ionized and protonated forms in the gas phase". Journal of the American Chemical Society 116 (6): 2481–2485. doi:10.1021/ja00085a031. ISSN 0002-7863. https://doi.org/10.1021/ja00085a031.
- ↑ PubChem. "Fluoroformic acid" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/90980996.
- ↑ 4.0 4.1 Thomas, Daniel A.; Mucha, Eike; Gewinner, Sandy; Schöllkopf, Wieland; Meijer, Gerard; von Helden, Gert (3 May 2018). "Vibrational Spectroscopy of Fluoroformate, FCO2–, Trapped in Helium Nanodroplets". The Journal of Physical Chemistry Letters 9 (9): 2305–2310. doi:10.1021/acs.jpclett.8b00664.
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