Chemistry:Gold in California

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Three gold nuggets from Tuolumne County, California, similar to what the early miners would have found.

Gold became highly concentrated in California, United States as the result of global forces operating over hundreds of millions of years. Volcanoes, tectonic plates and erosion all combined to concentrate billions of dollars' worth of gold in the mountains of California . During the California Gold Rush, gold-seekers known as "Forty-Niners" retrieved this gold, at first using simple techniques, and then developing more sophisticated techniques, which spread around the world.

Geology

Gold-bearing magma rising after being subducted under the continental crust.

Geologic evidence indicates that over a span of at least 400 million years, gold that had been widely dispersed in the Earth’s crust became more concentrated by geologic actions into the gold-bearing regions of California. Only gold that is concentrated can be economically recovered. Some 400 million years ago, rocks that would be accreted onto western North America to build California lay at the bottom of a large sea. Subsea volcanoes deposited lava and minerals (including gold) onto the sea floor; sometimes enough that islands were created.[1] Between 400 million and 200 million years ago, geologic movement forced the sea floor and these volcanic islands and deposits eastwards, colliding with the North American plate, which was moving westwards.[2]

Beginning about 200 million years ago, tectonic pressure forced the sea floor beneath the American continental mass.[3] As it sank, or subducted, beneath the western margin of the North American plate portions of the sea floor and overlying continental crust heated and melted, producing large molten masses (magma). Being lighter and hotter than the ancient continental crust above it, this magma forced its way upward, cooling as it rose[4] to become the granite rock found throughout the Sierra Nevada and other mountains in California today.[5] As the hot magma cooled, solidified, and came in contact with water, minerals with similar melting temperatures tended to concentrate together.[5] As the magma solidified, gold became concentrated within hydrous silica solutions and was deposited within veins of quartz.[4][6]

Goldfields in the mountains of northern and central California.

As the Sierra Nevada and other mountains in California were forced upwards by the actions of tectonic plates, the solidified minerals and rocks were raised to the surface and subjected to erosion.[7] The surrounding rock then weathered and crumbled, and the exposed gold and other materials were carried downstream by water. Because gold is denser than almost all other minerals, this process further concentrated the gold as it sank, and pockets of gold gathered in quiet gravel beds along the sides of old rivers and streams.[8]

The California mountains rose and shifted several times within the last fifty million years, and each time, old streambeds moved and were dried out, leaving the deposits of gold resting within the ancient gravel beds where the gold had been collecting.[9] Newer rivers and streams then developed, and some of these cut through the old channels, carrying the gold into still larger concentrations.[9]

The Forty-Niners of the California Gold Rush first focused their efforts on these deposits of gold, which had been gathered in the gravel beds by hundreds of millions of years of geologic action.

Gold recovery

Because the gold in the California gravel beds was so richly concentrated, the early forty-niners simply panned for gold in California's rivers and streams, a form of placer mining.[10][11] However, panning cannot take place on a large scale, and industrious miners and groups of miners graduated to placer mining "cradles" and "rockers" or "long-toms"[12] to process larger volumes of gravel.[13] Miners would also engage in "coyoteing".[14] This method involved digging a shaft 6 to 13 meters (20 to 43 ft) deep into placer deposits along a stream. Tunnels were then dug in all directions to reach the richest veins of pay dirt.

In the most complex placer mining, groups of prospectors would divert the water from an entire river into a sluice alongside the river, and then dig for gold in the newly exposed river bottom.[15] Modern estimates by the U.S. Geological Survey are that some 12 million ounces[16] (370 t) of gold were removed in the first five years of the Gold Rush (worth over United States dollar 16 billion at December 2010 prices).[17]

In the next stage, by 1853, hydraulic mining was used on ancient gold-bearing gravel beds on hillsides and bluffs in the goldfields.[18] In a modern style of hydraulic mining first developed in California, a high-pressure hose directed a powerful stream or jet of water at gold-bearing gravel beds.[19] The loosened gravel and gold would then pass over sluices, with the gold settling to the bottom where it was collected. By the mid-1880s, it is estimated that 11 million ounces (340 t) of gold (worth approximately US$15 billion at December 2010 prices) had been recovered by "hydraulicking".[17] This style of hydraulic mining later spread around the world.

A byproduct of these extraction methods was that large amounts of gravel, silt, heavy metals, and other pollutants went into streams and rivers.[20] (As of 1999) many areas still bear the scars of hydraulic mining, since the resulting exposed earth and downstream gravel deposits do not support plant life.[21]

After the Gold Rush had concluded, gold recovery operations continued. The final stage to recover loose gold was to prospect for gold that had slowly washed down into the flat river bottoms and sandbars of California's Central Valley and other gold-bearing areas of California (such as Scott Valley in Siskiyou County). By the late 1890s, dredging technology (also invented in California) had become economical,[22] and it is estimated that more than 20 million ounces (620 t) were recovered by dredging (worth approximately US$28 billion at December 2010 prices).[17]

Both during the Gold Rush and in the decades that followed, gold-seekers also engaged in "hard-rock" mining, that is, extracting the gold directly from the rock that contained it (typically quartz), usually by digging and blasting to follow and remove veins of the gold-bearing quartz.[23] By 1851, quartz mining had become the major industry of Coloma.[24] Once the gold-bearing rocks were brought to surface, the rocks were crushed and the gold separated, either using separation in water, using its density difference from quartz sand, or by washing the sand over copper plates coated with mercury (with which gold forms an amalgam). Loss of mercury in the amalgamation process was a source of environmental contamination.[25] Eventually, hard-rock mining wound up becoming the single largest source of gold produced in the Gold Country.[17][26] The total production of gold in California from then till now is estimated at 118 million ounces (3700 t).[27]

Geological after-effects

There were decades of minor earthquakes, more than at any other time in the historical record for Northern California, before the 1906 San Francisco earthquake. Previously interpreted as precursory activity to the 1906 earthquake, they have been found to have a strong seasonal pattern and due to large seasonal sediment loads in coastal bays that overlie faults as a result of mining of gold inland.[28]

Notes

  1. Hill, Mary (1999). Gold: the California story. Berkeley and Los Angeles: University of California Press.  p. 167.
  2. Hill, Mary (1999), p. 168.
  3. Hill, Mary (1999), pp. 168–69.
  4. 4.0 4.1 Brands, H.W. (2003). The age of gold: the California Gold Rush and the new American dream. New York: Doubleday. , pp. 195–196.
  5. 5.0 5.1 Hill, Mary (1999), pp. 149–58
  6. Hill, Mary (1999), pp. 174–78.
  7. Hill, Mary (1999), pp. 169–173.
  8. Hill, Mary (1999), pp. 94–100.
  9. 9.0 9.1 Hill, Mary (1999), pp. 105–110.
  10. Young, Otis E. (1970). Western Mining. Norman: University of Oklahoma Press. pp. 108–110. ISBN 0-8061-1352-9. 
  11. Brands, H. W. (2003), pp. 198–200.
  12. Images and detailed description of placer mining tools and techniques ; image of a long tom
  13. Bancroft, Hubert Howe (1888), pp. 87–88.
  14. Young, Otis E. (1970). Western Mining. Norman: University of Oklahoma Press. pp. 110–111. ISBN 0-8061-1352-9. 
  15. Rawls, James J. and Orsi, Richard (eds.) (1999), p. 90.
  16. The Troy weight system is traditionally used to measure precious metals, not the more familiar avoirdupois weight system. The term "ounces" used in this article to refer to gold typically refers to troy ounces. There are some historical uses where, because of the age of the use, the intention is ambiguous.
  17. 17.0 17.1 17.2 17.3 Mining History and Geology of the Mother Lode (accessed October 16, 2006).
  18. Starr, Kevin (2005), p. 89.
  19. Use of volumes of water in large-scale gold-mining dates at least to the time of the Roman Empire. Roman engineers built extensive aqueducts and reservoirs above gold-bearing areas, and released the stored water in a flood so as to remove over-burden and expose gold-bearing bedrock, a process known as hushing. The bedrock was then attacked using fire and mechanical means, and volumes of water were used again to remove debris, and to process the resulting ore. Examples of this Roman mining technology may be found at Las Médulas in Spain and Dolaucothi in South Wales. The gold recovered using these methods was used to finance the expansion of the Roman Empire. Hushing was also used in lead and tin mining in Northern Britain and Cornwall. There is, however, no evidence of the earlier use of hoses, nozzles and continuous jets of water in the manner developed in California during the Gold Rush.
  20. Rawls, James J. and Orsi, Richard (eds.) (1999), pp. 32–36.
  21. Rawls, James J. and Orsi, Richard (eds.) (1999), pp. 116–121.
  22. Rawls, James J. and Orsi, Richard (eds.) (1999), p. 199.
  23. Rawls, James J. and Orsi, Richard (eds.) (1999), pp. 36–39.
  24. "Amador City, California – Historic Gold Mining Town. [full text [book links]"]. readme-ebooks.org, The Pierian Press, 8 August 1999. Online. Internet.. 18 May 1743. http://readme-ebooks.org/databases/cgi-bin/main.asp?searchtype=kwq.asp&qu=@recnumber%20EBK30010065&FreeText=&sc=%2Fpierianp%2Febk%2F. Retrieved 6 September 2010. [yes|permanent dead link|dead link}}]
  25. Rawls, James J. and Orsi, Richard (eds.) (1999), pp. 39–43.
  26. "Mercury Contamination from Historical Gold Mining in California". U.S. Geological Survey. http://pubs.usgs.gov/fs/2005/3014/. Retrieved 2008-02-26. 
  27. Hausel, Dan. "California – Gold, Geology & Prospecting". http://californiangold.blogspot.dk/. Retrieved 19 February 2013. 
  28. Seasonal Seismicity of Northern California Before the Great 1906 Earthquake, (Journal) Pure and Applied Geophysics, ISSN 0033-4553 (Print) 1420-9136 (Online), volume 159, Numbers 1–3 / January, 2002, Pages 7–62.

References

  • Bancroft, Hubert Howe (1884–1890) History of California, vols. 18–24, The works of Hubert Howe Bancroft, complete text online
  • Brands, H.W. (2003). The age of gold: the California Gold Rush and the new American dream. New York City: Doubleday. ISBN 0-385-72088-2. 
  • Hill, Mary (1999). Gold: the California story. Berkeley and Los Angeles: University of California Press. ISBN 0-520-21547-8. 
  • Rawls, James J. and Orsi, Richard J. (eds.) (1999). A golden state: mining and economic development in Gold Rush California (California History Sesquicentennial Series, 2). Berkeley and Los Angeles: University of California Press. ISBN 0-520-21771-3. 
  • Starr, Kevin (2005). California: a history. New York: The Modern Library. ISBN 0-679-64240-4.