Chemistry:Heat release parameter

From HandWiki

In combustion, heat release parameter (or gas expansion parameter) is a dimensionless parameter which measures the amount of heat released by the combustion process.[1][2] It is defined as

[math]\displaystyle{ \alpha = \frac{T_b-T_u}{T_b} }[/math]

where

  • [math]\displaystyle{ T_b }[/math] is the burnt gas temperature
  • [math]\displaystyle{ T_u }[/math] is the unburnt mixture temperature.

In typical combustion process, [math]\displaystyle{ \alpha\approx 0.7-0.9 }[/math]. For isobaric combustion, using ideal gas law, the parameter can be expressed in terms of density,[3] i.e.,

[math]\displaystyle{ \alpha = \frac{T_b-T_u}{T_b} = \frac{\rho_u-\rho_b}{\rho_u}. }[/math]

The ratio of burnt gas to unburnt gas temperature is

[math]\displaystyle{ \frac{T_b}{T_u} = \frac{\rho_u}{\rho_b}=\frac{1}{1-\alpha}. }[/math]

See also

References

  1. Williams, Forman A. "Combustion theory." (1985).
  2. Linan, Amable, and Forman Arthur Williams. "Fundamental aspects of combustion." (1993).
  3. Clavin, P. (1985). Dynamic behavior of premixed flame fronts in laminar and turbulent flows. Progress in energy and combustion science, 11(1), 1-59.