Chemistry:Lithium formate

From HandWiki
Lithium formate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 209-133-0
  • monohydrate: 676-657-8
UNII
Properties
CHLiO2
Molar mass 51.96 g·mol−1
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H315, H319, H335
P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P271, P280, P302+352, P304+340, P305+351+338, P319Script error: No such module "Preview warning".Category:GHS errors, P321, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P403+233, P405, P501
Related compounds
Other anions
Lithium acetate
Other cations
Sodium formate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Lithium formate (also called lithium methanoate) is an ionic chemical compound with the formula HCOOLi, and a molar mass of 51.95 g/mol. It is potentially nephrotoxic[1].

Properties

Lithium formate crystalises in the orthorhombic crystal system, with space group Pna21. The unit cell has dimensions a = 6.99 Å, b = 6.50 Å and c = 4.85 Å.[2]

The monohydrate loses water to form the anhydrous salt at 94°C. Decomposition to lithium carbonate, carbon monoxide and hydrogen occurs at 230°C.[3][2]

References

  1. PubChem. "Lithium formate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/23680280. 
  2. 2.0 2.1 Ans, Jean d'; Lax, Ellen (1998) (in de). Taschenbuch für Chemiker und Physiker. Springer. p. 532. ISBN 978-3-540-60035-0. https://books.google.com/books?id=ssy59etLaksC&pg=PA532. 
  3. Meisel, T.; Halmos, Z.; Seybold, K.; Pungor, E. (February 1975). "The thermal decomposition of alkali metal formates". Journal of Thermal Analysis 7 (1): 73–80. doi:10.1007/BF01911627.