Chemistry:Oxalate phosphite

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Short description: Class of chemical compounds

The oxalate phosphites are chemical compounds containing oxalate and phosphite anions. They are also called oxalatophosphites or phosphite oxalates. Oxalate phosphates can form metal organic framework compounds.

Related compounds include the nitrite oxalates, arsenite oxalates,[1][2] phosphate oxalates and oxalatophosphonates.

The oxalate ion is rectangular and planar. The phosphite ion is shaped as a triangular pyramid. Because of high charge and stiff shape they will bridge across more than one cation, in particular those hard cations with a higher charge such as +3. Hydrogen can convert some of the oxygen on the anions to OH and reduce the charge. Many oxalate phosphite compounds have microporous structures where amines direct the structure formation.[3]

List

name chem mw crystal system space group unit cell Å volume density comment references
peha = pentaethylenehexamine [(H6peha)0.17(H2O)1.5][Al2(HPO3)2(C2O4)(HCOO)] +formate [4]
(H13C5NOH)0.5(H2C13H14N2)0.25[Al2(HPO3)2(C2O4)(OH)(H2O)]0.5H2O [4]
Li2(VOHPO3)2C2O4•6H2O triclinic P1 a=6.3592, b=8.0789, c=9.1692, α=64.390°, β=87.277°, γ=67.624° [5]
Li2(VOHPO3)2C2O4•4H2O monoclinic P21/a a=6.3555 b=12.6368 c=9.0242 β=105.167° [5]
Li2(VO)2(HPO3)2C2O4 [6]
diammonium (μ-oxalato)-bis(μ-phosphonato)-dioxo-di-vanadium hydrate (NH4)2(VOHPO3)2C2O4 2·9H2O triclinic P1 a = 6.3844, b = 7.2278, c = 9.2965, α = 67.260°, β = 72.927°, γ = 85.848° [7]
(μ6-Oxalato)-bis(μ4-hydrogen phosphonato)-bis(μ2-aqua)-bis(μ2-oxo)-di-sodium-di-vanadium Na2(VO)2(HPO3)2C2O4 463.87 triclinic P1 a 6.3255 b 6.7760 c 8.0759, α 104.992° β 101.679° γ 99.120° Z=1 319.20 2.413 blue [6]
K2(VO)2(HPO3)2C2O4 514.10 monoclinic C2/c a 17.75 b 6.370 c 13.977, β 115.42° Z=4 1427 2.393 blue [6]
K2MnII2(H2O)2C2O4(HPO3)2 472.09 hexagonal P63/m a=9.7371 c=22.4924 1846.8 2.547 pink [8]
(CN3H6)2·Mn2.5(HPO3)(C2O4)2.5(H2O)·H2O [9]
piperazine [C4N2H12][MnII2(HPO3)2(C2O4)] monoclinic P21/c a=6.0627 b=10.7122 c=10.387 β=97.956 Z=2 668.1 2.217 pale pink [10]
dab = 1,4-diaminobutane H2dab·Mn2(HPO3)2(C2O4)(H2O)2 monoclinic P21/n a = 5.616, b = 15.431, c = 9.445, β = 91.72(2)°, Z = 2 818.2 [11]
ethylenediammonium manganese phosphite-oxalate [C2N2H10][Mn2II(OH2)2(HPO3)2(C2O4)] monoclinic P21/c a 7.837 b 8.755 c 10.100, β 100.605° [12]
bis(1-(3-ammoniopropyl)imidazolium) tetrakis(μ-dihydrogen phosphato)-tetrakis(μ-oxalato)-tetra-manganes H2api·Mn2(H2PO4)2(C2O4)2 triclinic P1 a=7.6108 b=9.8476 c=15.2437, α=100.023° β=102.032° γ=110.612° [13]
(C6H14N2)0.5Mn(H2PO3)(C2O4) [14]
1,4-diazabicyclo[2.2.2]octane (DABCO) [C6N2H14]2[FeIII2F2(HPO3)2(C2O4)2]·2H2O monoclinic P21/n a=12.51 b=6.372 c=33.153 β=90.532 Z=4 2643.0 1.875 colourless; chains [15]
TREN [C6N4H21]2[FeII4(HPO3)2(C2O4)5]·5H2O triclinic P1 a=8.719 b=8.827 c=15.908 α=78.617 β=84.047 γ=68.241 Z=2 1114.1 1.770 brown; network [15]
[FeIII2(OH2)2(HPO3)2(C2O4)]·H2O monoclinic P21/c a=4.875 b=17.707 c=6.984 β=106.728 Z=4 577.46 2.368 colourless [15]
ethylenediammonium [C2N2H10][FeII2(OH2)2(HPO3)2(C2O4)] monoclinic P21/c a=7.684 b=8.651 c=10.053 β=100.821 Z=4 653.6 2.317 brown [15]
BAPEN [C8N4H26][FeIII6(HPO3)8(C2O4)3]·4H2O monoclinic P21/n a=8.493 b=16.685 c=16.215 β=95.919 Z=4 2280.35 2.157 colourless [15]
homopip [C5N2H14][FeII4(HPO3)2(C2O4)3] monoclinic P21/c a=7.682 b=7.726 c=18.092 β=94.443 Z=4 1070.8 2.004 brown [15]
Piperazinediium bis(μ4-phosphito)-(μ4-oxalato)-bis(μ3-oxalato)-tetra-iron(ii) [C4N2H12][FeII4(HPO3)2(C2O4)3] monoclinic P21/c a 7.7286 b 7.587 c 17.9816 β 98.214° [16]
dab = 1,4-diaminobutane (H2dab)0.5·Co(H2PO3)(C2O4) [17]
[C4N2H12][Co4(HPO3)2(C2O4)3] monoclinic P21/c a=7.614 b=7.51 c=17.750 β=97.351 Z=2 1007.3 2.466 [18]
CN3H6·Co(H2PO3)(C2O4) [8]
Co(H2PO3)(C2O4)·(C2H8N) triclinic P1 [19]
Co(H2PO3)(C2O4)·(C2H8N) monoclinic P21/n [19]
Co2(H2PO3)2(C2O4)3(C6N2H16)2 monoclinic P21/c a=5.8605 b=13.6144 c=19.361

β=105.582

1487.9 1.733 pink [20]
Co2(H2PO3)2(C2O4)2(C6N2H16) monoclinic P21/c a=15.3007 b=8.2832 c=16.2601 β=113.487 Z=2 1890 2.010 pink; proton conductor [20]
(C4H14N2)0.5Co(HPO3)(C2O4) [14]
bis(1,4-Diazoniabicyclo[2.2.2]octane) bis(μ3-hydrogen phosphito)-dihydroxy-bis(oxalato)-di-gallium(iii) dihydrate (C6N2H14)2[Ga2(OH)2(C2O4)2(HPO3)2]·2H2O monoclinic P21/n a 12.401 b 6.283 c 33.306 β 91.197° [21]
N,N,N',N'-Tetramethylethylenediammonium bis(μ3-hydrogen phosphito)-(μ2-oxalato)-dihydroxy-di-gallium(iii) (C6N2H18)0.5[Ga(OH)(C2O4)0.5(HPO3)] triclinic P1 a 6.257 b 8.558 c 9.253, α 93.219° β 108.265° γ 106.956° [21]
bis(μ3-Hydrogen phosphito)-(μ2-oxalato)-bis(1H-imidazole)-di-gallium(iii) Ga(C2O4)0.5(C3N2H4)(HPO3) monoclinic P21/c a 8.038 b 8.709 c 11.487, β 91.85° [21]
Ga(HPO3)(C2O4)(C3N2H4)·(C3N2H5) orthorhombic Pnma a=13.288, b=6.361, c=1.5364, Z=4 [22]
[bis(1,4-dimethylpiperazinediium) tetrakis(μ2-phosphito)-tetrakis(μ2-hydrogen phosphito)-bis(μ2-oxalato)-tetra-gallium] [Ga2(HPO3)2(H2PO3)2(C2O4)](C6N2H16) monoclinic P21/c a =10.183 b=12.525 c=16.295 β=98.218° [23]
[hemikis(1,4-dimethylpiperazinediium) bis(μ3-phosphito)-(μ2-hydrogen phosphito)-(μ2-oxalato)-di-gallium] [Ga2(HPO3)2(H2PO3)(C2O4)](C6N2H16)0.5 monoclinic C 2/c a =23.462 b= 8.1170 c =16.898, β 112.873° [23]
phen = 1,10-phenanthroline Cd2(phen)2(H2PO4)(H2PO3)(C2O4) chains [17]
Cd(C10H8N2)(HPO3)(C2O4)0.5 [14]
catena-(Piperazinedi-ium bis(μ3-hydrogen phosphito)-(μ2-oxalato)-(μ2-hydrogen phosphito)-di-indium) [C4H12N2][In2(HPO3)3(C2O4)] orthorhombic Cmcm a=6.555 b=15.384 c=18.135 [24]
[C4N2H12]3[In2(HPO3)2(C2O4)4].4H2O [25]
1,4-diazabicyclo[2.2.2]octane (dabco) C6H14N2[In2(HPO3)3(C2O4)] 671.79 orthorhombic Pna21 a = 12.414, b = 7.7166, c = 18.327, Z = 4 1755.6 2.542 [26]
[C4N2H12]2[In2(HPO3)3(C2O4)2].3H2O [25]
[C4N2H12]3[In4(HPO3)6(C2O4)3] [25]
[C4N2H14][In4(H2O)(HPO3)5(C2O4)2].2H2O [25]
H[In5(HPO3)6(H2PO3)2(C2O4)2]·(C4N2H11)2·H2O triclinic P1 a =7.822 b =10.626 c =13.156, α =94.720° β =92.336° γ =110.181° [27]
1-methylpiperazine In5(HPO3)6(H1.5PO3)2(C2O4)2·(H2C5N2H12)2 triclinic P1 a 10.1574 b 10.4440 c 10.6857, α 70.006° β 76.100° γ 79.337° [28]
1-ethylpiperazine In5(HPO3)6(H1.5PO3)2(C2O4)2·(H2C6N2H14)2 triclinic P1 a 10.1904 b 10.4327 c 10.7158, α 69.373° β 77.185° γ 79.268° [28]
dbu = 1,8-diazabicyclo[5.4.0]undec-7-ene Hdbu·In2(HPO3)2(C2O4)1.5 [17]
Ba2(C2O4)(H2PO3)2 531.38 monoclinic C2/c a = 12.3829, b = 7.9124, c = 11.0858, β=114.788 (2)°, Z = 4 986.10 3.534 colourless [29]
[Pr(H2O)(C2O4)0.5(HPO3)]·H2O 300.93 triclinic P1 a=6.6764 b=7.0684 c=7.8103 α=111.141° β=95.415° γ=90.457° Z=2 2.923 [30]
[Nd(H2O)(C2O4)0.5(HPO3)]·H2O 304.26 triclinic P1 a=6.6544 b=7.0684 c=7.8103 α=111.160° β=95.307° γ=90.590° Z=2 2.985 [30]
[Sm(H2O)(C2O4)0.5(HPO3)]·H2O [30]
[Eu(H2O)(C2O4)0.5(HPO3)]·H2O 311.98 triclinic P1 a=6.5619 b=6.9442 c=7.7412 α=111.369° β=95.495° γ=90.824° Z=2 3.173 [30]
[Gd(H2O)(C2O4)0.5(HPO3)]·H2O 317.27 triclinic P1 a=6.5434 b=6.9311 c=7.7465 α=111.487° β=95.645° γ=90.833° Z=2 3.244 [30]
[Ho(H2O)(C2O4)0.5(HPO3)]·H2O 324.95 triclinic P1 a=6.4628 b=6.8519 c=7.6936 α=111.646° β=95.779° γ=91.028° Z=2 3.421 [30]
[Er(H2O)(C2O4)0.5(HPO3)]·H2O 327.28 triclinic P1 a=6.4400 b=6.8326 c=7.6747 α=111.654° β=95.757° γ=91.096° Z=2 3.487 [30]
[Tm(H2O)(C2O4)0.5(HPO3)]·H2O triclinic P1 [30]
[Yb(H2O)(C2O4)0.5(HPO3)]·H2O 333.06 triclinic P1 a=6.4075 b=6.8050 c=7.6647 α=111.753° β=95.858° γ=91.204° Z=2 3.589 [30]
[Lu(H2O)(C2O4)0.5(HPO3)]·H2O triclinic P1 [30]

References

  1. ↑ "Crystal Structure of Novel Layered Iron Arsenate-Oxalate (NH4)3K3[Fe2(HAsO4)2(C2O4)4x2H2O"]. Журнал структурной химии (4). 2016. doi:10.15372/JSC20160428. https://www.sibran.ru/upload/iblock/a18/a1833198543c2da0ef4d99482b24ae9c.pdf. 
  2. ↑ Chakrabarti, Sandip; Green, Mark A.; Natarajan, Srinivasan (March 2002). "Hydrothermal synthesis of the first iron arsenate-oxalate [C4N2H12]2[Fe4(HAsO4)6( C2O4)2], possessing open architecture". Solid State Sciences 4 (3): 405–412. doi:10.1016/S1293-2558(02)01268-2. Bibcode: 2002SSSci...4..405C. 
  3. ↑ Natarajan, Srinivasan; Manual, Sukhendu; Mahata, Partha; Rao, Vandavasi Koteswara; Ramaswamy, Padmini; Banerjee, Abhishek; Paul, Avijit Kumar; Ramya, K. V. (November 2006). "The use of hydrothermal methods in the synthesis of novel open-framework materials" (in en). Journal of Chemical Sciences 118 (6): 525–536. doi:10.1007/BF02703950. ISSN 0253-4134. 
  4. ↑ 4.0 4.1 簡塏旻 (2016-01-01). 新穎有機-無機複合鋁/鎵亞磷酸鹽之 合成、結構與性質研究. https://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0016-0901201710354607. 
  5. ↑ 5.0 5.1 Auguste, S.; Alonzo, V.; Bataille, T.; Le Pollès, L.; Cañón-Mancisidor, W.; Venegas-Yazigi, D.; Le Fur, E. (March 2014). "Lithium vanadyl oxalatophosphite: Influence of the water content on the crystal structures and the dehydration scheme" (in en). Journal of Solid State Chemistry 211: 212–218. doi:10.1016/j.jssc.2013.12.019. Bibcode: 2014JSSCh.211..212A. https://linkinghub.elsevier.com/retrieve/pii/S0022459613006063. 
  6. ↑ 6.0 6.1 6.2 Hameed, A. Shahul; Reddy, M. V.; Sarkar, Nirjhar; Chowdari, B. V. R.; Vittal, Jagadese J. (2015). "Synthesis and electrochemical investigation of novel phosphite based layered cathodes for Li-ion batteries" (in en). RSC Advances 5 (74): 60630–60637. doi:10.1039/C5RA12410G. ISSN 2046-2069. Bibcode: 2015RSCAd...560630H. http://xlink.rsc.org/?DOI=C5RA12410G. 
  7. ↑ Kouvatas, C.; Alonzo, V.; Bataille, T.; Le Pollès, L.; Roiland, C.; Louarn, G.; Le Fur, E. (September 2017). "Synthesis, crystal structure of the ammonium vanadyl oxalatophosphite and its controlled conversion into catalytic vanadyl phosphates" (in en). Journal of Solid State Chemistry 253: 73–77. doi:10.1016/j.jssc.2017.05.026. Bibcode: 2017JSSCh.253...73K. https://linkinghub.elsevier.com/retrieve/pii/S0022459617301950. 
  8. ↑ 8.0 8.1 Orive, Joseba; Sivasamy, Ramesh; Fernández de Luis, Roberto; Mosquera, Edgar; Arriortua, María I. (2018). "K 2 MnII2(H 2 O) 2 C 2 O 4 (HPO 3 ) 2 : a new 2D manganese( ii ) oxalatophosphite with double-layered honeycomb sheets stabilized by potassium ions" (in en). CrystEngComm 20 (3): 301–311. doi:10.1039/C7CE01637A. ISSN 1466-8033. http://xlink.rsc.org/?DOI=C7CE01637A. 
  9. ↑ Liu, Lin; Luo, Daibing; Li, Defu; Lin, Zhien (2014). "Solvent-free synthesis of new metal phosphite–oxalates with open-framework structures" (in en). Dalton Trans. 43 (21): 7695–7698. doi:10.1039/C4DT00202D. ISSN 1477-9226. PMID 24718917. http://xlink.rsc.org/?DOI=C4DT00202D. 
  10. ↑ Mandal, Sukhendu; Green, Mark A.; Pati, Swapan K.; Natarajan, Srinivasan (2007). "Synthesis, structure and magnetic properties of an inorganic–organic hybrid compound" (in en). J. Mater. Chem. 17 (10): 980–985. doi:10.1039/B614186B. ISSN 0959-9428. http://xlink.rsc.org/?DOI=B614186B. 
  11. ↑ Lin, Zhien; Nayek, Hari Pada; Dehnen, Stefanie (November 2009). "Flux synthesis of three-dimensional open-framework zinc phosphite and manganese phosphite-oxalate with 12-ring channels" (in en). Microporous and Mesoporous Materials 126 (1–2): 95–100. doi:10.1016/j.micromeso.2009.05.025. https://linkinghub.elsevier.com/retrieve/pii/S1387181109002686. 
  12. ↑ Ramaswamy, Padmini; Mandal, Sukhendu; Natarajan, Srinivasan (September 2009). "Synthesis, structure and magnetic behavior of a new three-dimensional Manganese phosphite-oxalate: [C2N2H10[Mn2II(OH2)2(HPO3)2(C2O4)]"] (in en). Journal of Solid State Chemistry 182 (9): 2491–2496. doi:10.1016/j.jssc.2009.06.040. Bibcode: 2009JSSCh.182.2491R. https://linkinghub.elsevier.com/retrieve/pii/S0022459609002990. 
  13. ↑ Cao, Yue; Zhou, Xiaoying; Luan, Lindong; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (February 2021). "Organically templated metal phosphate-oxalates: Solvent-free synthesis, crystal structure, and proton conduction" (in en). Inorganic Chemistry Communications 124: 108403. doi:10.1016/j.inoche.2020.108403. https://linkinghub.elsevier.com/retrieve/pii/S138770032030993X. 
  14. ↑ 14.0 14.1 14.2 "金属亚磷酸-草酸盐的无溶剂合成--《中国化学会第29届学术年会摘要集——第05分会：无机化学》2014年". https://cpfd.cnki.com.cn/Article/CPFDTOTAL-ZGHY201408008350.htm. 
  15. ↑ 15.0 15.1 15.2 15.3 15.4 15.5 Mandal, Sukhendu; Natarajan, Srinivasan (2007-01-12). "Inorganic–Organic Hybrid Structures: Open-Framework Iron Phosphite–Oxalates of Varying Dimensionality" (in en). Chemistry - A European Journal 13 (3): 968–977. doi:10.1002/chem.200601026. PMID 17066396. https://onlinelibrary.wiley.com/doi/10.1002/chem.200601026. 
  16. ↑ Mandal, Sukhendu; Pati, Swapan K.; Green, Mark A.; Natarajan, Srinivasan (May 2005). "Inorganic−Organic Hybrid Compounds: Synthesis, Structure, and Magnetic Properties of the First Organically Templated Iron Oxalate−Phosphite, [C 4 N 2 H 12 [Fe II 4 (HPO 3 ) 2 (C 2 O 4 ) 3 ], Possessing Infinite Fe−O−Fe Chains"] (in en). Chemistry of Materials 17 (11): 2912–2917. doi:10.1021/cm0501968. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm0501968. 
  17. ↑ 17.0 17.1 17.2 Li, Jing; Li, Ting; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (September 2018). "Solvent-free synthesis of inorganic-organic hybrid solids with chainlike, layered, and open-framework structures" (in en). Inorganic Chemistry Communications 95: 8–11. doi:10.1016/j.inoche.2018.06.022. https://linkinghub.elsevier.com/retrieve/pii/S1387700318304623. 
  18. ↑ Mandal, Sukhendu; Natarajan, Srinivasan (July 2005). "Inorganic–organic hybrid structure: Synthesis, structure and magnetic properties of a cobalt phosphite–oxalate, [C4N2H12[Co4(HPO3)2(C2O4)3]"] (in en). Journal of Solid State Chemistry 178 (7): 2376–2382. doi:10.1016/j.jssc.2005.05.020. Bibcode: 2005JSSCh.178.2376M. https://linkinghub.elsevier.com/retrieve/pii/S0022459605002355. 
  19. ↑ 19.0 19.1 Xiu, Zhijia; Jiang, Yansong; Wang, Honghao; Liu, Lu; Ma, Yike; Li, Na; Huang, Liangliang; Bi, Yanfeng (2019-08-15). "Solvothermal Synthesis and Characterizations of Two Isomerism Cobalt Phosphite-Oxalates with Varying Dimensions Using the Same Template from in situ Reaction: Solvothermal Synthesis and Characterizations of Two Isomerism Cobalt Phosphite-Oxalates with Varying Dimensions Using the Same Template from in situ R" (in en). Zeitschrift für anorganische und allgemeine Chemie 645 (15): 1004–1009. doi:10.1002/zaac.201900024. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201900024. 
  20. ↑ 20.0 20.1 Gao, Fan; Huang, Liangliang; Xiu, Zhijia; Yin, Yanzhen; Ma, Yike; Bi, Yanfeng; Zheng, Zhiping (2018). "Solvent-free synthesis and room temperature proton conductivity of new cobalt phosphite–oxalates" (in en). CrystEngComm 20 (37): 5544–5550. doi:10.1039/C8CE01198B. ISSN 1466-8033. http://xlink.rsc.org/?DOI=C8CE01198B. 
  21. ↑ 21.0 21.1 21.2 Zhou, Guangpeng; Yang, Yulin; Fan, Ruiqing; Liu, Xinrong; Wang, Qing; Wang, Fuping (May 2010). "The first organically templated gallium phosphite–oxalates: Synthesis, structures, and characterizationseer" (in en). Solid State Sciences 12 (5): 873–881. doi:10.1016/j.solidstatesciences.2010.02.002. Bibcode: 2010SSSci..12..873Z. https://linkinghub.elsevier.com/retrieve/pii/S1293255810000543. 
  22. ↑ "具有三维超分子结构的亚磷酸-草酸镓的溶剂热合成及结构表征（英文）--《人工晶体学报》2014年09期". https://www.cnki.com.cn/Article/CJFDTotal-RGJT201409050.htm. 
  23. ↑ 23.0 23.1 Li, Caixia; Huang, Liangliang; Zhou, Mingdong; Xia, Jing; Ma, Hongwei; Zang, Shuliang; Wang, Li (December 2013). "Synthesis, structure and characterization of two new open-framework gallium phosphite-oxalates of varying dimensionality" (in en). Journal of Solid State Chemistry 208: 86–92. doi:10.1016/j.jssc.2013.10.003. Bibcode: 2013JSSCh.208...86L. https://linkinghub.elsevier.com/retrieve/pii/S002245961300460X. 
  24. ↑ Li, Huiduan; Zhang, Lirong; Huo, Qisheng; Liu, Yunling (January 2013). "Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization" (in en). Journal of Solid State Chemistry 197: 75–80. doi:10.1016/j.jssc.2012.09.017. Bibcode: 2013JSSCh.197...75L. https://linkinghub.elsevier.com/retrieve/pii/S0022459612006123. 
  25. ↑ 25.0 25.1 25.2 25.3 Ramaswamy, Padmini; Hegde, Nayana N.; Prabhu, Ramanath; Vidya, V. M.; Datta, Ayan; Natarajan, Srinivasan (2009-12-21). "Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium" (in en). Inorganic Chemistry 48 (24): 11697–11711. doi:10.1021/ic901744m. ISSN 0020-1669. PMID 19911816. https://pubs.acs.org/doi/10.1021/ic901744m. 
  26. ↑ Li, Huiduan; Zhang, Lirong; Liu, Li; Jiang, Tianchan; Yu, Yang; Li, Guanghua; Huo, Qisheng; Liu, Yunling (October 2009). "Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4) compound with intersecting channels"] (in en). Inorganic Chemistry Communications 12 (10): 1020–1023. doi:10.1016/j.inoche.2009.08.011. https://linkinghub.elsevier.com/retrieve/pii/S1387700309003712. 
  27. ↑ Zuo, Mengmeng; Zhou, Mingdong; Hu, Dianwen; Gao, Fan; Dong, Sijie; Huang, Liangliang (May 2016). "A novel 3D framework indium phosphite-oxalate based on a pcu-type topology" (in en). Journal of Solid State Chemistry 237: 219–224. doi:10.1016/j.jssc.2016.02.019. Bibcode: 2016JSSCh.237..219Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459616300457. 
  28. ↑ 28.0 28.1 Jiang, Yansong; Song, Jianshu; Xiu, Zhijia; Huang, Liangliang; Gao, Fan; Jiao, Shufei; Bi, Yanfeng (November 2019). "Solvent-free syntheses of two pcu topological indium phosphite-oxalates with a novel butterfly motif and proton conductivity" (in en). Microporous and Mesoporous Materials 289: 109643. doi:10.1016/j.micromeso.2019.109643. 
  29. ↑ Iveson, Samuel J.; Johnston, Chloe B.; Harrison, William T.A. (2011-06-08). "Barium Oxalates Combined with Oxo-Anions and Organic Cations: Syntheses and Structures of Ba2(C2O4)(H2PO3)2 and C2H10N2·Ba(H2O)2(HC2O4)4" (in en). Crystals 1 (2): 59–68. doi:10.3390/cryst1020059. ISSN 2073-4352. 
  30. ↑ 30.0 30.1 30.2 30.3 30.4 30.5 30.6 30.7 30.8 30.9 Wang, Chih-Min; Wu, Yi-Ying; Chang, Yu-Wei; Lii, Kwang-Hwa (2008-05-01). "Luminescent Lanthanide Oxalatophosphites with a 3D Framework Structure: [Ln(H 2 O)(C 2 O 4 ) 0.5 (HPO 3 )·H 2 O (Ln = Pr, Nd, and Sm−Lu)"] (in en). Chemistry of Materials 20 (9): 2857–2859. doi:10.1021/cm703703n. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm703703n. 



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