Chemistry:Strontium oxalate

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Strontium oxalate
Strontium oxalate.svg
Names
IUPAC name
Strontium oxalate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 212-415-6
UNII
Properties
SrC
2
O
4
Molar mass 175.64 g·mol−1
Appearance White powder[1]
Density 2.08 g/cm3
Boiling point Decomposes above 200 °C (392 °F; 473 K)
Insoluble in water
Hazards
Main hazards Skin and eye irritant. Inhaling the compound irritates mucous membrane in the lungs.
Safety data sheet [1]
GHS pictograms GHS07: Harmful
GHS Signal word Warning
HH302Script error: No such module "Preview warning".Category:GHS errors, HH312Script error: No such module "Preview warning".Category:GHS errors
PP264Script error: No such module "Preview warning".Category:GHS errors, PP270Script error: No such module "Preview warning".Category:GHS errors, PP280Script error: No such module "Preview warning".Category:GHS errors, PP301+P317Script error: No such module "Preview warning".Category:GHS errors, PP302+P352Script error: No such module "Preview warning".Category:GHS errors, PP317Script error: No such module "Preview warning".Category:GHS errors, PP321Script error: No such module "Preview warning".Category:GHS errors, PP330Script error: No such module "Preview warning".Category:GHS errors, PP362+P364Script error: No such module "Preview warning".Category:GHS errors, PP501Script error: No such module "Preview warning".Category:GHS errors
NFPA 704 (fire diamond)
Flammability code 0: Will not burn. E.g. waterHealth code 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineReactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no codeNFPA 704 four-colored diamond
0
1
1
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Strontium oxalate is a compound with the chemical formula SrC
2
O
4
. Strontium oxalate can exist either in a hydrated form (SrC
2
O
4
 · nH
2
O
) or as the acidic salt of strontium oxalate (SrC
2
O
4
 · mH
2
C
2
O
4
 · nH
2
O
).[2]

Use in pyrotechnics

With the addition of heat, strontium oxalate will decompose based on the following reaction:[3]

SrC
2
O
4
→ SrO + CO
2
+ CO

Strontium oxalate is a good agent for use in pyrotechnics since it decomposes readily with the addition of heat. When it decomposes into strontium oxide, it produces a red flame color. Since this reaction produces carbon monoxide, which can undergo a further reduction with magnesium oxide, strontium oxalate is an excellent red flame color producing agent in the presence of magnesium. If it is not in the presence of magnesium, strontium carbonate has been found to be a better option to produce an even greater effect.

References

  1. https://pubchem.ncbi.nlm.nih.gov/compound/Strontium-oxalate
  2. Knaepen, E. "Preparation and Thermal Decomposition of Various Forms of Strontium Oxalate". Thermochimica Acta 284.1 (1996): 213-27.
  3. Kosanke, K. "Chemical Components of Fireworks Compositions". Pyrotechnic Chemistry. Whitewater, CO: Journal of Pyrotechnics, 2004. 1-11.