Chemistry:Thiepane
From HandWiki
| |||
| Names | |||
|---|---|---|---|
| Preferred IUPAC name
Thiepane | |||
| Identifiers | |||
3D model (JSmol)
|
|||
| ChemSpider | |||
| EC Number |
| ||
PubChem CID
|
|||
| UNII | |||
| |||
| |||
| Properties | |||
| C6H12S | |||
| Molar mass | 116.22 g·mol−1 | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
 verify (what is   ?)
| |||
| Infobox references | |||
Tracking categories (test):
Thiepane is the organosulfur compound with the formula (CH2)6S. Thiepanes are seven-membered ring heterocycles that contains sulfide.[1] The parent thiepane has seldom been studied.
A variety of derivatives are known. Hexathiathiepane (CAS RN 17233-71-5, m.p. 90 °C) is CH2S6.[2] A naturally occurring derivative is lenthionine, 1,4-(CH2)2S5.
Thiepane (hexathiophane) itself may be a product of spontaneous coal fires in post-mining waste heaps.[3]
References
- ↑ Yamamoto, Kagetoshi; Yamazaki, Shoko (1996). "Thiepanes and Thiepines". in Newkome, George R. Comprehensive Heterocyclic Chemistry II. 9. pp. 67–111. doi:10.1016/B978-008096518-5.00211-2. ISBN 9780080965185.
- ↑ Fehér, F.; Lex, J. (1976). "Kristall- und Molecülstrukturen von Hexathiepan (S6CH2), Pentathiepan (S5CH2) und Dibenzylpentathian (S5C(CH2C6H5)2)". Z. Anorg. Allg. Chem. 423: 103–111. doi:10.1002/zaac.19764230203.
- ↑ Kruszewski, Ł.; Fabiańska, M.J.; Ciesielczuk, J.; Segit, T.; Orłowski, R.; Motyliński, R.; Kusy, D.; Moszumańska, I. (2018). "First multi-tool exploration of a gas-condensate-pyrolysate system from the environment of burning coal mine heaps: An in situ FTIR and laboratory GC an PXRD study based on Upper Silesian materials". STOTEN 640-641: 1044–1071. doi:10.1016/j.scitotenv.2018.05.319. PMID 30021271. Bibcode: 2018ScTEn.640.1044K.
 |  |
