Chemistry:Zadovite

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Zadovite
General
CategoryPhosphate minerals
Formula
(repeating unit)
BaCa6[(SiO4)(PO4)](PO4)2F
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2m)
Space groupR3m
Unit cella = 7.0966, c = 25.7284 [Å]; Z = 3
Identification
ColorColorless
FractureIrregular/uneven
|re|er}}Vitreous
StreakWhite
DiaphaneityTransparent
References[1]

Zadovite is an extremely rare mineral with formula BaCa6[(SiO4)(PO4)](PO4)2F. Together with its vanadium-analogue, aradite, zadovite occur in paralavas (type of pyrometamorphic rocks). Both minerals have structures similar to nabimusaite, and these three minerals occur in the Hatrurim Formation of Israel. Structure of all three minerals is related to that of hatrurite. Minerals combining barium, phosphorus and silicon together are scarce.[3][4][1]

References

  1. 1.0 1.1 "Aradite: Aradite mineral information and data". http://www.mindat.org/min-43920.html. 
  2. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  3. Galuskin, E.V., Gfeller, F., Galuskina, I.O., Pakhomova, A., Armbruster, T., Vapnik, Y., Włodyka, R., Dzierżanowski, P., and Murashko, M., 2015. New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part II. Zadovite, BaCa6[(SiO4)(PO4)](PO4)2F and aradite, BaCa6[(SiO4)(VO4)](VO4)2F, from paralavas of the Hatrurim Basin, Negev Desert, Israel. Mineralogical Magazine 79(5), 1073-1087
  4. Galuskin, E.V., Gfeller, F., Armbruster, T., Galuskina, I.O., Vapnik, Y., Murashko, M., Włodyka, R., and Dzierżanowski, P., 2015. New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa12(SiO4)4(SO4)2O2F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine 79(5), 1061-1072