Chemistry:Walfordite

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Short description: Tellurite mineral
Walfordite
Walfordite - Tambo Mine, Elqui Province, Coquimbo Region, Chile2.jpg
Walfordite from Tambo Mine, Elqui Province, Chile
General
CategoryTellurite minerals
Formula
(repeating unit)
Fe3+,Te6+Te4+3O8
Strunz classification4.JK.05
Crystal systemIsometric
Space groupI2, Ia3
Unit cella = 11.011 Å ; Z = 8
Identification
ColourOrange
Crystal habitMicroscopic cubic crystals
CleavageNone
TenacityBrittle
|re|er}}Adamantine
StreakOrange-yellow
DiaphaneityOpaque
Specific gravity5.841 (calculated)
Optical propertiesIsotropic
Refractive indexn = 2.23
References[1][2][3]

Walfordite is a very rare tellurite mineral that was discovered in Chile in 1999.[5] The mineral is described as orange with orange-yellow streak, and is determined to have a chemical formula of Fe3+,Te6+Te4+3O8[1] with minor titanium and magnesium substitution resulting in an approximate empirical formula of (Fe3+,Te6+,Ti4+,Mg)(Te4+)3O8.[5]

Occurrence

The only reported occurrence[2] is in the Wendy open pit, El Indio-Tambo mining district of the Coquimbo Region, northern Chile where it occurs in oxidized breccia associated with a tellurium-bearing gold deposit. Associated minerals include: alunite, rodalquilarite, native gold, emmonsite, jarosite and pyrite. The mineral was named for mine geologist Phillip Walford (1945— ) who first noted the mineral.[1]

See also

  • El Indio Gold Belt. Tambo is adjacent to the El Indio mine. Both are now closed.

References

  1. 1.0 1.1 1.2 Walfordite in the Handbook of Mineralogy
  2. 2.0 2.1 Walfordite on Mindat.org
  3. Walfordite data on Webmineral
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. 5.0 5.1 Back, Malcolm E.; Grice, Joel D.; Gault, Robert A.; Criddle, Alan J.; Mandarino, Joseph A. (1999). "Walfordite, a New Tellurite Species from the Wendy Open Pit, El Indio - Tambo Mining Property, Chile". The Canadian Mineralogist 37: 1261–1268. http://rruff.geo.arizona.edu/doclib/cm/vol37/CM37_1261.pdf.