Chemistry:Stellerite

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Short description: Zeolite mineral
Stellerite
Stellerite - Takat, Imilchil, Midelt Province, Drâa-Tafilalet Region, Morocco.jpg
General
CategoryZeolite mineral
Formula
(repeating unit)
Ca(Al2Si7O18)•7H20
Strunz classification9.GE.15
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupFmmm
Identification
ColorColorless to white, pink, orange
Crystal habitSpherical, Stellate, Tabular
CleavagePerfect on {010}
FractureUneven
Mohs scale hardness4.5
|re|er}}Pearly
Streakwhite
DiaphaneityTransparent to translucent
Specific gravityapproximately 2.2
Density2.13 g/cm3
Optical propertiesBiaxial (-), a=1.4848, b=1.4864-1.4964, g=1.4979
Birefringenceδ = 0.013
References[1]

Stellerite is a rare mineral discovered by and named after Georg Wilhelm Steller, a German explorer and zoologist.[1] The mineral has a general formula of Ca[Al2Si7O18]·7H2O.[3] Like most rare minerals, there are few commercial uses for stellerite. Mineral collectors are lucky to find it in good enough crystal form. Zeolites, including stellerite, have been studied using a dehydration process to gauge the potential use of their phases as molecular sieves, sorbents, and catalysts.[4]

Crystal habit

Stellerite is part of the orthorhombic crystal system which means it has three axes of unequal length that intersect at 90° angles. Its crystal class is rhombic-dipyramidal which means it has three perpendicular two-fold rotational axes with perpendicular mirror planes.[5] Stilbite, another zeolite, is very similar to stellerite in both chemical composition and physical appearance. Stellerite is more commonly found in rounded radiating clusters or as single crystals and appears more transparent than stilbite does.[5]

Optical properties

Stellerite is an anisotropic mineral, meaning that it has different properties in different directions-such as indices of refraction-when light passes through it. A refractive index (n) measures the speed of light in a substance—or in the case of mineralogy—in a mineral. It is expressed as a ratio of the speed of light in vacuum to that in a mineral.[6] Stellerite has three indices of refraction because it is a biaxial mineral.

References

  1. 1.0 1.1 Pabst, Adolf (March 1939). "The relation of stellerite and epidesmine to stilbite". Mineralogical Magazine and Journal of the Mineralogical Society 25 (164): 271–276. doi:10.1180/minmag.1939.025.164.06. Bibcode1939MinM...25..271P. 
  2. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  3. "Stellerite". PubChem. National Library of Medicine. https://pubchem.ncbi.nlm.nih.gov/compound/Stellerite#section=Synonyms. 
  4. Arletti, R.; Mazzucato, E.; Vezzalini, G. (1 April 2006). "Influence of dehydration kinetics on T-O-T bridge breaking in zeolites with framework type STI: The case of stellerite". American Mineralogist 91 (4): 628–634. doi:10.2138/am.2006.1966. Bibcode2006AmMin..91..628A. 
  5. 5.0 5.1 Miller, S. A.; Taylor, J. C. (1 January 1985). "Neutron single crystal diffraction study of an Australian Stellerite". Zeolites 5 (1): 7–10. doi:10.1016/0144-2449(85)90003-X. 
  6. "Index of Refraction." Encyclopedia Americana. Grolier Online http://ea.grolier.com/article?id=0213810-00 (accessed May 2, 2010)