Chemistry:Copper(II) borate

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Copper(II) borate
Copper(II) borate.JPG
Names
IUPAC name
Copper(II) borate
Other names
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 254-401-2
UNII
Properties
B2Cu3O6
Molar mass 308.25 g·mol−1
Appearance Dark green solid[1]
Density 4.54[1]
Insoluble
Structure
Triclinic[2]
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H312, H332, H302, H320, H315
P280, P301+312, P302+352, P304+340, P305+351+338, P332+313
NFPA 704 (fire diamond)
Flammability code 0: Will not burn. E.g. waterHealth code 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideReactivity (yellow): no hazard codeSpecial hazards (white): no codeNFPA 704 four-colored diamond
0
0
Related compounds
Other cations
Sodium orthoborate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Copper(II) borate is an inorganic compound with the formula Cu3(B O3)2. It has previously studied due to its photocatalytic properties.[2]

Preparation

Copper(II) borate can be prepared by heating a stoichiometric mixture of copper(II) oxide and diboron trioxide to 900 °C.[2][1]

[math]\ce{ 3CuO + B2O3 -> Cu3(BO3)2 }[/math]

See also

References

  1. 1.0 1.1 1.2 Liu, Jikai; Wen, Shuhao; Zou, Xiaoxin; Zuo, Fan; Beran, Gregory J. O.; Feng, Pingyun (2013). "Visible-light-responsive copper( ii ) borate photocatalysts with intrinsic midgap states for water splitting" (in en). J. Mater. Chem. A 1 (5): 1553–1556. doi:10.1039/C2TA00522K. ISSN 2050-7488. http://xlink.rsc.org/?DOI=C2TA00522K. 
  2. 2.0 2.1 2.2 Fukaya, Atsuko; Watanabe, Isao; Nagamine, Kanetada (October 2001). "Long-Range Order in a Copper Borate Cu 3 B 2 O 6" (in en). Journal of the Physical Society of Japan 70 (10): 2868–2871. doi:10.1143/JPSJ.70.2868. ISSN 0031-9015. https://journals.jps.jp/doi/10.1143/JPSJ.70.2868.