Chemistry:Copper(II) oxide
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| Names | |
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| IUPAC name
Copper(II) oxide
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| Other names
Cupric oxide
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| Identifiers | |
3D model (JSmol)
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| ChEBI | |
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PubChem CID
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| Properties | |
| CuO | |
| Molar mass | 79.545 g/mol |
| Appearance | black to brown powder |
| Density | 6.315 g/cm3 |
| Melting point | 1,326 °C (2,419 °F; 1,599 K) |
| Boiling point | 2,000 °C (3,630 °F; 2,270 K) |
| insoluble | |
| Solubility | soluble in ammonium chloride, potassium cyanide insoluble in alcohol, ammonium carbonate |
| Band gap | 1.2 eV |
| +238.9·10−6 cm3/mol | |
Refractive index (nD)
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2.63 |
| Structure | |
| monoclinic, mS8[1] | |
| C2/c, #15 | |
a = 4.6837, b = 3.4226, c = 5.1288 α = 90°, β = 99.54°, γ = 90°
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| Thermochemistry | |
Std molar
entropy (S |
43 J·mol−1·K−1 |
Std enthalpy of
formation (ΔfH⦵298) |
−156 kJ·mol−1 |
| Hazards | |
| Safety data sheet | Fisher Scientific |
| GHS pictograms | 
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| GHS Signal word | Warning |
| H410 | |
| P273, P391, P501 | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| NIOSH (US health exposure limits): | |
PEL (Permissible)
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TWA 1 mg/m3 (as Cu)[2] |
REL (Recommended)
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TWA 1 mg/m3 (as Cu)[2] |
IDLH (Immediate danger)
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TWA 100 mg/m3 (as Cu)[2] |
| Related compounds | |
Other anions
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Copper(II) sulfide |
Other cations
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Nickel(II) oxide Zinc oxide |
Related compounds
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Copper(I) oxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
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| Infobox references | |
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.[3]
Production
It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO.
It can be formed by heating copper in air at around 300–800 °C:
- 2 Cu + O2 → 2 CuO
For laboratory uses, pure copper(II) oxide is better prepared by heating copper(II) nitrate, copper(II) hydroxide, or basic copper(II) carbonate:[4]
- 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) + O2(g) (180°C)
- Cu2(OH)2CO3(s) → 2 CuO(s) + CO2(g) + H2O(g)
- Cu(OH)2(s) → CuO(s) + H2O(g) [5]
Reactions
Copper(II) oxide dissolves in mineral acids such as hydrochloric acid, sulfuric acid or nitric acid to give the corresponding copper(II) salts:[4]
- CuO + 2 HNO3 → Cu(NO3)2 + H2O
- CuO + 2 HCl → CuCl2 + H2O
- CuO + H2SO4 → CuSO4 + H2O
In presense of water It reacts with concentrated alkali to form the corresponding cuprate salts:
- 2 MOH + CuO + H2O → M2[Cu(OH)4]
- 2 NaOH + CuO + H2O → Na2[Cu(OH)4]
It can also be reduced to copper metal using hydrogen, carbon monoxide, or carbon:
- CuO + H2 → Cu + H2O
- CuO + CO → Cu + CO2
- 2 CuO + C → 2Cu + CO2
When cupric oxide is substituted for iron oxide in thermite the resulting mixture is a low explosive, not an incendiary.
Structure and physical properties
Copper(II) oxide belongs to the monoclinic crystal system. The copper atom is coordinated by 4 oxygen atoms in an approximately square planar configuration.[1]
The work function of bulk CuO is 5.3 eV[6]
Copper(II) oxide in a vial
Uses
As a significant product of copper mining, copper(II) oxide is the starting point for the production of other copper salts. For example, many wood preservatives are produced from copper oxide.[3]
Cupric oxide is used as a pigment in ceramics to produce blue, red, and green, and sometimes gray, pink, or black glazes.
It is incorrectly used as a dietary supplement in animal feed.[7] Due to low bioactivity, negligible copper is absorbed.[8]
It is used when welding with copper alloys.[9]
A copper oxide electrode formed part of the early battery type known as the Edison–Lalande cell. Copper oxide was also used in a lithium battery type (IEC 60086 code "G").
Pyrotechnics and fireworks
Used as moderate blue coloring agent in blue flame compositions with additional chlorine donors and oxidizers such as chlorates and perchlorates. Providing oxygen it can be used as flash powder oxidizer with metal fuels such as magnesium, aluminium, or magnalium powder. Sometimes it is used in strobe effects and thermite compositions as crackling stars effect.
Similar compounds
An example of natural copper(I,II) oxide is the mineral paramelaconite, Cu+2Cu2+2O3.[10][11]
See also
References
- ↑ 1.0 1.1 The effect of hydrostatic pressure on the ambient temperature structure of CuO, Forsyth J.B., Hull S., J. Phys.: Condens. Matter 3 (1991) 5257–5261, doi:10.1088/0953-8984/3/28/001. Crystallographic point group: 2/m or C2h. Space group: C2/c. Lattice parameters: a = 4.6837(5), b = 3.4226(5), c = 5.1288(6), α = 90°, β = 99.54(1)°, γ = 90°.
- ↑ 2.0 2.1 2.2 NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH). https://www.cdc.gov/niosh/npg/npgd0150.html.
- ↑ 3.0 3.1 Richardson, H. Wayne (2002). "Ullmann's Encyclopedia of Industrial Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a07_567.
- ↑ 4.0 4.1 O. Glemser and H. Sauer (1963). "Copper, Silver, Gold". in G. Brauer. Handbook of Preparative Inorganic Chemistry, 2nd Ed.. 1. NY, NY: Academic Press.
- ↑ Cudennec, Yannick; Lecerf, André (November 2003). "The transformation of Cu(OH)2 into CuO, revisited". Solid State Sciences 5 (11–12): 1471–1474. doi:10.1016/j.solidstatesciences.2003.09.009. Bibcode: 2003SSSci...5.1471C. https://hal.archives-ouvertes.fr/hal-02503180/file/publi.pdf.
- ↑ F. P. Koffyberg and F. A. Benko (1982). "A photoelectrochemical determination of the position of the conduction and valence band edges of p-type CuO". J. Appl. Phys. 53 (2): 1173. doi:10.1063/1.330567. Bibcode: 1982JAP....53.1173K.
- ↑ "Uses of Copper Compounds: Other Copper Compounds". Copper Development Association. 2007. http://www.copper.org/applications/compounds/other_compounds.html.
- ↑ Cupric Oxide Should Not Be Used As a Copper Supplement for Either Animals or Humans, Baker, D. H., J. Nutr. 129, 12 (1999) 2278-2279
- ↑ "Cupric Oxide Data Sheet". Hummel Croton Inc.. 2006-04-21. http://www.axxousa.com/data/cuox_d.html.
- ↑ "Paramelaconite". https://www.mindat.org/min-3098.html.
- ↑ "List of Minerals". 21 March 2011. https://www.ima-mineralogy.org/Minlist.htm.
External links
- National Pollutant Inventory - Copper and compounds fact sheet
- Copper oxides project page
- CDC - NIOSH Pocket Guide to Chemical Hazards
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