Chemistry:Davis reagent
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Revision as of 08:22, 6 May 2022 by imported>Importwiki (fixing)
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| IUPAC name
2-(Benzenesulfonyl)-3-phenyloxaziridine
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Other names
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C13H11NO3S | |
| Molar mass | 261.30 g·mol−1 |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Davis reagent (3-phenyl-2-(phenylsulfonyl)-1,2-oxaziridine or 2-(benzenesulfonyl)-3-phenyloxaziridine) is a reagent used for oxidation in the Davis oxidation reaction,[1] as well as oxidation of thiols to sulfones.[2] It is named for Franklin A. Davis.
References
- ↑ Davis, Franklin A.; Vishwakarma, Lal C.; Billmers, Joanne G.; Finn, John (1 August 1984). "Synthesis of α-hydroxycarbonyl compounds (acyloins): direct oxidation of enolates using 2-sulfonyloxaziridines". The Journal of Organic Chemistry 49 (17): 3241–3243. doi:10.1021/jo00191a048.
- ↑ Sandrinelli, Franck; Perrio, Stéphane; Beslin, Pierre (13 September 1999). "A New Reaction of 2-(Phenylsulfonyl)-3-phenyloxaziridine (Davis Reagent): Oxidation of Thiolates to Sulfinates. Application to the Synthesis of Sulfones". Organic Letters 1 (8): 1177–1180. doi:10.1021/ol990170k.
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