Chemistry:1,1'-Ferrocenetrisulfide
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| Other names
1,1'-trithiaferrocenophane
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C10H8FeS3 | |
| Molar mass | 280.20 g·mol−1 |
| Appearance | yellow solid |
| Density | 1.887 g/cm3[1] |
| Melting point | 149.5–150.5 °C (301.1–302.9 °F; 422.6–423.6 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
1,1'-Ferrocenetrisulfide is the organoiron compound with the formula Fe(C
5H
4S)
2S. A yellow solid, it is the simplest polysulfide derivative of ferrocene. It can be synthesized by treatment of dilithioferrocene with elemental sulfur.[2] Using proton NMR spectroscopy, the relatively slow conformational flexing of the trisulfide ring can be established.
References
- ↑ Davis, Betty R.; Bernal, Ivan (1972). "Structure of a novel fluxional molecule: 1,2,3-trithia-[3]-ferrocenophane". Journal of Crystal and Molecular Structure 2 (3): 107–114. doi:10.1007/BF01464791.
- ↑ Bishop, J.J.; Davison, A.; Katcher, M.L.; Lichtenberg, D.W.; Merrill, R.E.; Smart, J.C. (1971). "Symmetrically disubstituted ferrocenes". Journal of Organometallic Chemistry 27 (2): 241–249. doi:10.1016/S0022-328X(00)80571-9.
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