Chemistry:1,2-Dithiole
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In organosulfur chemistry, 1,2-dithioles are a type of heterocycles. The parent of this class of compounds is 1,2-dithiacyclopentene. The anticancer drug oltipraz is a dithiole.[1] Trithiapentalene is an example of theoretical interest.
The drug oltipraz features a 1,2-dithiole ring.
Many 1,2-dithioles are 1,2-dithiol-3-thiones.[2][3]
The parent 1,2-dithiole has been characterized as its diruthenium complex.[4]
See also
References
- ↑ Ogurtsov, Vladimir A; Rakitin, Oleg A (2012). "Reactivity of 1,2-dithioles". Russian Chemical Reviews 81 (7): 638. doi:10.1070/RC2012v081n07ABEH004231. Bibcode: 2012RuCRv..81..638O.
- ↑ Rašović, Aleksandar (2022). "1,2-Dithioles". Comprehensive Heterocyclic Chemistry IV. pp. 766–833. doi:10.1016/B978-0-12-818655-8.00137-2. ISBN 978-0-12-818656-5.
- ↑ Rolf Huisgen; J. Rapp (1997). "1,3-Dipolar Cycloadditions. 98. The Chemistry of Thiocarbonyl S-Sulfides". Tetrahedron 53 (3): 942. doi:10.1016/S0040-4020(96)01068-X. "The literature on 1,2-dithioles is mainly concentrated on 1,2-dithiolium cations and l,2-dithiole-3-thiones.".
- ↑ Hatemata, Shiho; Sugiyama, Hiroyasu; Sasaki, Saori; Matsumoto, Kazuko (2002). "Elimination of HX (X = Cl, Br) from Haloalkenes on the Ru2Q2 (Q = S, Se) Core Complex". Inorganic Chemistry 41 (23): 6006–6012. doi:10.1021/ic020499t. PMID 12425626.
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