Chemistry:1-Adamantanecarboxylic acid
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Other names
1-Adamantane carboxylic acid
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3D model (JSmol)
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Properties | |
C11H16O2 | |
Molar mass | 180.247 g·mol−1 |
Appearance | white solid |
Melting point | 175–176.5 °C (347.0–349.7 °F; 448.1–449.6 K) |
Related compounds | |
Related compounds
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2-Adamantanecarboxylic acid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Tracking categories (test):
1-Adamantanecarboxylic acid is an organic compound with the formula (CH
2)
6(CH)
3(CCO
2H). A white solid, it is the simplest carboxylic acid derivative of adamantane. The compound is notable for its synthesis by carboxylation of adamantane.[1] 1-Adamantanecarboxylic acid is unusual in forming mononuclear tris(carboxylate) coordination complexes of the formula [M(O2CR)3]− (M = Mn, Ni, Co, Zn).[2]
References
- ↑ H. Koch and W. Haaf (1964). "1-Adamantanecarboxylic Acid". Organic Syntheses 44: 1. doi:10.15227/orgsyn.044.0001.
- ↑ Fursova, E. Yu.; Romanenko, G. V.; Tolstikov, S. E.; Ovcharenko, V. I. (2019). "Mononuclear Transition Metal Adamantane-1-Carboxylates". Russian Chemical Bulletin 68 (9): 1669–1674. doi:10.1007/s11172-019-2610-4.