Chemistry:2,2'-Bipyrimidine

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2,2′-Bipyrimidine
2,2'-bipyrimidine, corrected.png
Names
Preferred IUPAC name
2,2′-Bipyrimidine
Other names
2,2′-Dipyrimidine, bipyrimidyl
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 252-137-2
UNII
Properties
C8H6N4
Molar mass 158.164 g·mol−1
Appearance white solid
Melting point 113–115 °C (235–239 °F; 386–388 K)
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H315, H319, H335
P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

2,2′-Bipyrimidine is an organic compound with the formula (C4H3N2)2. It is a derivative of the heterocycle pyrimidine. It is a white solid. The compound is used as a bridging ligand in coordination chemistry.[1]

2,2′-Bipyrimidines can be prepared by Ullmann coupling of 2-iodopyrimidines.[2]

References

  1. Periana, Roy A.; Taube, Douglas J.; Gamble, Scott; Taube, Henry; Satoh, Takashi; Fujii, Hiroshi (1998). "Platinum Catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative". Science 280 (5363): 560–564. doi:10.1126/science.280.5363.560. PMID 9554841. Bibcode1998Sci...280..560P. 
  2. Vlád, Gábor; Horváth, István T. (2002). "Improved synthesis of 2,2′-bipyrimidine". The Journal of Organic Chemistry 67 (18): 6550–6552. doi:10.1021/jo0255781. PMID 12201781.