Chemistry:Bis(dicyclohexylphosphino)ethane
From HandWiki
| |||
Names | |||
---|---|---|---|
Preferred IUPAC name
(Ethane-1,2-diyl)bis(dicyclohexylphosphane) | |||
Other names
dcpe
| |||
Identifiers | |||
3D model (JSmol)
|
|||
ChemSpider | |||
PubChem CID
|
|||
| |||
| |||
Properties | |||
C26H48P2 | |||
Molar mass | 422.61 | ||
Appearance | white solid | ||
Melting point | 96–97 °C (205–207 °F; 369–370 K) | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
Infobox references | |||
Tracking categories (test):
Bis(dicyclohexylphosphino)ethane, abbreviated dcpe, is an organophosphorus compound with the formula (C6H11)2PCH2CH2P(C6H11)2. It is a white solid that is soluble in nonpolar organic solvents. The compound is used as a bulky and highly basic diphosphine ligand in coordination chemistry.[1]
References
- ↑ Sowa, J. R., Jr., Zanotti, V., Facchin, G., Angelici, R. J., "Calorimetric studies of the heats of protonation of the metal in Fe(CO)3(bidentate phosphine, arsine) complexes: effects of chelate ligands on metal basicity", J. Am. Chem. Soc. 1992, 114, 160. doi:10.1021/ja00027a023