Chemistry:Borophosphate

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The borophosphates are mixed anion compounds containing borate and phosphate anions, which may be joined together by a common oxygen atom. Compounds that contain water or hydroxy groups can also be included in the class of compounds.[1] Borophosphates can be classified by whether or not they are hydrated, and the anion structure, which can be single, double, triple, isolated ring, isolated branched ring, simple chain, branched chain, loop chain, layers, or three-dimensional network.[1] The isolated anion compounds are the borate phosphates, which contain separate borate and phosphate groups. Some of the borophosphate structures resemble silicates.[1]

Related compounds include aluminophosphates, which have aluminium instead of boron, gallophosphates,[2] with gallium in place of boron, and by substituting the phosphate: boroarsenates, boroantimonates, and vanadoborates.

Formation

Borophosphates can be formed by heating compounds together at up to 900 °C. The products are dense, anhydrous, and do not contain organic substances.[2]

Solvothermal synthesis uses a non water solvent such as ethylene glycol to dissolve the product.[2]

The flux method crystallises from a molten flux of boric acid and sodium dihydrogen phosphate at around 171.[3]

The hydrothermal method heats the ingredients with water under pressure up to 200 °C. The ingredients are boric acid, phosphoric acid, metal salts, or organic bases. Products often contain hydrogen.[2]

The ionothermal synthesis method uses an ionic liquid such as 1-alkyl-3-methylimidazolium bromide as a solvent. This can be done at atmospheric pressure and temperatures under 100 °C.[2]

Characteristics

Borophosphate compounds have been investigated for magnetic, electrical, optical and catalytic properties. Some borophosphates are porous and so have surface for interaction on their interiors, not just their surface. They can reversibly absorb water, or have channels that can allow ions to conduct. The reflection of a labelled tetrahedron cannot be superimposed (even with rotation or movements), so the compounds containing phosphate and borate tetrahedrons can be non-centrosymmetric, or chiral.[2]

List

name formula crystal system space group unit cell Å volume density comment refs
Li[B3PO6(OH)3] looped chain B3O3 rings OH on B and P [1]
Li2B3PO8 P1 [2]
Li3BP2O8 P1 [2]
NH4BeBP2O8·1/3H2O cubic P213 zeolite-ANA structure [4]
(NH4)2[B3PO7(OH)2] looped chain B3O3 rings OH on B [1]
(NH4)2B2P3O11(OH) monoclinic P21/c a=15.774 b=7.5213 c=8.9661 β=106.93° Z=4 1020.0 2.238 [5]
(NH4)3H2[BOB(PO4)3] infinite chains [6]
(NH4)4[H2B2P4O16] tetragonal P41212 [2]
(NH4)2BP2O7(OH) tetragonal P41212 a=7.2162 c=14.8258 Z=4 772.03 2.046 [5]
Na2[BP2O7(OH)] orthorhombic Pna21 a=6.8236, b=20.7911, c=13.1446, Z=12 layers [7]
Na3B6PO13 orthorhombic Pnma a=9.3727, b=16.2307, c=6.7232, Z=4 8 member rings [3]
Na3BP2O8 monoclinic C2/c a=12.567, b=10.290, c=10.210, β=92.492, Z=2 infinite chains [3]
Na5[BOB(PO4)3)] infinite chains [6]
NaBeBP2O8·1/3H2O cubic P213 zeolite-ANA structure [4]
Na13(H2O)2[B6P11O42(OH)2]Cl2·H2O F23 [2]
MgBPO4(OH)2 P3121 [2]
dimagnesium (monohydrogen­monophosphate­dihydrogenmonoborate­monophosphate) Mg2[BP2O7(OH)3] triclinic P1 a=6.452, b=6.455, c=8.360, α=82.50, β=82.56, γ=80.98, Z=1 338.8 triple [8]
(H3O)Mg(H2O)2[BP2O8]·H2O P6122 [2]
Mg3(H2O)6(B(OH)3PO4)2 double [1]
LiMg(H2O)2[BP2O8]·H2O P6522 [2]
NaMg(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.428, c=15.820 loop branched chain [9]
Na2[MgB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.771, c=12.100, Z=6 2.537 colourless [10]
K2B2P2O9 orthorhombic P212121 a=7.8227 b=8.1393 c=12.925 Z=4 822.9 2.468 [5]
K2BP2O7(OH) orthorhombic P212121 a=7.068 b=7.2396 c=14.116 Z=4 722.3 2.574 [5]
K3B4PO10 triclinic P1 a=6.546, b=6.567, c=12.930, α=86.04, β=81.40, γ=60.42, Z=2 477.9 2.443 colourless 2D sheet [11]
K7B2P5O19 [2]
K3[B5PO10(OH)3] loop branch [1]
LiK2BP2O8 P21/n [2]
Li3K2BP4O14 Cmca [2]
KBeBP2O8·1/3H2O cubic P213 a=12.427, Z=12 1,919 zeolite-ANA structure [4]
KMg(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.463, c=15.815 loop branched chain [9]
Ca[BPO5] loop branch B2PO3 rings [1]
Sc(H2O)2[BP2O8]·H2O hexagonal P6522 a=9.5752, c=15.8145, Z=6 1,255.7 2.378 [12]
Sc(H2O)2[BP2O8] hexagonal P6522 a=9.535, c=15.768, Z=6 [12]
NaSc[BP2O6(OH)3]·HPO4 P21/c [2]
Ti[BP2O7(OH)3] I41/amd [2]
V2[B(PO4)3] [13]
(VO)2BP2O10 [14]
Li3V2[BP3O12(OH)][HPO4] P21/c [2]
Na2[VB3P2O12(OH)]·2.92H2O I-43m [13]
NH4VIII[BP2O8(OH)] monoclinic P21/c a=9.425, b=8.269, c=9.697, β=102.26°, Z=4 738.5 [15]
[ImH2]3.8(H3O)1.2[(VIVO)4(BO)2(PO4)5]·0.3H2O monoclinic C2/c a=9.4737, b=22.144, c=17.219, β=105.936°, Z=4 layered [16]
[enH2]2[Na(VO)10B(O)2(OPO3H)2}5]·22.5H2O [17]
[trienH4]4H[NH4(VO)12{B(O)2(OPO3)2}6]·14H2O orthorhombic Pbca a=21.45, b=16.315, c=29.65, Z=4 10378 1.920 [18]
[trienH4]4H[K(VO)12{O3POB(O)2OPO3}6]·16H2O orthorhombic Pbca a=21.537, b=16.267, c=29.717, Z=4 10411 1.996 [18]
KV[BP2O8(OH)] triclinic P1 [2]
Cr2[B(PO4)3] P63/m [13]
Na{Cr[BP2O7(OH)3]} monoclinic C2/c a=10.4220, b=8.2468, c=9.2053, β=116.568°, Z=4 707.63 [19]
Na8[Cr4B12P8O44(OH)4][P2O7]·nH2O I23 [2]
Na11K5[NaCr8B4P12O60H8]·H2O Pmnn [2]
H2Mn5(H2O)6[BP2O8]4•4H2O hexagonal P6122 a=9.655, c=15.791, Z=1.5 pale pink [20]
Mn[BPO4(OH)2] P3221 a=7.5750, c=12.927, Z=6 642.37 3.020 [21]
LiMn(H2O)2[BP2O8(OH)]·H2O P6522 [2]
[NH4]4[Mn9B2(OH)2(HPO4)4(PO4)6] monoclinic C2/c a=32.603, b=10.617, c=10.718, β=108.26°, Z=4 3523 2.971 light pink [22]
(NH4)6[Mn3B6P9O36(OH)3]·4H2O C2 [2]
(NH4)7Mn4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4] Pnma [2]
(C3H12N2)[MnB2P3O12(OH)] [2]
(C4H12N2)[MnB2P3O12(OH)] Ima2 [2]
NaMn(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.589, c=15.939 loop branched chain [9]
Na5(H3O){Mn3[B3O3(OH)]3(PO4)6}·2H2O hexagonal P63/m a=11.9683, c=12.1303, Z=2 [23]
Na5(NH4)Mn3[B9P2O33(OH)3]·3/2H2O P63 [2]
Na2[MnB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.940, c=12.098, Z=6 2.670 colourless [10]
KMnBP2O7(OH)2 monoclinic P21/c a=6.659, b=12.049, c=9.790, β=109.12°, Z=4 742.2 orange-red luminescence [24]
KMn(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.639, c=15.931 loop branched chain [9]
K5Mn2B2P5O19(OH)2 P21/n [2]
FeIII2[B(PO4)3] P63/m [13]
Fe[B2P2O7(OH)5] monoclinic C2/c a=17.745, b=6.720, c=7.059, β=109.01°, Z=4 796 2.808 unbranched chain [1]
Fe(H2O)2BP2O8·H2O hexagonal a=9.4583, c=15.707, Z=6 1216.9 2.543 [25]
Fe[BPO4(OH)2] P3221 a=7.4844, c=12.844, Z=6 623.06 3.129 [21]
FeII(H2O)2[B2P2O8(OH)2]·H2O P21/c [2]
Fe1.834IIFe0.166IIIB0.5[PO3(OH)]0.8(HPO3)2.033 cubic I43d a=21.261, Z=48 [26]
NH4FeIII[BP2O8(OH)] monoclinic P21/c a=9.393, b=8.285, c=9.689, β=102.07°, Z=4 737.4 [15]
(NH4)0.75Fe(H2O)2[BP2O8]·1/4H2O P6522 [2]
(C3H12N2)[FeB2P3O12(OH)] Ima2 [2]
(C4H12N2)[FeB2P3O12(OH)] Ima2 [2]
(dienH3)(dienH2)0.5[FeII*III2B4P7O26(OH)4] P1 [2]
NaFe[BP2O7(OH)3] triple
sodium diaquoiron(II) catena-[monoboro-diphosphate] monohydrate NaFe(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.499, c=15.931 loop branched chain [9]
Na2[FeB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.812, c=12.067, Z=6 2.742 light yellow [10]
potassium diaquoiron(II) catena-[monoboro-diphosphate] hemihydrate KFe(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.510, c=15.952 loop branched chain [9]
K2Fe2[B2P4O16(OH)2] monoclinic P21/c a=9.372, b=8.146, c=9.587, β=101.18°, Z=2 718.0 B2P2O4 ring with phosphate sides [27]
KFeBP2O8(OH) P21/c [2]
CaFe[BP2O7(OH)3] C2/c [2]
Ca0.5Fe(H2O)2[BP2O8]·H2O P6522 [2]
Co5[BP3O14] double + phosphate [1]
Co3[BPO7] monoclinic Cm a=9.774, b=12.688, c=4.9057, β=119.749°, Z=4 528.2 [28]
Co[BPO4(OH)2] P3121 a=7.4554, c=12.7397, Z=6 613.24 3.229 [21]
(NH4)7Co4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4] Pnma [2]
(NH4)8[Co2B4P8O30(OH)4] P1 [2]
CoII(H2O)2[B2P2O8(OH)2]·H2O P21/c [2]
[Co(en)3][B2P3O11(OH)2] [29]
CoB2P3O12(OH)·H2en [30]
Co(C4H12N2)[B2P3O12(OH)] orthorhombic Ima2 a=12.4635, b=9.4021, c=11.4513, Z=4 1341.90 [31]
H2Co5(H2O)6[BP2O8]4•4H2O hexagonal P6122 a=9.639, c=15.931, Z=1.5 purple
LiCo(H2O)2[BP2O8]·H2O P6522
NaCo(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.455, c=15.847 loop branched chain [9]
NaCoH2BP2O9 monoclinic P21/c a=6.547, b=11.404, c=9.650, β=107.37 687.6 2.905 pink; discovered in Tunisia [32]
Na2[CoB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.759, c=12.099, Z=6 2.781 purple [10]
Na5(H3O){Co3[B3O3(OH)]3(PO4)6}·2H2O hexagonal P63/m a=11.7691, c=12.112, Z=2 [23]
Na6Co3B2P5O21Cl·H2O Pnma
KCo(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.483, c=15.827 loop branched chain [9]
CaCo(H2O)[BP2O8(OH)]·H2O P1 [2]
(K0.17Ca0.42)Co(H2O)2[BP2O8]·H2O P6522 [2]
(Co0.6Mn0.4)2(H2O)[BP3O9(OH)4] P212121 [2]
cobalt borophosphate ethylenediamine CoB2P3O12(OH)·en orthorhombic Pbca a=9.3501, b=12.2426, c=20.880 2,390.1 2.471 purple; layered [33][34]
(NH4)7Co4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4] Orthorhombic Pnma a=16.9206, b=10.5592, c=22.000, Z=4 3,930.6 2.386 pink [35]
(NH4)2(C4H12N2)[Co2B4P6O24(OH)2]·H2O I41/a [2]
NiBPO4(OH)2 P3121 [2]
Ni(H2O)2[B2P2O8(OH)2]·H2O P21/c [2]
LiNi(H2O)2[BP2O8]·H2O P6522 [2]
NaNi(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.371, c=15.831 loop branched chain [9]
Na2[NiB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.728, c=12.074, Z=6 2.799 yellow [10]
Na5(H3O){Ni3[B3O3(OH)]3(PO4)6}·2H2O hexagonal P63/m a=11.7171, c=12.0759, Z=2 [23]
KNi(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.392, c=15.842 loop branched chain [9]
Cu3[B2P3O12(OH)3] monoclinic Cc a=6.1895, b=13.6209, c=11.9373, β=97.62°, Z=4 997.5 [36]
Cu(H2O)2[B2P2O8(OH)2] [37]
Cu2(H2O)[BP2O8(OH)] Pbca [2]
LiCu2[BP2O8(OH)2] C2/c [2]
LiCu2[BP2O8(OH)2] P212121 [2]
Na2[CuB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.554, c=12.314, Z=6 2.862 sky-blue [10]
Na4Cu3[B2P4O15(OH)2]•2HPO4 ring with side phosphate and extra phosphate
Na5KCu3[B9P6O33(OH)3]·H2O P63/m [2]
Zn(C4H12N2)[B2P3O12(OH)] orthorhombic Ima2 a=12.4110, b=9.4550, c=11.4592, Z=4 1344.69 [31]
lithium zinc diaqua catena-[monoboro-diphosphate]-monohydrate LiZn(H2O)2[BP2O8] · H2O hexagonal P61 a=9.469, c=15.667, Z=6 1216.6 spiral ribbons [38]
Na[ZnBP2O8]⋅H2O hexagonal P6122 a=9.5404, c=14.7780, Z=6 1164.88 [39]
NaZn(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.456, c=15.828 loop branched chain [9]
Na2[ZnB3P2O11(OH)]·2/3H2O hexagonal P63 a=11.963, c=12.363, Z=6 2.683 colourless [10]
NH4[ZnBP2O8] triclinic P1 a=7.437, b=7.612, c=7.850, α=119.05, β=101.59, γ=103.43, Z=2 351.18 2.687 [40]
Na[ZnBP2O8] triclinic P1 [2]
K[ZnBP2O8] monoclinic C2/c a=12.617, b=12.773, c=8.415, β=91.25°, Z=8 1355.8 2.991 [40]
[trienH4]1.5[Zn6B6P12O48]·3/2H2O hexagonal P6522 a=9.6685, c=14.8879; Z=1 [41]
RBPO Rb3B11P2O23 Triclinic P1 a=7.785, b=7.839, c=7.963, α=89,774, β=89.129, γ=88.211, Z=2 485.6 2.753 transparent above 168 nm; SHG 2.5× KDP; birefringence =0.071@1064 nm [42]
Rb[P2B2O8(OH)] network [1]
Li3Rb2BP4O14 Cmca [2]
K2RbB4PO10 triclinic P1 a=6.5577, b=6.5931, c=13.098, α=84.626, β=80.514, γ=60.457, Z=2 485.9 2.719 colourless [11]
K2RbB8PO16 birefringence 0.057@1064 nm [43]
Rb2Co3(H2O)2[B4P6O24(OH)2] orthorhombic Pbca a = 9.501, b = 12.272, c = 20.074, Z = 4 [44]
Rb[ZnBP2O8] triclinic P1 a=7.439, b=7.639, c=7.861, α=118.82, β=101.73, γ=103.51, Z=2 353.4 3.304 [40]
Sr[BPO5] P3221 loop branch B2PO3 rings [1]
KSrBP2O8 I42d a=7.109, c=13.882 [45]
SrFe[BP2O8(OH)2] C2/c [2]
SrCo2BPO7 monoclinic P21/c a=6.485, b=9.270, c=10.066, β=111.14, Z=4 548.7 red [46]
AgMg(H2O)2[BP2O8]·H2O P6522 [2]
2/3H2O P6522 [2]
(Ag0.57Ni0.22)Ni(H2O)2[BP2O8]·2/3H2O P6522 [2]
Na3Cd3BP4O16 orthorhombic Pmc21 a=13.6854, b=5.335, c=18.2169, Z=4 SHG 1.1×KDP [2][47]
NH4Cd(H2O)2(BP2O8)·0.72H2O hexagonal P65 a=9.698, c=16.026, Z=6 1305.3 2.886 colourless [48]
In2[B(PO4)3] P63/m [13]
Cs[P2B2O8(OH)] 3D network [1]
Li2Cs2B2P4O15
K2CsB4PO10 triclinic P1 a=6.6235, b=6.6243, c=13.273, α=79.734, β=86.558, γ=60.095, Z=2 496.46 2.979 colourless [11]
Cs2Cr3(BP4O14)(P4O13) monoclinic P21/c a=14.7918, b=15.819, c=9.7037, β=92.450, Z=4 876.9 3.257 green; [B(P2O7)2]5− [49]
CsFe(BP3O11) orthorhombic Pnma a=8.5375, b=12.7829, c=8.3346, Z=4 909.59 3.434 [N(PO4)(P2O7)]4- [49]
Cs2Co3(H2O)2[B4P6O24(OH)2] orthorhombic Pbca a=9.5526, b=12.3190, c=20.1123 2366.8 pink [2][50]
Cs[ZnBP2O8] triclinic P1 a=7.506, b=7.914, c=8.038, α=1198.05, β=102.96, γ=104.50, Z=2 373.9 3.545 [40]
Ba[BPO5] P3221 [2]
Ba[BP3O12] orthorhombic Ibca a=7.066, b=14.268, c=22.159 2233.9 4.209 [1][51]
KBaBP2O8 I42d a=7.202, c=14.300 [45]
BaFe[BP2O8(OH)] P1 [2]
BaCo[BP2O8(OH)] P1 [2]
Pb[BPO5] loop branch B2PO3 rings [1]
Pb3[(PO4)2BPO4] orthorhombic Pbca a=6.946, b=14.199, c=21.116, Z=8 2082.5 5.851 open branch, 2 PO4 extra on each B [51]
Na3PbII[B(O3POH)4] I41/a [2]
KPbBP2O8 I42d [2]
PbII4Cl{Co2[B(OH)2P2O8](PO4)2]} R3c [2]
RbPbBP2O8 I42d [2]
BiCo2BP2O10 P21/m [2]
BiNi2BP2O10 P21/m [2]
K2(UO2)12[B(H2PO4)4](PO4)8(OH)(H2O)6 tetragonal I42m a=21.8747, c=7.0652 3380.7 [52]
K5(UO2)2[B2P3O12(OH)]2(OH)(H2O)2 monoclinic P21 a=6.7623, b=19.5584, c=11.0110, β=95.579° 1449.42 [52]
Ag2(NH4)3{(UO2)2[B3O(PO4)4(HPO4)2]}·H2O P1 [2]
Ag2−x(NH4)3{(UO2)2[B2P5−yAsyO20−x(OH)x]} Pcmn [2]
Cs3(UO2)3[B(PO4)4]∙(H2O)0.5 P41212 a=12.2376, c=33.9468, Z=4 5083.8 yellow; microporous [53]

References

  1. ↑ 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.14 Kniep, Rüdiger; Engelhardt, Holger; Hauf, Cornelia (October 1998). "A First Approach to Borophosphate Structural Chemistry" (in en). Chemistry of Materials 10 (10): 2930–2934. doi:10.1021/cm980263g. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm980263g. 
  2. ↑ 2.00 2.01 2.02 2.03 2.04 2.05 2.06 2.07 2.08 2.09 2.10 2.11 2.12 2.13 2.14 2.15 2.16 2.17 2.18 2.19 2.20 2.21 2.22 2.23 2.24 2.25 2.26 2.27 2.28 2.29 2.30 2.31 2.32 2.33 2.34 2.35 2.36 2.37 2.38 2.39 2.40 2.41 2.42 2.43 2.44 2.45 2.46 2.47 2.48 2.49 2.50 2.51 2.52 2.53 2.54 2.55 2.56 2.57 2.58 2.59 2.60 2.61 2.62 2.63 2.64 2.65 2.66 2.67 2.68 2.69 Li, Min; Verena-Mudring, Anja (6 April 2016). "New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates". Crystal Growth & Design 16 (4): 2441–2458. doi:10.1021/acs.cgd.5b01035. 
  3. ↑ 3.0 3.1 3.2 Xiong, Ding-Bang; Chen, Hao-Hong; Yang, Xin-Xin; Zhao, Jing-Tai (January 2007). "Low-temperature flux syntheses and characterizations of two 1-D anhydrous borophosphates: Na3B6PO13 and Na3BP2O8" (in en). Journal of Solid State Chemistry 180 (1): 233–239. doi:10.1016/j.jssc.2006.09.034. Bibcode: 2007JSSCh.180..233X. https://linkinghub.elsevier.com/retrieve/pii/S0022459606005184. 
  4. ↑ 4.0 4.1 4.2 Zhang, Haoyu; Chen, Zhenxia; Weng, Linhong; Zhou, Yaming; Zhao, Dongyuan (February 2003). "Hydrothermal synthesis of new berylloborophosphates MIBeBPO (MI=K+, Na+ and NH4+) with zeolite ANA framework topology" (in en). Microporous and Mesoporous Materials 57 (3): 309–316. doi:10.1016/S1387-1811(02)00605-4. https://linkinghub.elsevier.com/retrieve/pii/S1387181102006054. 
  5. ↑ 5.0 5.1 5.2 5.3 Yang, Xia; Zhang, Wenbin; Pan, Xueting; Hou, Xueling; Han, Shujuan (2023-11-22). "Hydroxyl-Driven Enhanced Birefringence in Borophosphates" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c03394. ISSN 0020-1669. PMID 37992320. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c03394. 
  6. ↑ 6.0 6.1 Ridenour, J. August; Chaloux, Brian L.; Johannes, Michelle D.; Finn, Matthew T.; Ryou, Heonjune; Epshteyn, Albert (2023-10-19). "High thermal stability 1D borophosphate proton conducting polyelectrolytes" (in en). MRS Advances 8 (15): 811–815. doi:10.1557/s43580-023-00663-6. ISSN 2059-8521. Bibcode: 2023MRSAd...8..811R. https://link.springer.com/10.1557/s43580-023-00663-6. 
  7. ↑ Kniep, Rüdiger; Engelhardt, Holger (1998). "Na1.89Ag0.11[BP2O7(OH) und Na2[BP2O7(OH)] – Isotype Borophosphate mit Tetraeder-Schichtpaketen"] (in de). Zeitschrift für anorganische und allgemeine Chemie 624 (8): 1291–1297. doi:10.1002/(SICI)1521-3749(199808)624:8<1291::AID-ZAAC1291>3.0.CO;2-R. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3749%28199808%29624%3A8%3C1291%3A%3AAID-ZAAC1291%3E3.0.CO%3B2-R. 
  8. ↑ Häuf, C.; Boy, I.; Kniep, R. (1999-03-01). "Crystal structure of dimagnesium (monohydrogenmonophosphate-dihydrogenmonoborate-monophosphate), Mg2[BP2O7(OH)3]". Zeitschrift für Kristallographie - New Crystal Structures 214 (1): 3–4. doi:10.1515/ncrs-1999-0103. ISSN 2197-4578. 
  9. ↑ 9.00 9.01 9.02 9.03 9.04 9.05 9.06 9.07 9.08 9.09 9.10 Kniep, Rüdiger; Will, Horst Günter; Boy, Insan; Röhr, Caroline (1997). "61 Helices from Tetrahedral Ribbons ∞1[BP2O3−8: Isostructural Borophosphates MIMII(H2O)2[BP2O8] · H2O (MI=Na, K; MII=Mg, Mn, Fe, Co, Ni, Zn) and Their Dehydration to Microporous Phases MIMII(H2O)[BP2O8]"]. Angewandte Chemie International Edition in English 36 (9): 1013–1014. doi:10.1002/anie.199710131. ISSN 1521-3773. https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.199710131. 
  10. ↑ 10.0 10.1 10.2 10.3 10.4 10.5 10.6 Yang, Tao; Li, Guobao; Ju, Jing; Liao, Fuhui; Xiong, Ming; Lin, Jianhua (August 2006). "A series of borate-rich metalloborophosphates Na2[MIIB3P2O11(OH)·0.67H2O (MII=Mg, Mn, Fe, Co, Ni, Cu, Zn): Synthesis, structure and magnetic susceptibility"] (in en). Journal of Solid State Chemistry 179 (8): 2534–2540. doi:10.1016/j.jssc.2006.04.052. Bibcode: 2006JSSCh.179.2534Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459606002404. 
  11. ↑ 11.0 11.1 11.2 Hou, Ying; Zhang, Bingbing; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2020-12-31). "K3B4PO10 and K2MB4PO10 (M=Rb/Cs): rare mixed-coordinated borophosphates with large birefringence" (in en). Inorganic Chemistry Frontiers 8 (6): 1468–1475. doi:10.1039/D0QI01354D. ISSN 2052-1553. https://pubs.rsc.org/en/content/articlelanding/2021/qi/d0qi01354d. 
  12. ↑ 12.0 12.1 Ewald, Bastian; Prots, Yurii; Kudla, Christian; Grüner, Daniel; Cardoso-Gil, Raul; Kniep, Rüdiger (February 2006). "Crystal Structure and Thermochemical Properties of a First Scandium Borophosphate, Sc(H2O)2[BP2O8·H2O"] (in en). Chemistry of Materials 18 (3): 673–679. doi:10.1021/cm051577o. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm051577o. 
  13. ↑ 13.0 13.1 13.2 13.3 13.4 Netzsch, Philip; Gross, Peter; Takahashi, Hirotaka; Höppe, Henning A. (2018-07-16). "Synthesis and Characterization of the First Borosulfates of Magnesium, Manganese, Cobalt, Nickel, Zinc" (in en). Inorganic Chemistry 57 (14): 8530–8539. doi:10.1021/acs.inorgchem.8b01234. ISSN 0020-1669. PMID 29957944. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01234. 
  14. ↑ Bontchev, Ranko P.; Do, Junghwan; Jacobson, Allan J. (1999). "Templated Synthesis of Vanadium Borophosphate Cluster Anions" (in en). Angewandte Chemie International Edition 38 (13–14): 1937–1940. doi:10.1002/(SICI)1521-3773(19990712)38:13/14<1937::AID-ANIE1937>3.0.CO;2-5. ISSN 1521-3773. PMID 34182687. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3773%2819990712%2938%3A13/14%3C1937%3A%3AAID-ANIE1937%3E3.0.CO%3B2-5. 
  15. ↑ 15.0 15.1 Kritikos, Mikael; Wikstad, Emma; Walldén, Karin (2001-08-01). "Hydrothermal synthesis, characterization and magnetic properties of three isostructural chain borophosphates; NH4M(III)[BP2O8(OH) with M=V or Fe and NH4(Fe(III)0.53V(III)0.47)[BP2O8(OH)]"] (in en). Solid State Sciences 3 (6): 649–658. doi:10.1016/S1293-2558(01)01182-7. ISSN 1293-2558. Bibcode: 2001SSSci...3..649K. http://www.sciencedirect.com/science/article/pii/S1293255801011827. 
  16. ↑ Bontchev, Ranko P.; Do, Junghwan; Jacobson, Allan J. (July 2000). "Synthesis and Characterization of the Layered Vanadium Borophosphate (Imidazolium)3.8(H3O)1.2[(VO)4(BO)2(PO4)5·0.3H2O"] (in en). Inorganic Chemistry 39 (15): 3320–3324. doi:10.1021/ic000177u. ISSN 0020-1669. PMID 11196870. https://pubs.acs.org/doi/10.1021/ic000177u. 
  17. ↑ Warren, Christopher J; C. Haushalter, Robert; Rose, David J; Zubieta, Jon (January 1998). "The first oxometalate borophosphate polyanion: hydrothermal synthesis and structure of (H3NCH2CH2NH3)2[Na(VO)10{HO3POB(O)2OPO3H}5]·22.5H2O" (in en). Inorganic Chemistry Communications 1 (1): 4–6. doi:10.1016/S1387-7003(97)00002-6. 
  18. ↑ 18.0 18.1 Zhao, Yongnan; Shi, Zhan; Ding, Shihai; Bai, Ni; Liu, Wang; Zou, Yongcun; Zhu, Guangshan; Zhang, Ping et al. (September 2000). "Synthesis and Structure of 12-Member Ring Crown-Shaped Oxovanadium Borophosphate Polyanions: [H3NC2H4NH2C2H4NH2C2H4NH34H[M(VO)12{O3POB(O)2OPO3}6]·nH2O (M=NH4+, K+)"] (in en). Chemistry of Materials 12 (9): 2550–2556. doi:10.1021/cm990597l. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm990597l. 
  19. ↑ Yamnova, N. A.; Aksenov, S. M.; Borovikova, E. Yu.; Volkov, A. S.; Gurbanova, O. A.; Dimitrova, O. V.; Burns, P. C. (March 2019). "A Novel Sodium and Chromium Borophosphate Na{Cr[BP2O7(OH)3}: Synthesis, Crystal Structure, Hydrogen Bonding, and Comparative Crystal Chemistry"] (in en). Crystallography Reports 64 (2): 228–238. doi:10.1134/S1063774519020342. ISSN 1063-7745. http://link.springer.com/10.1134/S1063774519020342. 
  20. ↑ Yilmaz, A.; Tatar Yįldįrįm, L.; Bu, X.; Kizilyalli, M.; Stucky, G. D. (2005). "New zeotype borophosphates with chiral tetrahedral topology: (H)0.5M1.25(H2O)1.5[BP2O8];·H2O (M=Co(II) and Mn(II))". Crystal Research and Technology 40 (6): 579–585. doi:10.1002/crat.200410386. Bibcode: 2005CryRT..40..579Y. 
  21. ↑ 21.0 21.1 21.2 Huang, Ya-Xi; Ewald, Bastian; Schnelle, Walter; Prots, Yurii; Kniep, Rüdiger (September 2006). "Chirality and Magnetism in a Novel Series of Isotypic Borophosphates: M II [BPO 4 (OH) 2 (M II=Mn, Fe, Co)"] (in en). Inorganic Chemistry 45 (19): 7578–7580. doi:10.1021/ic0607991. ISSN 0020-1669. PMID 16961345. https://pubs.acs.org/doi/10.1021/ic0607991. 
  22. ↑ Yang, Miao; Yu, Jihong; Shi, Lei; Chen, Peng; Li, Guanghua; Chen, Yan; Xu, Ruren; Gao, Song (January 2006). "Synthesis, Structure, and Magnetic Property of a New Open-Framework Manganese Borophosphate, [NH 4 4 [Mn 9 B 2 (OH) 2 (HPO 4 ) 4 (PO 4 ) 6 ]"] (in en). Chemistry of Materials 18 (2): 476–481. doi:10.1021/cm052170m. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm052170m. 
  23. ↑ 23.0 23.1 23.2 Yang, Miao; Yu, Jihong; Di, Jiancheng; Li, Jiyang; Chen, Peng; Fang, Qianrong; Chen, Yan; Xu, Ruren (May 2006). "Syntheses, Structures, Ionic Conductivities, and Magnetic Properties of Three New Transition-Metal Borophosphates Na 5 (H 3 O){M II 3 [B 3 O 3 (OH) 3 (PO 4 ) 6 }·2H 2 O (M II=Mn, Co, Ni)"] (in en). Inorganic Chemistry 45 (9): 3588–3593. doi:10.1021/ic051916f. ISSN 0020-1669. PMID 16634589. https://pubs.acs.org/doi/10.1021/ic051916f. 
  24. ↑ Wang, Guangmei; Valldor, Martin; Lorbeer, Chantal; Mudring, Anja-Verena (June 2012). "Ionothermal Synthesis of the First Luminescent Open-Framework Manganese Borophosphate with Switchable Magnetic Properties" (in en). European Journal of Inorganic Chemistry 2012 (18): 3032–3038. doi:10.1002/ejic.201200110. http://doi.wiley.com/10.1002/ejic.201200110. 
  25. ↑ Yilmaz, Aysen; Bu, Xianhui; Kizilyalli, Meral; Stucky, Galen D. (November 2000). "Fe(H 2 O) 2 BP 2 O 8 ·H 2 O, a First Zeotype Ferriborophosphate with Chiral Tetrahedral Framework Topology" (in en). Chemistry of Materials 12 (11): 3243–3245. doi:10.1021/cm001082t. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm001082t. 
  26. ↑ Yaghoobnejad Asl, Hooman; Morris, Ronetta; Tran, T. Thao; Halasyamani, P. Shiv; Ghosh, Kartik; Choudhury, Amitava (2016-03-02). "A Cubic Non-Centrosymmetric Mixed-Valence Iron Borophosphate–Phosphite". Crystal Growth & Design 16 (3): 1187–1194. doi:10.1021/acs.cgd.5b01106. ISSN 1528-7483. https://doi.org/10.1021/acs.cgd.5b01106. 
  27. ↑ Wang, Guangmei; Mudring, Anja-Verena (2011-04-19). "A New Open-framework Iron Borophosphate from Ionic Liquids: KFe[BP2O8(OH)]" (in en). Crystals 1 (2): 22–27. doi:10.3390/cryst1020022. ISSN 2073-4352. 
  28. ↑ Yilmaz, Aysen; Bu, Xianhui; Kizilyalli, Meral; Kniep, Rudiger; Stucky, Galen D. (February 2001). "Cobalt Borate Phosphate, Co3[BPO7, Synthesis and Characterization"] (in en). Journal of Solid State Chemistry 156 (2): 281–285. doi:10.1006/jssc.2000.8963. Bibcode: 2001JSSCh.156..281Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459600989631. 
  29. ↑ Yang, Guo-Yu; Sevov, Slavi C. (May 2001). "[Co(en) 3 [B 2 P 3 O 11 (OH) 2 ]: A Novel Borophosphate Templated by a Transition-Metal Complex"] (in en). Inorganic Chemistry 40 (10): 2214–2215. doi:10.1021/ic001397a. ISSN 0020-1669. PMID 11327891. https://pubs.acs.org/doi/10.1021/ic001397a. 
  30. ↑ Sevov, Slavi C. (1996). "Synthesis and Structure of CoB2P3O12(OH)·C2H10N2: The First Metal Borophosphate with an Open Framework Structure". Angewandte Chemie International Edition in English 35 (22): 2630–2632. doi:10.1002/anie.199626301. ISSN 1521-3773. https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.199626301. 
  31. ↑ 31.0 31.1 Schäfer, Gerd; Borrmann, Horst; Kniep, Rüdiger (2001). "MII(C4H12N2)[B2P3O12(OH) (MII=Co, Zn): Synthesis and Crystal Structure of Novel Open Framework Borophosphates"] (in en). Zeitschrift für anorganische und allgemeine Chemie 627 (1): 61–67. doi:10.1002/1521-3749(200101)627:1<61::AID-ZAAC61>3.0.CO;2-O. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749%28200101%29627%3A1%3C61%3A%3AAID-ZAAC61%3E3.0.CO%3B2-O. 
  32. ↑ Guesmi, A.; Driss, A. (2004). "Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9". Advanced Engineering Materials 6 (10): 840–842. doi:10.1002/adem.200400088. 
  33. ↑ Sevov, Slavi C. (18 November 1996). "Synthese und Struktur von CoB2P3O12(OH) · C2H10N2: das erste Metallborophosphat mit einer offenen Gerüststruktur" (in de). Angewandte Chemie 108 (22): 2814–2816. doi:10.1002/ange.19961082218. Bibcode: 1996AngCh.108.2814S. http://doi.wiley.com/10.1002/ange.19961082218. 
  34. ↑ Sevov, Slavi C. (December 1996). "Synthesis and Structure of CoB2P3O12(OH)·C2H10N2: The First Metal Borophosphate with an Open Framework Structure" (in en). Angewandte Chemie International Edition in English 35 (22): 2630–2632. doi:10.1002/anie.199626301. ISSN 0570-0833. http://doi.wiley.com/10.1002/anie.199626301. 
  35. ↑ Yang, Miao; Xu, Feifei; Liu, Qingshan; Yan, Peifang; Liu, Xiumei; Wang, Chang; Welz-Biermann, Urs (2010). "Chelated orthoborate ionic liquid as a reactant for the synthesis of a new cobalt borophosphate containing extra-large 16-ring channels" (in en). Dalton Transactions 39 (44): 10571–3. doi:10.1039/c0dt00368a. ISSN 1477-9226. PMID 20830394. http://xlink.rsc.org/?DOI=c0dt00368a. 
  36. ↑ Duan, Ruijing; Liu, Wei; Cao, Lixin; Su, Ge; Xu, Hongmei; Zhao, Chenggong (February 2014). "A new copper borophosphate with novel polymeric chains and its structural correlation with raw materials in molten hydrated flux synthesis" (in en). Journal of Solid State Chemistry 210 (1): 60–64. doi:10.1016/j.jssc.2013.10.043. Bibcode: 2014JSSCh.210...60D. https://linkinghub.elsevier.com/retrieve/pii/S0022459613005215. 
  37. ↑ Shi, Hengzhen; Li, Min; Tangbo, Hejin; Kong, Aiguo; Chen, Bo; Shan, Yongkui (November 2005). "A Novel Open-Framework Copper Borophosphate: Cu(H 2 O) 2 [B 2 P 2 O 8 (OH) 2 "] (in en). Inorganic Chemistry 44 (23): 8179–8181. doi:10.1021/ic0511773. ISSN 0020-1669. PMID 16270949. https://pubs.acs.org/doi/10.1021/ic0511773. 
  38. ↑ Boy, I.; Kniep, R. (2001-01-01). "Crystal structure of lithium zinc diaqua catena-[monoboro-diphosphate]- monohydrate, LiZn(H2O)2[BP2O8] · H2O". Zeitschrift für Kristallographie - New Crystal Structures 216 (1–4). doi:10.1524/ncrs.2001.216.14.9. ISSN 2197-4578. 
  39. ↑ Boy, Insan; Stowasser, Frank; Schäfer, Gerd; Kniep, Rüdiger (2001). "NaZn(H2O)2[BP2O8⋅H2O: A Novel Open-Framework Borophosphate and its Reversible Dehydration to Microporous Sodium Zincoborophosphate Na[ZnBP2O8]⋅H2O with CZP Topology"] (in en). Chemistry – A European Journal 7 (4): 834–839. doi:10.1002/1521-3765(20010216)7:4<834::AID-CHEM834>3.0.CO;2-A. ISSN 1521-3765. PMID 11288875. https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/1521-3765%2820010216%297%3A4%3C834%3A%3AAID-CHEM834%3E3.0.CO%3B2-A. 
  40. ↑ 40.0 40.1 40.2 40.3 Kniep, Rüdiger; Schäfer, Gerd; Engelhardt, Holger; Boy, Insan (1999). "K[ZnBP2O8 and A[ZnBP2O8] (A=NH4+, Rb+, Cs+): Zincoborophosphates as a New Class of Compounds with Tetrahedral Framework Structures"] (in en). Angewandte Chemie International Edition 38 (24): 3641–3644. doi:10.1002/(SICI)1521-3773(19991216)38:24<3641::AID-ANIE3641>3.0.CO;2-B. ISSN 1521-3773. PMID 10649310. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3773%2819991216%2938%3A24%3C3641%3A%3AAID-ANIE3641%3E3.0.CO%3B2-B. 
  41. ↑ Wiebcke, Michael; Bögershausen, Ansgar; Koller, Hubert (March 2005). "Hydrothermal synthesis, crystal structure and thermal behaviour of a zincoborophosphate, (H4TETA)1.5[Zn6B6P12O48·1.5H2O (TETA=triethylenetetraamine), with a chiral tetrahedral framework (CZP framework type)"] (in en). Microporous and Mesoporous Materials 78 (2–3): 97–102. doi:10.1016/j.micromeso.2004.09.020. https://linkinghub.elsevier.com/retrieve/pii/S1387181104003956. 
  42. ↑ Liu, Haonan; Wu, Hongping; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng; Halasyamani, P. Shiv; Yu, Hongwei (2022-12-12). "Rb 3 B 11 P 2 O 23 : Materials Design of a New Chemically Benign Deep-Ultraviolet Nonlinear Optical Material" (in en). ACS Materials Letters 5: 155–161. doi:10.1021/acsmaterialslett.2c00929. ISSN 2639-4979. https://pubs.acs.org/doi/10.1021/acsmaterialslett.2c00929. 
  43. ↑ Zuo, Jianyi; Feng, Qiuyuan; Du, Hong (2023-12-15). "K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c03090. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c03090. 
  44. ↑ Engelhardt, Holger; Schnelle, Walter; Kniep, Rüdiger (2000). "Rb2Co3(H2O)2[B4P6O24(OH)2: Ein Borophosphat mit -Tetraeder-Anionenteilstruktur und Oktaeder-Trimeren (CoO12(H2O)2)"] (in de). Zeitschrift für anorganische und allgemeine Chemie 626 (6): 1380–1386. doi:10.1002/(SICI)1521-3749(200006)626:6<1380::AID-ZAAC1380>3.0.CO;2-Z. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3749%28200006%29626%3A6%3C1380%3A%3AAID-ZAAC1380%3E3.0.CO%3B2-Z. 
  45. ↑ 45.0 45.1 Zhao, Dan; Cheng, Wen-Dan; Zhang, Hao; Huang, Shu-Ping; Xie, Zhi; Zhang, Wei-Long; Yang, Song-Lin (2009-07-20). "KMBP 2 O 8 (M=Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework" (in en). Inorganic Chemistry 48 (14): 6623–6629. doi:10.1021/ic900620x. ISSN 0020-1669. PMID 19507825. https://pubs.acs.org/doi/10.1021/ic900620x. 
  46. ↑ Gou, Wenbin; He, Zhangzhen; Yang, Ming; Zhang, Weilong; Cheng, Wendan (2013-03-04). "Synthesis and Magnetic Properties of a New Borophosphate SrCo 2 BPO 7 with a Four-Column Ribbon Structure" (in en). Inorganic Chemistry 52 (5): 2492–2496. doi:10.1021/ic3023979. ISSN 0020-1669. PMID 23406089. https://pubs.acs.org/doi/10.1021/ic3023979. 
  47. ↑ Shi, Yunjing; Pan, Shilie; Dong, Xiaoyu; Wang, Ying; Zhang, Min; Zhang, Fangfang; Zhou, Zhongxiang (2012-10-15). "Na 3 Cd 3 B(PO 4 ) 4 : A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units" (in en). Inorganic Chemistry 51 (20): 10870–10875. doi:10.1021/ic301351k. ISSN 0020-1669. PMID 23005578. https://pubs.acs.org/doi/10.1021/ic301351k. 
  48. ↑ Ge, Ming-Hui; Liu, Wei; Chen, Hao-Hong; Li, Man-Rong; Yang, Xin-Xin; Zhao, Jing-Tai (2005). "NH4Cd(H2O)2(BP2O8)·0.72H2O: a New Borophosphate with Abnormal Structure Changes Caused by Hydrogen Interactions". Zeitschrift für anorganische und allgemeine Chemie 631 (6–7): 1213–1217. doi:10.1002/zaac.200400551. 
  49. ↑ 49.0 49.1 Zhang, Weilong; Cheng, Wendan; Zhang, Hao; Geng, Lei; Li, Yeyu; Lin, Chensheng; He, Zhangzhen (March 2010). "Syntheses and Characterizations of Cs 2 Cr 3 (BP 4 O 14 )(P 4 O 13 ) and CsFe(BP 3 O 11 ) Compounds with Novel Borophosphate Anionic Partial Structures" (in en). Inorganic Chemistry 49 (5): 2550–2556. doi:10.1021/ic902463t. ISSN 0020-1669. PMID 20112999. https://pubs.acs.org/doi/10.1021/ic902463t. 
  50. ↑ Menezes, Prashanth W.; Hoffmann, Stefan; Prots, Yurii; Kniep, Rüdiger (2009-01-01). "Crystal structure of dicaesium diaquatricobalt(II) (phosphate-borate-hydrogenphosphate), Cs2Co3(H2O)2[B4P6O24(OH)2]". Zeitschrift für Kristallographie - New Crystal Structures 224 (1): 1–2. doi:10.1524/ncrs.2009.0001. ISSN 2197-4578. 
  51. ↑ 51.0 51.1 Park, C. H.; Bluhm, K. (1995-11-01). "Synthese und Kristallstruklur von Triblei-Diphosphato-Borat-Phosphat, eine Verbindung mit einem 1∞[(PO4)2BPO4]6–-Anion / Synthesis and Crystal Structure of Trilead-Diphosphato-Borate-Phosphate, a Compound with a 1∞[(PO4)2BPO4]6–-Anion". Zeitschrift für Naturforschung B 50 (11): 1617–1622. doi:10.1515/znb-1995-1107. ISSN 1865-7117. 
  52. ↑ 52.0 52.1 Hao, Yucheng; Murphy, Gabriel L.; Bosbach, Dirk; Modolo, Giuseppe; Albrecht-Schmitt, Thomas E.; Alekseev, Evgeny V. (2017-08-07). "Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures" (in en). Inorganic Chemistry 56 (15): 9311–9320. doi:10.1021/acs.inorgchem.7b01443. ISSN 0020-1669. PMID 28718634. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01443. 
  53. ↑ Hao, Yucheng (2017). "New Insight into the Crystal Chemistry of Uranium and Thorium Borates, Borophosphates and Borate-phosphates". https://d-nb.info/1169830692/34. 



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