Chemistry:Dundasite

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Dundasite
Dundasite and Crocoite.jpg
Dundasite (the white mineral) and crocoite from Dundas, Tasmania. Field of view is 5mm.
General
CategoryCarbonate mineral
Formula
(repeating unit)
PbAl2[(OH)2|CO3]2 • H2O
Strunz classification5.DB.10
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPbmm (no. 51)
Unit cella = 9.08, b = 16.37
c = 5.62 [Å]; Z = 4
Identification
ColorWhite to very pale blue; colorless in transmitted light
Crystal habitAcicular crystals typically in spherical aggregates and matted crusts
CleavagePerfect On {010}
Mohs scale hardness2
|re|er}}Vitreous to silky
StreakWhite
DiaphaneityTransparent
Specific gravity3.10 – 3.55
Optical propertiesBiaxial (-)
Refractive indexnα = 1.603 nβ = 1.716 nγ = 1.750
Birefringenceδ = 0.147
2V angleMeasured: 30° to 40°, calculated: 54°
References[1][2][3]

Dundasite is a rare lead aluminium carbonate mineral. The mineral is named after the type locality, Dundas, Tasmania, Australia .[1] The mineral was first discovered in the Adelaide Proprietary Mine.[5] Dundasite was first described by William Frederick Petterd in 1893.[6]

Dundasite is an uncommon secondary mineral occurring in the oxidized zone of lead ore deposits.[2] It commonly overgrows crocoite. It may also be overgrown by yellow cerussite.[5] It may be associated with cerussite, plattnerite, azurite, malachite, pyromorphite, mimetite, beudantite, duftite, crocoite, gibbsite, allophane and limonite.[2]

Besides its type location on Tasmania, the mineral has also been found in New Zealand, Mainland Australia , China, Belgium, Germany , France , Greece, United Kingdom , Ireland, Italy, Austria, Czech Republic, Namibia, and the US.[1]

References

  1. 1.0 1.1 1.2 "Dundasite mineral information and data". mindat.org. http://www.mindat.org/min-1330.html. 
  2. 2.0 2.1 2.2 "Handbook of Mineralogy: Dunasite". RRUF Database. http://rruff.geo.arizona.edu/doclib/hom/dundasite.pdf. 
  3. "Dundasite Mineral Data". Webmineral. http://www.webmineral.com/data/Dundasite.shtml. 
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. 5.0 5.1 Bottrill, Ralph (April 12, 2009). "Dundasite". http://www.mindat.org/forum.php?read,70,134092,134295. Retrieved 2009-10-16. 
  6. "Volume 14". The Mineralogical Magazine and Journal of the Mineralogical Society (Great Britain: Mineralogical Society). 1965.