Chemistry:Fire retardant

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Short description: Substance reducing flammability
Fire retardant dispersed aerially onto brush adjoining a firebreak to contain the Tumbleweed Fire in California, in July 2021

A fire retardant is a substance that is used to slow down or stop the spread of fire or reduce its intensity. This is commonly accomplished by chemical reactions that reduce the flammability of fuels or delay their combustion.[1][2] Fire retardants may also cool the fuel through physical action or endothermic chemical reactions. Fire retardants are available as powder, to be mixed with water, as fire-fighting foams and fire-retardant gels. Fire retardants are also available as coatings or sprays to be applied to an object.[3]

Fire retardants are commonly used in fire fighting, where they may be applied aerially or from the ground.

Principles of operation

In general, fire retardants reduce the flammability of materials by either blocking the fire physically or by initiating a chemical reaction that stops the fire.

Physical action

There are several ways in which the combustion process can be retarded by physical action:

  • By cooling: Some chemical reactions actually cool the material down.
  • By forming a protective layer that prevents the underlying material from igniting.
  • By dilution: Some retardants release water and/or carbon dioxide while burning. This may dilute the radicals in the flame enough for it to go out.

Commonly used fire retardant additives include mixtures of huntite and hydromagnesite, aluminium hydroxide, and magnesium hydroxide. When heated, aluminium hydroxide dehydrates to form aluminum oxide (alumina, Al2O3), releasing water vapor in the process. This reaction absorbs a great deal of heat, cooling the material into which it is incorporated. Additionally, the residue of alumina forms a protective layer on the material's surface. Mixtures of huntite and hydromagnesite work in a similar manner. They endothermically decompose releasing both water and carbon dioxide,[4][5] giving fire retardant properties[6][7][8] to the materials in which they are incorporated.

Chemical action

  • Reactions in the gas phase: chemical reactions in the flame (i.e. gas phase) can be interrupted by fire retardants. Generally, these retardants are organic halides (haloalkanes) such as Halon and PhostrEx. The chemicals used in these types of retardants are often toxic.
    Further information: Flame retardant § Gas phase radical quenching
  • Reaction in the solid phase: some retardants break down polymers so they melt and flow away from the flame. Although this allows some materials to pass certain flammability tests[which?], it is not known whether fire safety is truly improved by the production of flammable plastic droplets.
  • Char Formation: For carbon-based fuels, solid phase flame retardants cause a layer of carbonaceous char to form on the fuel surface. This char layer is much harder to burn and prevents further burning.[9][10]
  • Intumescents: These types of retardant materials incorporate chemicals which cause swelling behind the protective char layer, providing much better insulation. They are available as plastic additives, and as paints for protecting wooden buildings or steel structures.

Uses

Portable fire extinguisher

Fire extinguishers

Class A foam is used as a fire retardant in 2.5 gallon [APW] and [CAFS] extinguishers to contain incipient brush fires and grass fires by creating a fire break. Other chemical retardants are capable of rendering class A material and Class B fuels non-flammable and extinguishing class A, class B, and some class D fires.[citation needed] Fire retardant slurries dropped from aircraft are normally applied ahead of a wildfire to prevent ignition, while fire suppression agents are used to extinguish fires.

Surface coating

Objects may be coated with fire retardants. For example, Christmas trees are sprayed with retardants, as a tree dries out it becomes very flammable and a fire-hazard.

Steel structures have a fire retardant coating around columns and beams to prevent structural elements from weakening during a fire.

Dormitories in the US are also considering using these products.[citation needed] Since 2000, 109 people have died in fires in dormitories or off-campus student housing across the nation, according to Campus Firewatch, an online newsletter.[when?] Campus Firewatch's publisher, Ed Comeau, said a January 2000 fire at Seton Hall University in New Jersey drew attention to the perils of fire on campus. A common area in a Seton Hall dorm caught fire after two students ignited a banner from a bulletin board. The fire quickly spread to furniture and killed three students and injured 58 others.[11]

Forest-fire fighting

A MAFFS-equipped Air National Guard C-130 Hercules drops fire retardant on wildfires in Southern California
Red-dyed line of fire retardant stands out clearly on this Arizona hill, to control the Alambre Fire

Early fire retardants were mixtures of water and thickening agents, and later included borates[12] and ammonium phosphates.[citation needed]

Generally, fire retardants are dropped from aircraft or applied by ground crews around a wildfire's edges in an effort to contain its spread. This allows ground crews time to work to extinguish the fire. However, when needed, retardant can also be dropped directly onto flames to cool the fire and reduce flame length.[13]

Aerial firefighting

Aerial firefighting is a method to combat wildfires using aircraft. The types of aircraft used include fixed-wing aircraft and helicopters. Smokejumpers and rappellers are also classified as aerial firefighters, being delivered by parachute from a variety of fixed-wing aircraft, or rappelling from helicopters. Chemicals used to fight fires may include water, water enhancers, or specially-formulated fire retardants.[14]

Textiles

Materials

Wildfire retardants

Fire retardants applied to wildfires are usually a mixture of water and chemicals designed to wet the area as well as chemically retard a fire's progression through vegetation. Typically it is colored[15] so that the application area can be seen from the air. Fire retardant gel based retardants which meet NFPA Standard 1150 are also being used in service. These are dyed other colors to differentiate them from the traditional red retardant. The gels and their dyes are designed to biodegrade naturally.[16]

Any fire retardant approved for use against wildfires on US Federal lands must be included on the United States Forest Service Qualified Products List.[17] To be added to that list, the product must be tested by Wildland Fire Chemical Systems, a division of the National Technology and Development Program, a process that can take up to two years.[18] Phos-Chek is a brand of long-term retardant currently approved for wildland fire use.[19] Phos-Chek also has a consumer-based fire retardant spray called Wildfire Home Defense that is effective immediately after application and that remains effective until it is washed off with heavy water levels. It is designed to be applied to fuel beds around homes and outbuildings to create a firebreak in the fuels leading up to each structure.[20] Ember Bloc is another consumer-based fire retardant gel that can be applied to the exterior of one's house and nearby structures to help protect against both embers and flames in a wildfire. It has a unique ability to cling onto the side of a house to withstand high heat and windy conditions.[21]

Environmental concerns

Forest fire retardants that are used are generally considered non-toxic,[22] but even less-toxic compounds carry some risk when organisms are exposed to large amounts.[23] Fire retardants used in firefighting can be toxic to fish and wildlife as well as firefighters[24] by releasing dioxins and furans when halogenated fire retardants are burned during fires,[25] and drops within 300 feet of bodies of water are generally prohibited unless lives or property are directly threatened.[26] The US Forest Service is the governing agency that conducts research and monitors the effect of fire retardants on wildland systems in the US.[27][28]

A study published in June 2014 found that marine bacteria have the ability to manufacture a non-synthetic source of chemically identical polybrominated diphenyl ethers (PBDEs). These chemicals are used as flame retardant, but are known to be toxic to the environment.[29]

Potential risk and health concerns

Risks

Most chemical fire retardants are organic halides (haloalkanes) such as Halon and PhostrEx, which are proven to be toxic. During 1980s, the most commonly used fire retardant material was penta-bromodiphenyl ether. It was banned by the Government due to its potential health and environment concerns. It was then replaced by chlorinated tris, chloroalkyl phosphates, halogenated aryl esters, and tetrabromophthalate diol diester, which later were proven by an EPA study that they contained mutagens that could be absorbed into children's bodies.[30]

Studies have shown that a small percentage of the population may have an allergy towards the chemical substance used as fire retardant.[31] Studies have also shown that a drop of the retardant chemical directly into a stream may cause a sufficient ammonia concentration in the water, which is lethal to fish and other aquatic organisms.[32] If the amount is large enough, there is a risk that it could lead to lethal consequences towards humans.

Health concerns

Long-term exposure to these chemicals are likely to develop cancer or skin disease for fire fighters, and the potential contamination towards the environment will be another safety concern.[33] Many of these chemicals are now recognized as global contaminants and are associated with adverse health effects in animals and humans, including endocrine and thyroid disruption, immunotoxicity, reproductive toxicity, cancer, and adverse effects on fetal and child development and neurologic function.[34]

One of the most common way to spread fire retardant is through aerial firefighting, which means that there are chances that these toxic chemicals will contaminate the soil and water system, and then find their way into human body. This will lead to the likelihood of developing long-term health issues, such as respiratory disease or other risky health concerns.[35]

Another notable health concern is that fire-suppressant foams are toxic in standardized soft and hard water, and it is likely that water creatures will be infected. If they were to be consumed by humans, there is a great chance that these toxicities will be transferred into human body.[36]

See also

References

  1. ↑ "BLM Wyoming Wildland Fire Glossary". Blm.gov. 2008-06-18. http://www.blm.gov/wy/st/en/programs/Fire/glossary.html#f. 
  2. ↑ Coford Glossary "Fire Retardant"
  3. ↑ "Zinsser Glossary". Zinsser.com. http://www.zinsser.com/glossary.asp?letter=F. 
  4. ↑ Hollingbery, LA; Hull TR (2010). "The Thermal Decomposition of Huntite and Hydromagnesite - A Review". Thermochimica Acta 509 (1–2): 1–11. doi:10.1016/j.tca.2010.06.012. http://clok.uclan.ac.uk/1139. 
  5. ↑ Hollingbery, LA; Hull TR (2012). "The Thermal Decomposition of Natural Mixtures of Huntite and Hydromagnesite". Thermochimica Acta 528: 45–52. doi:10.1016/j.tca.2011.11.002. http://clok.uclan.ac.uk/3414. 
  6. ↑ Hollingbery, LA; Hull TR (2010). "The Fire Retardant Behaviour of Huntite and Hydromagnesite - A Review". Polymer Degradation and Stability 95 (12): 2213–2225. doi:10.1016/j.polymdegradstab.2010.08.019. http://clok.uclan.ac.uk/1432. 
  7. ↑ Hollingbery, LA; Hull TR (2012). "The Fire Retardant Effects of Huntite in Natural Mixtures with Hydromagnesite". Polymer Degradation and Stability 97 (4): 504–512. doi:10.1016/j.polymdegradstab.2012.01.024. http://clok.uclan.ac.uk/3420. 
  8. ↑ Hull, TR; Witkowski A; Hollingbery LA (2011). "Fire Retardant Action of Mineral Fillers". Polymer Degradation and Stability 96 (8): 1462–1469. doi:10.1016/j.polymdegradstab.2011.05.006. http://clok.uclan.ac.uk/2963. 
  9. ↑ "PHOS-CHeK D75 Fire Retardants". http://phos-chek.com/uploads/images/Product_Profile_D75_ICL.pdf. 
  10. ↑ "How do flame retardants work?". European Chemical Industry Council (CEFIC) and European Flame Retardants Association (EFRA). http://www.cefic-efra.com/Content/Default.asp?PageName=openfile&DocRef=2006-02-21-00001. 
  11. ↑ Amy Farnsworth (2007-08-06). "New coatings cut risk of a dorm fire". The Boston Globe. http://www.boston.com/business/technology/articles/2007/08/06/new_coatings_cut_risk_of_a_dorm_fire/. 
  12. ↑ "Methods and compositions for controlling fires" US patent 2858895, published November 4, 1958.
  13. ↑ "Interagency Standards for Fire and Aviation Operations 2007, Chapter 17". National Interagency Fire Center. http://www.nifc.gov/red_book/2007/Chapter17.pdf. 
  14. ↑ "USDA Forest Service Wildland Fire Chemicals". http://www.fs.fed.us/rm/fire/wfcs/index.htm. 
  15. ↑ & Kegeler, Gary H."Colorant liquid, method of use, and wildfire retardant liquids containing the same" US patent 6676858, published January 13, 2004.
  16. ↑ "New fire retardant gel developed that can remain effective for months". 4 October 2019. https://wildfiretoday.com/2019/10/04/new-fire-retardant-gel-developed-that-can-remain-effective-for-months/. 
  17. ↑ Qualified Products List
  18. ↑ "Long-Term Fire Retardants - National Technology and Development Program - USDA Forest Service". https://www.fs.fed.us/rm/fire/wfcs/long-term-fire-retardants.php. 
  19. ↑ "Wildland Fire Chemical Product Information". http://www.fs.fed.us/rm/fire/wfcs/products/index.htm. 
  20. ↑ "Phos-Chek Wildfire Home Defense FAQs". https://phos-chekhomedefense.com/faq/. 
  21. ↑ "Ember bloc fire gel fact sheet / Technical specs". https://www.jjsfiresupply.com/emberbloc_factsheet.asp. 
  22. ↑ {{cite web | url=http://www.firebreaksystems.com/files/Phos-Chek%20LC-95W%20MSDS.pdf | title=Phos-Chek MSDS | access-date=2008-11-14
  23. ↑ Bell, Tina; Tolhurst, Kevin; Wouters, Michael (16 May 2005). "Bell, T., Tolhurst, K., and Wouters, M. Effects of the fire retardant Phos-Chek on vegetation in eastern Australian heathlands. International Journal of Wildland Fire. 14(2) 199–211.". International Journal of Wildland Fire 14 (2): 199–211. doi:10.1071/WF04024. http://www.publish.csiro.au/paper/WF04024.htm. 
  24. ↑ "Greensciencepolicy.org". Greensciencepolicy.org. http://greensciencepolicy.org/?page_id=15. 
  25. ↑ "Effect of Fire Retardant on Water Quality". http://www.fs.fed.us/psw/publications/documents/psw_gtr109/psw_gtr109_79.pdf. 
  26. ↑ William Yardley (November 15, 2008). "In Fighting Wildfires, Concerns About Chemicals". The New York Times. https://www.nytimes.com/2008/11/16/us/16wildfires.html?pagewanted=1&_r=1. 
  27. ↑ "USDA Forest Service Wildland Fire Chemical Systems". http://www.fs.fed.us/rm/fire/index.htm. 
  28. ↑ "Wildland Fire Chemical Products Toxicity and Environmental Concerns". http://www.fs.fed.us/rm/fire/wfcs/documents/envinfo.pdf. 
  29. ↑ "Marine bacteria are natural source of chemical fire retardants". June 29, 2014. http://phys.org/news/2014-06-marine-bacteria-natural-source-chemical.html. 
  30. ↑ Lorber, Matthew (January 2008). "Exposure of Americans to polybrominated diphenyl ethers" (in en). Journal of Exposure Science & Environmental Epidemiology 18 (1): 2–19. doi:10.1038/sj.jes.7500572. ISSN 1559-064X. PMID 17426733. https://www.nature.com/articles/7500572. 
  31. ↑ Bakker, Martine I.; de Winter-Sorkina, Renata; de Mul, Anika; Boon, Polly E.; van Donkersgoed, Gerda; van Klaveren, Jacob D.; Baumann, Bert A.; Hijman, Willie C. et al. (February 2008). "Dietary intake and risk evaluation of polybrominated diphenyl ethers in The Netherlands". Molecular Nutrition & Food Research 52 (2): 204–216. doi:10.1002/mnfr.200700112. ISSN 1613-4133. PMID 18058856. https://pubmed.ncbi.nlm.nih.gov/18058856/. 
  32. ↑ Dietrich, Joseph P.; Myers, Mark S.; Strickland, Stacy A.; Van Gaest, Ahna; Arkoosh, Mary R. (January 2013). "Toxicity of forest fire retardant chemicals to stream-type chinook salmon undergoing parr-smolt transformation". Environmental Toxicology and Chemistry 32 (1): 236–247. doi:10.1002/etc.2052. ISSN 1552-8618. PMID 23161484. 
  33. ↑ Shaw, Susan D.; Blum, Arlene; Weber, Roland; Kannan, Kurunthachalam; Rich, David; Lucas, Donald; Koshland, Catherine P.; Dobraca, Dina et al. (October 2010). "Halogenated flame retardants: do the fire safety benefits justify the risks?". Reviews on Environmental Health 25 (4): 261–305. doi:10.1515/reveh.2010.25.4.261. ISSN 0048-7554. PMID 21268442. https://pubmed.ncbi.nlm.nih.gov/21268442/. 
  34. ↑ Shaw, Susan D.; Blum, Arlene; Weber, Roland; Kannan, Kurunthachalam; Rich, David; Lucas, Donald; Koshland, Catherine P.; Dobraca, Dina et al. (October 2010). "Halogenated flame retardants: do the fire safety benefits justify the risks?". Reviews on Environmental Health 25 (4): 261–305. doi:10.1515/reveh.2010.25.4.261. ISSN 0048-7554. PMID 21268442. https://pubmed.ncbi.nlm.nih.gov/21268442/. 
  35. ↑ Sugeng, Eva J.; de Cock, Marijke; Schoonmade, Linda J.; van de Bor, Margot (October 2017). "Toddler exposure to flame retardant chemicals: Magnitude, health concern and potential risk- or protective factors of exposure: Observational studies summarized in a systematic review". Chemosphere 184: 820–831. doi:10.1016/j.chemosphere.2017.06.041. ISSN 1879-1298. PMID 28645086. Bibcode: 2017Chmsp.184..820S. 
  36. ↑ Gaikowski, M. P.; Hamilton, S. J.; Buhl, K. J.; McDonald, S. F.; Summers, C. H. (August 1996). "Acute toxicity of firefighting chemical formulations to four life stages of fathead minnow". Ecotoxicology and Environmental Safety 34 (3): 252–263. doi:10.1006/eesa.1996.0070. ISSN 0147-6513. PMID 8812194. https://pubmed.ncbi.nlm.nih.gov/8812194/. 

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